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Volume 30
Main Index

Issue 1


EXAFS studies of the formation of chromia pillared clay catalysts
Klaus Bornholdt, Judith M. Corker, John Evans, and Jacqueline M. Rummey
pp 1 - 2; DOI:
10.1021/ic00001a001
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Crystal and molecular structures and spectroscopic properties of dichloro(2,5-dimethyl-2',5'-diisocyanohexane)digold; evidence for quasi-one-dimensional linear chains with weak Au(I)...Au(I) interactions in the solid state
Daniel Perreault, Marc Drouin, Andre Michel, and Pierre D. Harvey
pp 2 - 4; DOI:
10.1021/ic00001a002
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Synthesis and photochemical reactions of a layered manganese carbonyl-zirconium hydrogen phosphate compound
Charlotte F. Lee and Mark E. Thompson
pp 4 - 5; DOI:
10.1021/ic00001a003
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Synthesis and structural characterization of Mo2Cl4(tetraphos-1)(tetraphos-1 = Ph2PCH2CH2P(Ph)CH2CH2P(Ph)CH2CH2PPh2). The first complexes of enantiomeric 1,2,5,8/1,2,6,7 type
Jhy Der Chen and F. Albert Cotton
pp 6 - 7; DOI:
10.1021/ic00001a004
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Manganese complexes of .alpha.-hydroxy acids
Salman M. Saadeh, Myoung Soo Lah, and Vincent L. Pecoraro
pp 8 - 15; DOI:
10.1021/ic00001a005
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Metalloporphyrins containing .sigma.-bonded nitrogen axial ligands. 1. Synthesis and characterization of indium(III) porphyrin complexes. Molecular structures of (4-phenyltetrazolato) and (5-methyltetrazolato)(2,3,7,8,12,13,17,18-octaethylporphinato)indium(III)
R. Guilard, N. Jagerovic, A. Tabard, P. Richard, L. Courthaudon, A. Louati, C. Lecomte, and Karl M. Kadish
pp 16 - 27; DOI:
10.1021/ic00001a006
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Metalloprophyrins containing .sigma.-bonded nitrogen axial ligands. 2. Synthesis and characterization of iron(III) tetrazolato and triazolato porphyrin complexes. Molecular structure of (5-methyltetrazolato)(2,3,7,8,12,13,17,18-octaethylporphinato)iron(III)
R. Guilard, I. Perrot, A. Tabard, P. Richard, C. Lecomte, Y. H. Liu, and Karl M. Kadish
pp 27 - 37; DOI:
10.1021/ic00001a007
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Heteronuclear multiple-quantum coherence NMR spectroscopy of paramagnetic heme and cytochrome c-551
Russell Timkovich
pp 37 - 42; DOI:
10.1021/ic00001a008
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Photophysical properties of a series of octacarbonyl(.alpha.,.alpha.-diimine)dirhenium compounds
Londa J. Larson, Ad Oskam, and Jeffrey I. Zink
pp 42 - 48; DOI:
10.1021/ic00001a009
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pH control of the photophysical properties of ruthenium complexes containing 3-(pyrazin-2-yl)-1,2,4-triazole ligands
Heleen A. Nieuwenhuis, Jaap G. Haasnoot, Ronald Hage, Jan Reedijk, Theo L. Snoeck, Derk J. Stufkens, and Johannes G. Vos
pp 48 - 54; DOI:
10.1021/ic00001a010
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Interaction energies associated with short intermolecular contacts of carbon-hydrogen bonds. 1. Ab initio computational study of C-H.cntdot..cntdot..cntdot.anion interactions, C-H.cntdot..cntdot..cntdot.X-(X- = I3-, IBr2-, ICl2-)
Juan J. Novoa, Fernando Mota, Myung Hwan Whangbo, and Jack M. Williams
pp 54 - 58; DOI:
10.1021/ic00001a011
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Gas-phase structure of sulfur cyanate pentafluoride, SF5OCN. Electron diffraction and ab initio study
Petra Zylka, Hans Georg Mack, Arno Schmuck, Konrad Seppelt, and Heinz Oberhammer
pp 59 - 62; DOI:
10.1021/ic00001a012
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A tungsten-183 NMR study of mononuclear tungsten(VI) methyl complexes containing terminal oxo, sulfido, and imido ligands
Yinong Ma, Peter Demou, and J. W. Faller
pp 62 - 64; DOI:
10.1021/ic00001a013
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Mononuclear octahedral and dinuclear edge-sharing and face-sharing bioctahedral compounds of molybdenum(III). Electronic control on the extent of metal-metal interaction in the dinuclear systems. An equilibrium, structural, and paramagnetic NMR study
Rinaldo Poli and Humberto D. Mui
pp 65 - 77; DOI:
10.1021/ic00001a014
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Isolation, characterization, and substitution reactions of the osmium trinuclear triflate complex H2Os3(CO)9(O3SCF3)2. X-ray crystal structure of the mixed oxyligand cluster (.mu.-H)2Os3(CO)9(.mu.,.eta.2-O2CCH3)(.eta.1-O3SCF3)
Greg R. Frauenhoff, Scott R. Wilson, and John R. Shapley
pp 78 - 85; DOI:
10.1021/ic00001a015
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Formation of a metal-hydride bond and the insertion of carbon dioxide. Key steps in the electrocatalytic reduction of carbon dioxide to formate anion
J. Richard Pugh, Mitchell R. M. Bruce, B. Patrick Sullivan, and Thomas J. Meyer
pp 86 - 91; DOI:
10.1021/ic00001a016
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Closed-shell electronic requirements for condensed clusters of the group 11 elements
Zhenyang Lin, Rene P. F. Kanters, and D. Michael P. Mingos
pp 91 - 95; DOI:
10.1021/ic00001a017
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Synthesis and spectroscopic properties of bis(trimethylsilyl)amides of the alkaline-earth metals magnesium, calcium, strontium, and barium
Matthias Westerhausen
pp 96 - 101; DOI:
10.1021/ic00001a018
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Preparation characterization and crystal structure of chloryl hexafluororuthenate(1-). Crystal structure of [ClF2]+[RuF6]-
Roland Bougon, Walter V. Cicha, Monique Lance, Laurent Meublat, Martine Nierlich, and Julien Vigner
pp 102 - 109; DOI:
10.1021/ic00001a019
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Crystal structure and electronic spectroscopy of bis(hydrazinium) hexachlorotricuprate(2I,II): a copper(I)-copper(II) mixed-valence system exhibiting intervalence charge transfer
Brian Scott and Roger Willett
pp 110 - 113; DOI:
10.1021/ic00001a020
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EPR spectra of dichloro(pentamethylcyclopentadienyl)bis(trimethylphosphine)molybdenum in solution and in single crystals of (C5Me5)MoCl(PMe3)2(N2)
R. Tom Baker, J. R. Morton, K. F. Preston, A. J. Williams, and Y. Le Page
pp 113 - 116; DOI:
10.1021/ic00001a021
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Vibrational study of the effects of high external pressures on the structure and phase behavior of pentacarbonyl(methyl)manganese(I) and pentacarbonyl(methyl)rhenium(I)
Yining Huang, Ian S. Butler, Denis F. R. Gilson, and Dominique Lafleur
pp 117 - 120; DOI:
10.1021/ic00001a022
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Syntheses and structures of a series of very low coordinate barium compounds: Ba[N(SiMe3)2]2(THF)2, {Ba[N(SiMe3)2)]2(THF)}2, and {Ba[N(SiMe3)2]2}2
Brian A. Vaartstra, John C. Huffman, William E. Streib, and Kenneth G. Caulton
pp 121 - 125; DOI:
10.1021/ic00001a023
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Reactivity of palladium(II) complexes with bidentate bis(phosphine) ligands toward the octahydrotriborate(1-) anion and dependence of the reaction upon halide arrangement: molecular structure of the trans-(bis(diphenylphosphino)hexane)palladium(II) dichloride dimer
Catherine E. Housecroft, Bilal A. M. Shaykh, Arnold L. Rheingold, and Brian S. Haggerty
pp 125 - 130; DOI:
10.1021/ic00001a024
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Generalized synthesis of cis- and trans-dioxorhenium(V) (bi)pyridyl complexes
M. S. Ram and Joseph T. Hupp
pp 130 - 133; DOI:
10.1021/ic00001a025
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Transannular oscillation of metal centers in the pendant arm macrocyclic complex [1,4,8,11-tetrakis(2-hydroxyethyl)-1,4,8,11-tetraazacyclotetradecane]mercury(II) and its lead(II) analog. NMR study of the carbon-13 natural abundance and specifically enriched complexes
Philip Clarke, Stephen F. Lincoln, and Kevin P. Wainwright
pp 134 - 139; DOI:
10.1021/ic00001a026
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Volumes of activation for electron transfer between a series of cobalt clathrochelates and ferrocenes as a function of solvent and added electrolyte
Mark A. Murguia and Scot Wherland
pp 139 - 144; DOI:
10.1021/ic00001a027
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Titanium(IV) and zirconium(IV) tetrahydroborate moieties supported by a phenoxo ligand
Fabio Corazza, Carlo Floriani, Angiola Chiesi-Villa, and Carlo Guastini
pp 145 - 148; DOI:
10.1021/ic00001a028
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Synthesis and characterization of some (trifluoroethoxy)boranes
S. Yvette Shaw and Robert H. Neilson
pp 148 - 150; DOI:
10.1021/ic00001a029
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Complexes of hexaphenoxycyclotriphosphazene and sulfur trioxide
Enzo Montoneri, Giuliana Ricca, Mario Gleria, and Maria C. Gallazzi
pp 150 - 152; DOI:
10.1021/ic00001a030
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Issue 2


A new microporous (ca. 25 vol .permill. void space) molybdenum phosphate based on the octahedral-tetrahedral Mo2O2(PO4)2(H2PO4)- framework
Linda A. Mundi, Karl G. Strohmaier, and Robert C. Haushalter
pp 153 - 154; DOI:
10.1021/ic00002a001
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Novel titanium(II) amine complexes L4TiCl2[L = 1/2 N,N,N',N'-tetramethylethylenediamine (TMEDA), 1/2 N,N,N'-trimethylethylenediamine, pyridine, 1/2 2,2'-bipyridine]: synthesis and crystal structure of monomeric trans-(TMEDA)2TiCl2
Jilles J. H. Edema, Robbert Duchateau, Sandro Gambarotta, Rosemary Hynes, and Eric Gabe
pp 154 - 156; DOI:
10.1021/ic00002a002
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Activated molybdenum-molybdenum quadruple bonds. 2. First example of alkyne additions to metal-metal quadruple bonds
Michael C. Kerby, Bryan W. Eichhorn, Loriann Doviken, and K. Peter C. Vollhardt
pp 156 - 158; DOI:
10.1021/ic00002a003
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Single-crystal structure of tantalum sulfide (Ta3S2). Structure and bonding in the Ta6Sn (n = 1,3,4,5?) pentagonal-antiprismatic chain compounds
Sung Jin Kim, K. S. Nanjundaswamy, and Timothy Hughbanks
pp 159 - 164; DOI:
10.1021/ic00002a004
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Structural and magnetic versatility of the manganese(II)/copper complex[Cu(X4obbz)]2- system (X4obbz = oxamido-N,N'-bis(3,5-dihalogenobenzoato); X = Cl, Br). Crystal structures and magnetic properties of MnCu(Cl4obbz)(H2O)5 and MnCu(Br4obbz)(H2O)3.cntdot.2.5H2O
Keitaro Nakatani, Jorunn Sletten, Sabine Halut-Desporte, Suzanne Jeannin, Yves Jeannin, and Olivier Kahn
pp 164 - 171; DOI:
10.1021/ic00002a005
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Solid-state NMR studies of magneto-structural correlations in anhydrous copper(II) carboxylates
Gordon C. Campbell, Joseph H. Reibenspies, and James F. Haw
pp 171 - 176; DOI:
10.1021/ic00002a006
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Copper(I) and silver(I) complexes of the crown thioether ligand 2,5,8-trithia[9]-o-benzenophane (TT[9]OB). Structures of [Cu(PPh2Me)(TT[9]OB)][ClO4] and [Ag(PPh3)(TT[9]OB)][ClO4]
Broer De Groot, Garth R. Giesbrecht, Stephen J. Loeb, and George K. H. Shimizu
pp 177 - 182; DOI:
10.1021/ic00002a007
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Layered structure of crystalline compounds silver thiolates (AgSR)
Ian G. Dance, Keith J. Fisher, R. M. Herath Banda, and Marcia L. Scudder
pp 183 - 187; DOI:
10.1021/ic00002a008
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Mercury polysulfide complexes, [Hg(Sx)(Sy)]2-: syntheses, mercury-199 NMR studies in solution, and crystal structure of (Ph4P)4[Hg(S4)2]Br2
Trevor D. Bailey, R. M. Herath Banda, Donald C. Craig, Ian G. Dance, Ida N. L. Ma, and Marcia L. Scudder
pp 187 - 191; DOI:
10.1021/ic00002a009
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An unexpected stoichiometric effect in both solution and solid state in mercury-rich dithiocarbamate cation chemistry: crystal and molecular structure of polymeric tris(piperidinecarbodithioato)dimercury(II) perchlorate
Alan M. Bond, Ray Colton, Anthony F. Hollenkamp, Bernard F. Hoskins, Katherine McGregor, and Edward R. T. Tiekink
pp 192 - 197; DOI:
10.1021/ic00002a010
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Association of a methylplatinum fluoroalkoxide complex with a fluoro alcohol through O-H...O hydrogen bonding in the solid state and in solution
Kohtaro Osakada, Yong Joo Kim, Masako Tanaka, Shinichi Ishiguro, and Akio Yamamoto
pp 197 - 200; DOI:
10.1021/ic00002a011
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Reaction products of [Pt(ethylenediamine)(dimethyl sulfoxide)Cl]Cl and [Pt(ethylenediamine)Cl2] with d(GpG) and 5'GMP. Unambiguous evidence for stable 1:1 intermediate N7 adducts with coordinated dimethyl sulfoxide
Edwin L. M. Lempers, Marieke J. Bloemink, and Jan Reedijk
pp 201 - 206; DOI:
10.1021/ic00002a012
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Synthesis and reactivity of dinuclear copper complexes having a m-xylyl spacer between coordination units
Thomas N. Sorrell, Vivian A. Vankai, and Martha L. Garrity
pp 207 - 210; DOI:
10.1021/ic00002a013
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Synthesis and reactivity of imidazolyl- and benzimidazolyl-containing copper complexes
Thomas N. Sorrell and Martha L. Garrity
pp 210 - 215; DOI:
10.1021/ic00002a014
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Crystal structure and magnetic interactions in bis(D,L-alaninato)copper(II) hydrate
R. Calvo, P. R. Levstein, E. E. Castellano, S. M. Fabiane, O. E. Piro, and S. B. Oseroff
pp 216 - 220; DOI:
10.1021/ic00002a015
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Spectroscopic and binding studies of azide-copper(II) model complexes
Luigi Casella, M. Gullotti, G. Pallanza, and M. Buga
pp 221 - 227; DOI:
10.1021/ic00002a016
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Multinuclear NMR investigation of zinc(2+) binding to a dodecamer oligodeoxyribonucleotide: insights from carbon-13 NMR spectroscopy
Xin Jia, Gerald Zon, and Luigi G. Marzilli
pp 228 - 239; DOI:
10.1021/ic00002a017
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Octabromotetraphenylporphyrin and its metal derivatives: Electronic structure and electrochemical properties
P. Bhyrappa and V. Krishnan
pp 239 - 245; DOI:
10.1021/ic00002a018
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Exchange coupling and resonance delocalization in reduced iron-sulfur [Fe4S4]+ and iron-selenium [Fe4Se4]+ clusters. 1. Basic theory of spin-state energies and EPR and hyperfine properties
Louis Noodleman
pp 246 - 256; DOI:
10.1021/ic00002a019
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Exchange coupling and resonance delocalization in reduced iron-sulfur [Fe4S4]+ and iron-selenium [Fe4Se4]+ clusters. 2. A generalized nonlinear model for spin-state energies and EPR and hyperfine properties
Louis Noodleman
pp 256 - 264; DOI:
10.1021/ic00002a020
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Sharp-line electronic spectroscopy and metal-ligand geometry in the pentaamminehydroxochromium(III) complex
Kyu Wang Lee and Patrick E. Hoggard
pp 264 - 270; DOI:
10.1021/ic00002a021
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Synthesis, absorption spectra, and photochemical behavior of mono- and dinuclear ruthenium(II) complexes
Gaetano Di Marco, Antonino Bartolotta, Vittorio Ricevuto, Sebastiano Campagna, Gianfranco Denti, Luigina Sabatino, and Giuseppina De Rosa
pp 270 - 275; DOI:
10.1021/ic00002a022
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Magnetic circular dichroism spectra for the octakis(triphenylphosphino)nonagold(3+) ion
Huey Rong C. Jaw and W. Roy Mason
pp 275 - 278; DOI:
10.1021/ic00002a023
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Classical and nonclassical polyhydride ruthenium(II) complexes stabilized by the tetraphosphine P(CH2CH2PPh2)3
Claudio Bianchini, Pedro J. Perez, Maurizio Peruzzini, Fabrizio Zanobini, and Alberto Vacca
pp 279 - 287; DOI:
10.1021/ic00002a024
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Synthesis, reactivity, molecular structure, and catalytic activity of the novel dichlorodihydridoosmium(IV) complexes OsH2Cl2(PR3)2 (PR3 = P-i-Pr3, PMe-t-Bu2)
M. Aracama, M. A. Esteruelas, F. J. Lahoz, J. A. Lopez, U. Meyer, L. A. Oro, and H. Werner
pp 288 - 293; DOI:
10.1021/ic00002a025
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Hexacarbonylocta(.mu.3-sulfido)hexacobalt.cntdot.tris(octasulfur). Structure, bonding, and vibrational analysis of an exceptionally electron-rich carbonyl cluster
E. Diana, G. Gervasio, R. Rossetti, F. Valdemarin, G. Bor, and P. L. Stanghellini
pp 294 - 299; DOI:
10.1021/ic00002a026
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Preparation and properties of mononuclear vanadium thiolates: structural characterization of the [V(SBu-tert)4]0,- pair and carbon-sulfur bond cleavage in V(SBu-tert)4 in the gas phase
Dwight D. Heinrich, Kirsten Folting, John C. Huffman, John G. Reynolds, and George Christou
pp 300 - 305; DOI:
10.1021/ic00002a027
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Protonation of tricarbonylbis(tricyclohexylphosphine)tungsten
Lori Stepan Van der Sluys, Kimberly A. Kubat-Martin, Gregory J. Kubas, and Kenneth G. Caulton
pp 306 - 310; DOI:
10.1021/ic00002a028
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Synthesis, characterization, and structure of tungsten-pentadienyl compounds. An observable .eta.5.dblarw..eta.3 equilibrium for a pentadienyl ligand
Sheng Liang Wu, Chih Yi Cheng, Sue Lein Wang, and Rai Shung Liu
pp 311 - 316; DOI:
10.1021/ic00002a029
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NMR study of the chemical exchange of the hydrido ligands in the bis(bis(diphenylphosphino)ethane)trihydridodiplatinum(II) cation by T1, T2, and HD isotopic perturbation
Silvio Aime, R. Gobetto, A. L. Bandini, G. Banditelli, and G. Minghetti
pp 316 - 318; DOI:
10.1021/ic00002a030
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Photochemical reactivity of diplatinum .mu.-alkenylidene complexes: evidence of atom-transfer chemistry
Eduardo Baralt and C. M. Lukehart
pp 319 - 320; DOI:
10.1021/ic00002a031
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Synthesis and characterization of erbium(3+) and neodymium(3+) cryptates
F. de M. Ramirez, M. Solache-Rios, and A. Campero
pp 321 - 325; DOI:
10.1021/ic00002a032
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New orthocyclophane cyclotetraphosphazanes: [C6H4N2(PR)2]2 (R = Ph, Me) and [C6H4N2(PPh)(PhPS)]2
Joseph M. Barendt, Elizabeth G. Bent, Susan M. Young, R. Curtis Haltiwanger, and Arlan D. Norman
pp 325 - 331; DOI:
10.1021/ic00002a033
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Five-coordinate nickel(III) phosphines: spectroscopic and EXAFS studies
Judith M. Corker, John Evans, William Levason, Mark D. Spicer, and Paul Andrews
pp 331 - 334; DOI:
10.1021/ic00002a034
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Synthesis and characterization of a tetranuclear iron(III) complex derived from a new m-xylyl-bridged tetraimidazole ligand
Jonathan L. Sessler, Jeffrey D. Hugdahl, Vincent Lynch, and Brian Davis
pp 334 - 336; DOI:
10.1021/ic00002a035
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Electrochemical, spectroscopic, and structural characterization of rhodium complexes Rh2(dpf)4, Rh2(dpf)4(CH3CN), and [Rh2(dpf)4(CH3CN)]ClO4, where dpf = N,N'-diphenylformamidinate(1-)
John L. Bear, C. L. Yao, R. S. Lifsey, J. D. Korp, and K. M. Kadish
pp 336 - 340; DOI:
10.1021/ic00002a036
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Electronic spectra of the cations of europium(II), samarium(II) and ytterbium(II) in anhydrous hydrogen fluoride
Colin G. Barraclough, Russell W. Cockman, and Thomas A. O'Donnell
pp 340 - 343; DOI:
10.1021/ic00002a037
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Preparation and characterization of samarium(II) hexafluorogermanate
Colin G. Barraclough, Russell W. Cockman, and Thomas A. O'Donnell
pp 343 - 344; DOI:
10.1021/ic00002a038
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Reactivity of polyaza diphosphorus macrocycles
Jean Pierre Majoral, Meryam Badri, Anne Marie Caminade, Michel Delmas, and Antoine Gaset
pp 344 - 346; DOI:
10.1021/ic00002a039
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Pathological luminescence characteristics of cis-bis(2,2'-bipyridine)dichloroiridium(1+)
Lynne Wallace, Graham A. Heath, Elmars Krausz, and Grainne Moran
pp 347 - 349; DOI:
10.1021/ic00002a040
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A new look at the vanadium(III) and vanadium(IV) complexes of the dibenzotetramethyltetraaza[14]annulene (tmtaa) ligand. Synthesis and molecular structures of CpV(tmtaa) and (O)V(tmtaa)
F. Albert Cotton, J. Czuchajowska, and X. Feng
pp 349 - 353; DOI:
10.1021/ic00002a041
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Synthesis and complexation studies of mesocyclic and macrocyclic polythioethers. 7. Benzene trisulfide, the strongest field thioether ligand: its nickel(II) complex
Gregory J. Grant, Carolyn D. Grant, and William N. Setzer
pp 353 - 355; DOI:
10.1021/ic00002a042
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Chelate ring closure in (o-phenanthroline)pentacarbonylmetal transients (metal = chromium, molybdenum, tungsten) generated by pulsed laser flash photolysis
Shulin Zhang, Volker Zang, Gerard R. Dobson, and Rudi Van Eldik
pp 355 - 356; DOI:
10.1021/ic00002a043
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Issue 3


Preparation and solid-state structure of a novel carboxylate derivative of copper(I), (Ph3P)2Cu(O2CCH2CN)2H
Donald J. Darensbourg, Elisabeth M. Longridge, Earl V. Atnip, and Joseph H. Reibenspies
pp 357 - 358; DOI:
10.1021/ic00003a001
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Comments on the substitutional lability of the dimetal carboxylates of molybdenum and rhodium. Effects of M-M MO configuration
Jose M. Casas, Roger H. Cayton, and Malcolm H. Chisholm
pp 358 - 360; DOI:
10.1021/ic00003a002
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Thermal decomposition of energetic materials. 48. Structures and decomposition mechanisms of copper(II) complexes of furazans (1,2,5-oxadiazoles)
C. E. Stoner, A. L. Rheingold, and T. B. Brill
pp 360 - 364; DOI:
10.1021/ic00003a003
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Template condensation reactions of formaldehyde with tetraamines and ethylenediamine: preparation, properties, and structures of nickel(II) and copper(II) complexes of hexaaza macrotricyclic ligands 1,3,6,8,11,14-hexaazatricyclo[12.2.1.18,11]octadecane and 1,3,6,8,12,15-hexaazatricyclo[13.3.1.18,12]eicosane
Myunghyun Paik Suh, Shin Geol Kang, Virgil L. Goedken, and Sang Hee Park
pp 365 - 370; DOI:
10.1021/ic00003a004
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Structure and reactivity of the nickel(II) complex of a new open-chain amine 6,6-bis(4-amino-2-azabutyl)-1,4-diazacycloheptane and of the nickel(III) complex of its macrocyclic analog: effects on the reduction of perchlorate ion
A. McAuley and S. Subramanian
pp 371 - 378; DOI:
10.1021/ic00003a005
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Synthesis of new cyclopentadienyliron and -ruthenium benzenethiolate, thiol, and thio ether complexes
Paul M. Treichel, Mark S. Schmidt, and Richard A. Crane
pp 379 - 381; DOI:
10.1021/ic00003a006
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Relationships between structure and redox properties of dodecacarbonyl(.mu.4-.eta.2-diphenylacetylene)tetraruthenium and [Et4N]2[Ru4(CO)11(.mu.4-.eta.2-C2Ph2)]
Jiandang Wang, Michal Sabat, Leslie J. Lyons, and Duward F. Shriver
pp 382 - 387; DOI:
10.1021/ic00003a007
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Heterometallic gold-platinum phosphine complexes. 2. X-ray crystal and molecular structures of [(CO)(PPh3)Pt(AuPPh3)5](Cl) and [(PPh3)Pt(AuPPh3)5(HgNO3)2](NO3)
Larry N. Ito, Anna Maria P. Felicissimo, and Louis H. Pignolet
pp 387 - 396; DOI:
10.1021/ic00003a008
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Synthesis and phosphorus-31 NMR spectroscopy of trinuclear, phosphido-bridged iridium and rhodium clusters. Crystal and molecular structures of [M3(.mu.-PPh2)3(CO)nL2] (M = Ir or Rh, n = 3, L2 = 1,2-bis(diphenylphosphino)methane; M = Ir, n = 5, L = tert-BuNC)
David E. Berry, Jane Browning, Khashayar Dehghan, Keith R. Dixon, Neil J. Meanwell, and Andrew J. Phillips
pp 396 - 402; DOI:
10.1021/ic00003a009
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Synthesis and reactivity of ruthenium hydride complexes of chelating triphosphines. 3. Synthesis and characterization of new ruthenium hydride complexes containing C6H5P (CH2CH2CH2P (c-C6H11)2)2 (Cyttp)
Guochen Jia, Devon W. Meek, and Judith C. Gallucci
pp 403 - 410; DOI:
10.1021/ic00003a010
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Isomer preference of oxidation states. Chemistry of the bis(triphenylphosphine)bis(xanthato)osmium(z) (z = 0, +) family
Amitava Pramanik, Nilkamal Bag, Debashis Ray, Goutam Kumar Lahiri, and Animesh Chakravorty
pp 410 - 417; DOI:
10.1021/ic00003a011
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Relationship between the bite size of diphosphine ligands and tetrahedral distortions of "square-planar" nickel(II) complexes: stabilization of nickel(I) and palladium(I) complexes using diphosphine ligands with large bites
Alex Miedaner, R. Curtis Haltiwanger, and Daniel L. DuBois
pp 417 - 427; DOI:
10.1021/ic00003a012
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Scandium carbide, Sc3C4, a carbide with C3 units derived from propadiene
Rainer Poettgen and Wolfgang Jeitschko
pp 427 - 431; DOI:
10.1021/ic00003a013
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Zirconium chloride cluster phases centered by transition metals Mn-Ni. Examples of the Nb6F15 structure
Jie Zhang and John D. Corbett
pp 431 - 435; DOI:
10.1021/ic00003a014
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Ferromagnetic dihydroxo-bridged Cr(III)-Cu(II) and Cr(III)-Cu(II)-Cr(III) complexes, [Cr(tet b)(OH)2Cu(bpy)(CH3OH)](ClO4)3 and {Cu[Cr(tet b)(OH)2]2} (ClO4)4.cntdot.H2O (tet b = racemic 5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane and bpy = 2,2'-bipyridine)
Zhuang J. Zhong, Naohide Matsumoto, Hisashi Okawa, and Sigeo Kida
pp 436 - 439; DOI:
10.1021/ic00003a015
PDF
Ruthenium(II) chloride complexes of the mesocyclic ligand 1,5-dithiacyclooctane 1-oxide. Preparation and structure of the "all-trans" complex
Brian W. Arbuckle, Parimal K. Bharadwaj, and W. Kenneth Musker
pp 440 - 445; DOI:
10.1021/ic00003a016
PDF
Hydrothermal synthesis and crystal structure of the vanadyl(IV) hydrogen phosphate hydrate K2(VO)2P3O9(OH)3.cntdot.1.125H2O
Kwang Hwa Lii and Hung Jen Tsai
pp 446 - 448; DOI:
10.1021/ic00003a017
PDF
Preparation and characterization of a bis(pentaammineosmium(II)) pyrene complex
Tai Hasegawa, Mikiya Sekine, William P. Schaefer, and Henry Taube
pp 449 - 452; DOI:
10.1021/ic00003a018
PDF
Allyl complexes of pentaammineosmium
W. D. Harman, Tai Hasegawa, and Henry Taube
pp 453 - 456; DOI:
10.1021/ic00003a019
PDF
Solvent effects on the reactivity of vanadium(II)
John C. Dobson, Mitsuru Sano, and Henry Taube
pp 456 - 462; DOI:
10.1021/ic00003a020
PDF
Complexation of lithium(I) and silver(I) by 4,7,13,16-tetraoxa-1,10-diazabicyclo[8.8.2]eicosane in a range of solvents. A lithium-7 nuclear magnetic resonance and potentiometric titration study
Amira Abou-Hamdan and Stephen F. Lincoln
pp 462 - 466; DOI:
10.1021/ic00003a021
PDF
Importance of ion association in the induced reactions of cobalt(III)-acido complexes. 7. The mercury(2+)-assisted reaction of t-[Co(tren)(NH3)X]2+ (X = Cl-, Br-) in aqueous solution
David A. Buckingham, Charles R. Clark, and Wayne S. Webley
pp 466 - 474; DOI:
10.1021/ic00003a022
PDF
Electrochemistry of symmetrical and asymmetrical dinuclear ruthenium, osmium, and mixed-metal 2,2'-bipyridine complexes bridged by 2,2'-bibenzimidazolate
Masaaki Haga and Alan M. Bond
pp 475 - 480; DOI:
10.1021/ic00003a023
PDF
Preparation of a series of (imidazole)pentaaquachromium(III) complexes and kinetics of their reduction by 1-hydroxy-1-methylethyl radicals
A. Bakac, V. Butkovic, J. H. Espenson, R. Marcec, and M. Orhanovic
pp 481 - 483; DOI:
10.1021/ic00003a024
PDF
Electron transfer. 101. Reaction of carboxylato-bound chromium(V) with dimeric molybdenum(V)
M. C. Ghosh and Edwin S. Gould
pp 483 - 487; DOI:
10.1021/ic00003a025
PDF
Electron transfer. 104. Reductions of pyridinecarboxamides with vitamin B12s (cob(I)alamin)
S. K. Ghosh, P. N. Balasubramanian, G. Chithambarathanu Pillai, and E. S. Gould
pp 487 - 491; DOI:
10.1021/ic00003a026
PDF
Electron transfer. 106. Stabilized aqueous chromium(IV), as prepared from the chromium(VI)-arsenic(III) reaction
M. C. Ghosh and E. S. Gould
pp 491 - 494; DOI:
10.1021/ic00003a027
PDF
Proton-coupled electron transfer in high-valent oxomanganese dimers: role of the ancillary ligands
Rajesh Manchanda, H. Holden Thorp, Gary W. Brudvig, and Robert H. Crabtree
pp 494 - 497; DOI:
10.1021/ic00003a028
PDF
Cadmium(2+) and zinc(2+) interactions with amino acids N-substituted by a sulfonic group. Effect of the additional ligand 2,2'-bipyridine on the metal-induced amide deprotonation
G. Battistuzzi Gavioli, M. Borsari, L. Menabue, M. Saladini, and M. Sola
pp 498 - 502; DOI:
10.1021/ic00003a029
PDF
Kinetics of iron removal from monoferric and cobalt-labeled monoferric human serum transferrin by nitrilotris(methylenephosphonic acid) and nitrilotriacetic acid
Pawan K. Bali, Wesley R. Harris, and Diane Nesset-Tollefson
pp 502 - 508; DOI:
10.1021/ic00003a030
PDF
Lipophilic coordination compounds: aluminum, gallium, and indium complexes of 1-aryl-3-hydroxy-2-methyl-4-pyridinones
Zaihui Zhang, Steven J. Rettig, and Chris Orvig
pp 509 - 515; DOI:
10.1021/ic00003a031
PDF
Platinum(II)-thiolate cluster formation in heptaplatinum-metallothionein
Jacob Bongers, John U. Bell, and David E. Richardson
pp 515 - 519; DOI:
10.1021/ic00003a032
PDF
Ferric ion sequestering agents. 23. Synthesis of tris(hydroxypyridinethione) ligands and their ferric complexes; x-ray structure analysis of N,N',N"-tris((1,2-didehydro-1-hydroxy-2-thioxopyrid-6-yl)carbonyl)-2,2',2"-triaminotriethylaminato)iron(III)
Kamal Abu-Dari and Kenneth N. Raymond
pp 519 - 524; DOI:
10.1021/ic00003a033
PDF
Boron derivatives of 3-ferrocenylpyrazole
Kurt Niedenzu, J. Serwatowski, and S. Trofimenko
pp 524 - 527; DOI:
10.1021/ic00003a034
PDF
Synthesis and structure of diarylboryl-substituted hydrazines and diphosphanes: role of .sigma.-oribital hybridization and .pi.-orbital overlap in N-N and P-P multiple-bond lengths
Doris C. Pestana and Philip P. Power
pp 528 - 535; DOI:
10.1021/ic00003a035
PDF
Cesium fluoride promoted halogenation of cyanogen by chlorine and bromine and selected reactions of products
Qui Chi Mir and Darryl D. DesMarteau
pp 535 - 538; DOI:
10.1021/ic00003a036
PDF
Phenyl substituents and excited-state lifetimes in ruthenium(II) terpyridyls
Clark R. Hecker, Ann. K. I. Gushurst, and David R. McMillin
pp 538 - 541; DOI:
10.1021/ic00003a037
PDF
Emission and photochemical reactivity in fluorescent arene complexes of cyclopentadienylruthenium(II). Requirements for an emissive CpRu(arene)+ complex
Robert S. Koefod and Kent R. Mann
pp 541 - 548; DOI:
10.1021/ic00003a038
PDF
Three new compounds containing M3S4 (M = molybdenum, tungsten) cores prepared from M3S7X4 (M = Mo, W; X = Cl, Br) starting materials
F. Albert Cotton, Piotr A. Kibala, and Charla S. Miertschin
pp 548 - 553; DOI:
10.1021/ic00003a039
PDF
Photophysics and photochemistry of hexachlororhenate(IV) and hexabromorhenate(IV)
Andrew W. Maverick, Marc D. Lord, Qin Yao, and Leslie J. Henderson
pp 553 - 558; DOI:
10.1021/ic00003a040
PDF
Steric influences on the photoluminescence from copper(I) phenanthrolines in rigid media
R. Michael Everly, Raymond Ziessel, Jean Suffert, and David R. McMillin
pp 559 - 561; DOI:
10.1021/ic00003a041
PDF
Vibrational spectra of niobium(V) fluoro and oxo fluoro complexes formed in alkali-metal fluoride melts
J. H. Von Barner, E. Christensen, N. J. Bjerrum, and B. Gilbert
pp 561 - 566; DOI:
10.1021/ic00003a042
PDF
Solvent effects and excited-state dynamics in photochemical ligand substitution of the tungsten carbonyl complex W(CO)5L (L = piperidine, py)
Carol Moralejo and Cooper H. Langford
pp 567 - 569; DOI:
10.1021/ic00003a043
PDF
Synthesis and reactivity of (.eta.6-C6H6)Mn(CO)2SC(S)H and (.eta.6-C6(CH3)6)Mn(CO)2SC(S)H
Steven J. Schauer, Darrell P. Eyman, Randall J. Bernhardt, Marie A. Wolff, and Larry M. Mallis
pp 570 - 572; DOI:
10.1021/ic00003a044
PDF
A hydrogen-bonding mode in the ion association of the d-tartrate anion with the .LAMBDA.-ob3-tris(1R,2R)-diaminocyclohexane)cobalt(III) cation
Tsutomu Mizuta, Kazuo Toshitani, and Katsuhiko Miyoshi
pp 572 - 574; DOI:
10.1021/ic00003a045
PDF
The cubane structure of tetrakis(dimethylamine)tetraoxotetra-.mu.3-oxotetrakis(trimethylsiloxo)tetramolybdenum
Gyu Shik Kim, Douglas A. Keszler, and Carroll W. DeKock
pp 574 - 577; DOI:
10.1021/ic00003a046
PDF
Novel trimethylsilyl-substituted aminoboranes
K. J. L. Paciorek, S. R. Masuda, L. A. Hoferkamp, J. H. Nakahara, and R. H. Kratzer
pp 577 - 579; DOI:
10.1021/ic00003a047
PDF
Complex of a silyl ether with a dichloroaluminum alkoxide. Reaction of the bis(trimethylsilyl) ether of trans-1,2-cyclohexanediol with aluminum chloride
Vijay Sharma, Michel Simard, and James D. Wuest
pp 579 - 581; DOI:
10.1021/ic00003a048
PDF
On the rapid, monophasic reaction of the rabbit liver metallothionein .alpha.-domain with 5,5'-dithiobis (2-nitrobenzoic acid) (DTNB)
M. Meral Savas, David H. Petering, and C. Frank Shaw
pp 581 - 583; DOI:
10.1021/ic00003a049
PDF
Intercalation of 2,2'-bipyridine and complex formation in the interlayer space of montmorillonite by solid-solid reactions
Makoto Ogawa, Toshinobu Hashizume, Kazuyuki Kuroda, and Chuzo Kato
pp 584 - 585; DOI:
10.1021/ic00003a050
PDF
Synthesis and structure of trans-sec,rac-[MeCoL(H2O)](O3SCF3)2: L = 5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraaza-4,11-cyclotetradecadiene. Steric selectivity in alkyl radical-metal radical reactions
David J. Szalda, Carolyn L. Schwarz, and Carol Creutz
pp 586 - 588; DOI:
10.1021/ic00003a051
PDF
Barrier to internal rotation in a heterometallic tetrahedrane cluster. NMR evidence for metal cluster-aryl orbital overlap
P. Yuan, M. G. Richmond, and Martin Schwartz
pp 588 - 590; DOI:
10.1021/ic00003a052
PDF
Aerobic photooxidation of substituted benzenes catalyzed by the tungsten isopolyanion [W10O32]4-
Donato Attanasio, Lorenza Suber, and Klaus Thorslund
pp 590 - 592; DOI:
10.1021/ic00003a053
PDF
X-ray crystal structure and homonuclear phosphorus-31-phosphorus-31 .sigma./J-resolved NMR spectroscopic studies of tetrakis(1,8-diisocyanomenthane)bis(triphenylphosphine)diiridiumsilver(3+) tris(hexafluorophosphate). Observation of a statistical mixture of "head/tail" isomers [Erratum to document cited in CA114(6):54717e]
Andrew G. Sykes and Kent R. Mann
pp 592 - 592; DOI:
10.1021/ic00003a054
PDF
Synthesis, structure and physical properties of (μ-Oxo)(μ-carboxylato)bis{(tris(2-pyridylmethyl)amine)chromium(III)} complexes [Erratum to document cited in CA113(24):223417u]
B. G. Gafford, R. E. Marsh, W. P. Schaefer, J. H. Zhang, C. J. O'Connor, and R. A. Holwerda
pp 592 - 592; DOI:
10.1021/ic00003a055
PDF

Issue 4


An acidic .eta.2-dihydrogen complex protonating coordinated dinitrogen
Guochen Jia, Robert H. Morris, and Caroline T. Schweitzer
pp 593 - 594; DOI:
10.1021/ic00004a001
PDF
Molecular precursors for indium phosphide and synthesis of small III-V semiconductor clusters in solution
Trevor Douglas and Klaus H. Theopold
pp 594 - 596; DOI:
10.1021/ic00004a002
PDF
Concerning the dependence of the volume of activation for a limiting D substitution mechanism on the size of the leaving group. The aquation of pentacyano(amine)ferrate(II) complexes
K. Bal Reddy and R. Van Eldik
pp 596 - 598; DOI:
10.1021/ic00004a003
PDF
Metal to ligand charge-transfer photochemistry of metal-metal-bonded complexes. 8. Photochemistry of (pentacarbonylmanganese)tricarbonyl(.alpha.-diimine)manganese complexes. Coupling reactions of the radicals formed and x-ray structure of the photoproduct (CO)4Mn(.sigma.-N,.sigma.-N',.eta.2-CN-iso-Pr-PyCa)Mn(CO)3 (iso-Pr-PyCa = pyridine-2-carbaldehyde-N-isopropylimine).
Tim Van der Graaf, Derk J. Stufkens, Ad Oskam, and Kees Goubitz
pp 599 - 608; DOI:
10.1021/ic00004a004
PDF
Synthesis, molecular structure, and chemical behavior of hydrogen trans-bis(dimethyl sulfoxide)tetrachlororuthenate(III) and mer-trichlorotris(dimethyl sulfoxide)ruthenium(III): the first fully characterized chloride-dimethyl sulfoxide-ruthenium(III) complexes
Enzo Alessio, Gabriele Balducci, Mario Calligaris, Giacomo Costa, Wahib M. Attia, and Giovanni Mestroni
pp 609 - 618; DOI:
10.1021/ic00004a005
PDF
Inner-sphere electron-transfer stereoselectivities in the oxidation of bis(1,2-diaminoethane)cobalt(II) derivatives by tris(oxalato)cobaltate(3-)
Rosemary A. Marusak, Marie A. Ivanca, Kenneth J. Haller, and A. Graham Lappin
pp 618 - 623; DOI:
10.1021/ic00004a006
PDF
Nonaqueous, outer-sphere electron transfer: .DELTA.H.thermod., .DELTA.S.thermod., and .DELTA.V.thermod. for a O/2+ charge-type reaction
Kim A. Anderson and Scot Wherland
pp 624 - 629; DOI:
10.1021/ic00004a007
PDF
Electrocatalytic reduction of nitrite ion by edta complexes of iron(II) and ruthenium(II)
Matthew R. Rhodes, Mark H. Barley, and Thomas J. Meyer
pp 629 - 635; DOI:
10.1021/ic00004a008
PDF
Metal-ligand charge transfer spectra and carbon monoxide binding to iron(II) difluoro(dioximato)borate complexes in weak donor solvents
David W. Thompson and Dennis V. Stynes
pp 636 - 640; DOI:
10.1021/ic00004a009
PDF
Mononuclear and dinuclear osmium(II) compounds containing 2,2'-bipyridine and 3,5-bis(pyridin-2-yl)-1,2,4-triazole: synthesis, electrochemistry, absorption spectra, and luminescence properties
Francesco Barigelletti, Luisa De Cola, Vincenzo Balzani, Ronald Hage, Jaap G. Haasnoot, Jan Reedijk, and Johannes G. Vos
pp 641 - 645; DOI:
10.1021/ic00004a010
PDF
Theoretical studies of inorganic and organometallic reaction mechanisms. 2. The trans effect in square-planar platinum(II) and rhodium(I) substitution reactions
Zhenyang Lin and Michael B. Hall
pp 646 - 651; DOI:
10.1021/ic00004a011
PDF
Fast atom bombardment tandem mass spectrometry of (polypyridyl)ruthenium(II) complexes
Xiangqiu Liang, Somchai Suwanrumpha, and Royal B. Freas
pp 652 - 658; DOI:
10.1021/ic00004a012
PDF
Evidence for dissociative photosubstitution reactions of (acetonitrile)(bipyridine)(terpyridine)ruthenium(2+). Crystal and molecular structure of [Ru(trpy)(bpy)(py)](PF6)2.cntdot.(CH3)2CO
Clark R. Hecker, Phillip E. Fanwick, and David R. McMillin
pp 659 - 666; DOI:
10.1021/ic00004a013
PDF
Surface-attached [(NC)5Fe(CN)Pt(NH3)4(NC)Fe(CN)5]4-: a study in the electrochemical and photochemical control of surface morphology
Brian W. Pfennig and Andrew B. Bocarsly
pp 666 - 672; DOI:
10.1021/ic00004a014
PDF
Photoelectron spectroscopic studies of the electronic structure of .alpha.-silicon carbide
Stephen V. Didziulis, Jeffrey R. Lince, Paul D. Fleischauer, and Jory A. Yarmoff
pp 672 - 678; DOI:
10.1021/ic00004a015
PDF
Reorientational dynamics and the barrier to internal rotation in Cp2Co3(.mu.2-CO)(CO)3(.mu.3-CPh)
P. Yuan, M. G. Richmond, and Martin Schwartz
pp 679 - 683; DOI:
10.1021/ic00004a016
PDF
Spectroscopic and electrochemical studies of monomeric oxomolybdenum(V) complexes with five-membered chelate rings and alkoxo or alkanethiolato ligands
Chaung Sheng J. Chang and John H. Enemark
pp 683 - 688; DOI:
10.1021/ic00004a017
PDF
Technetium electrochemistry. 7. Electrochemical and spectroelectrochemical studies on technetium(III) and -(II) complexes containing polypyridyl ligands
Bruce E. Wilcox and Edward Deutsch
pp 688 - 693; DOI:
10.1021/ic00004a018
PDF
A new catalytic system for activation of molecular oxygen within the cavity of a dinuclear macrocyclic complex. Redox reaction of the (.mu.-mesoxalato)(.mu.-peroxo)dicobalt-BISDIEN complex
Ramunas J. Motekaitis and Arthur E. Martell
pp 694 - 700; DOI:
10.1021/ic00004a019
PDF
Stability and characterization of iron(III) and iron(II) heme peptides encapsulated in aqueous detergent micelles: proton NMR and UV-visible spectroscopic studies
Shyamalava Mazumdar, Okhil K. Medhi, and Samaresh Mitra
pp 700 - 705; DOI:
10.1021/ic00004a020
PDF
Catalase modeling with metalloporphyrin complexes having an oxygen ligand in a proximal position. Comparison with complexes containing a proximal nitrogen
Anne Robert, Bernard Loock, Michel Momenteau, and Bernard Meunier
pp 706 - 711; DOI:
10.1021/ic00004a021
PDF
Water-soluble ferric porphyrinates: solution and solid-state species.
Marie A. Ivanca, A. Graham Lappin, and W. Robert Scheidt
pp 711 - 718; DOI:
10.1021/ic00004a022
PDF
Preparations and properties of transition-metal pterin complexes. Models for the metal site in phenylalanine hydroxylase
Joanna Perkinson, Sharon Brodie, Keum Yoon, Karoline Mosny, Patrick J. Carroll, T. Vance Morgan, and Sharon J. Nieter Burgmayer
pp 719 - 727; DOI:
10.1021/ic00004a023
PDF
Synthesis and characterization of copper(II), nickel(II), and cobalt(II) binuclear complexes with a new tricyclic octadentate ligand, 1,5,8,12,15,19,22,26-octaazatricyclo[17.9.2.25,15]dotriacontane (tcoa): trapping of carbon dioxide in a neutral aqueous solution
Ichiro Murase, Gordana Vuckovic, Masahito Kodera, Hirotaka Harada, Naohide Matsumoto, and Sigeo Kida
pp 728 - 733; DOI:
10.1021/ic00004a024
PDF
Low-potential nickel(III,II) complexes: new systems based on tetradentate amidate-thiolate ligands and the influence of ligand structure on potentials in relation to the nickel site in [NiFe]-hydrogenases
H. J. Kruger, Gang Peng, and R. H. Holm
pp 734 - 742; DOI:
10.1021/ic00004a025
PDF
Heterometal cubane-type clusters: a rhenium-iron-sulfur (ReFe3S4) single-cubane cluster by cleavage of an iron-bridged double cubane and the site-voided cubane [Fe3S4] as a cluster ligand
Stefano Ciurli and R. H. Holm
pp 743 - 750; DOI:
10.1021/ic00004a026
PDF
Synthesis and characterization of tetrakis(perfluorophenoxo)tetrakis(trimethyl phosphine)dimolybdenum
F. A. Cotton and K. J. Wiesinger
pp 750 - 754; DOI:
10.1021/ic00004a027
PDF
Studies of the reactivity of binary thio- and tertiary oxothiomolybdates toward electrophiles. Reactions with dicarbomethoxyacetylene and the synthesis and structures of the [Et4N2[MoO(L)2], anti-[Et4N]2[Mo2O2S2(L)2]], syn-[Ph4P]2[Mo2O2S2(L)2].cntdot.2DMF, Ph4P]2[Mo(L)3]DMF.cntdot.C6H6, and [Ph4P]2[Mo2S2(L)4]2CH2Cl2 complexes (L = 1,2-dicarbomethoxy-1,2-ethylenedithiolate)
D. Coucouvanis, A. Hadjikyriacou, A. Toupadakis, Sang Man Koo, O. Ileperuma, M. Draganjac, and A. Salifoglou
pp 754 - 767; DOI:
10.1021/ic00004a028
PDF
Solution and solid-state conformational isomers of the molecular dihydrogen complex chloro(dihydrogen)tetrakis(methyldiphenylphosphine)rhenium: does it contain an asymmetric molecular dihydrogen ligand?
F. Albert Cotton and Rudy L. Luck
pp 767 - 774; DOI:
10.1021/ic00004a029
PDF
Studies on organometallic oxidants: structure, redox properties, and magnetism of tribromo- and triodo(cyclopentadienyl)vanadium
David B. Morse, Thomas B. Rauchfuss, and Scott R. Wilson
pp 775 - 778; DOI:
10.1021/ic00004a030
PDF
Synthesis and structures of rhodium isocyanide complexes containing an .eta.2-hydrotris(3,5-dimethylpyrazolyl)borate ligand
William D. Jones and Edward T. Hessell
pp 778 - 783; DOI:
10.1021/ic00004a031
PDF
Nitrogen-bonded triazole derivatives of boron: cyclotetrakis(triazolylboranes)
C. P. Brock, A. L. Companion, L. D. Kock, and Kurt Niedenzu
pp 784 - 789; DOI:
10.1021/ic00004a032
PDF
Novel synthesis of unusual classes of fluorocarbon organosulfur compounds using elemental fluorine as a reagent
Hsu Nan Huang, Richard J. Lagow, and Herbert Roesky
pp 789 - 794; DOI:
10.1021/ic00004a033
PDF
Hydrothermal crystallization of porphyrin-containing layer silicates
Kathleen A. Carrado, P. Thiyagarajan, R. E. Winans, and R. E. Botto
pp 794 - 799; DOI:
10.1021/ic00004a034
PDF
Desorption kinetics of 1:3 erbium cobalt intermetallic hydride
R. M. Donohue and Andrew J. Goudy
pp 800 - 802; DOI:
10.1021/ic00004a035
PDF
Thermally activated magnetic interactions in a one-dimensional semiconductor. Structural, charge-transport, and magnetic studies of bis[(tetramethylporphyrinato)copper] perrhenate
Ellen M. McGhee, Martin R. Godfrey, Brian M. Hoffman, and James A. Ibers
pp 803 - 808; DOI:
10.1021/ic00004a036
PDF
Isolation of unusual conformations of the [14]aneN4 aza crown ether: syntheses and molecular structures of [M(CH3)3]2[14]aneN4 (M = aluminum, gallium) and the group 13 heterobimetallic complex [Al(CH3)]2[14]aneN4[Ga(CH3)3]2
Gregory H. Robinson, William T. Pennington, Baosheng Lee, Mark F. Self, and Duane C. Hrncir
pp 809 - 812; DOI:
10.1021/ic00004a037
PDF
Cage opening of parent closo cage carboranes with fluoride ion: formation of 5-fluoro-hexahydro-nido-2,4-dicarbahexaborate(1-) ([5-F-nido-2,4-C2B4H6]-)
Harumi Tomita, Helen Luu, and Thomas Onak
pp 812 - 815; DOI:
10.1021/ic00004a038
PDF
Tetranuclear heterometallic complexes of the general types [M{(OH)2CrA4}3]5+ and [M{(OH)2CoA4}3]5+
Derek J. Hodgson, Kirsten Michelsen, Erik Pedersen, and Debra K. Towle
pp 815 - 822; DOI:
10.1021/ic00004a039
PDF
Identification of a novel tetragonally compressed six-coordinate copper(II) complex: preparation and characterization of a 3-chloroanilinium copper chloride complex, (3-chloroanilinium)8[CuCl6]Cl4
Denise A. Tucker, Peter S. White, Kathleen L. Trojan, Martin L. Kirk, and William E. Hatfield
pp 823 - 826; DOI:
10.1021/ic00004a040
PDF
Synthesis of dinuclear rhenium(VI) oxo-sulfido compounds
S. Cai, D. M. Hoffman, and D. A. Wierda
pp 827 - 831; DOI:
10.1021/ic00004a041
PDF
Hydrolytic polymerization of rhodium(III). 1. Preparation, solution studies, and x-ray structure of the doubly bridged dimer [(H2O)4Rh(.mu.-OH)2Rh(OH2)4](dmtos)4.cntdot.8H2O
Raoul Cervini, Gary D. Fallon, and Leone Spiccia
pp 831 - 836; DOI:
10.1021/ic00004a042
PDF
Photochemical generation of reactive transition-metal intermediates from air-stable precursors. Carbon-hydrogen bond activation via near-ultraviolet photolysis of Cp*Ir(L)(oxalate) and Cp*Ir(L)(N3)2 complexes
Daniel A. Freedman and Kent R. Mann
pp 836 - 840; DOI:
10.1021/ic00004a043
PDF
Dinuclear complexes of copper(II) derived from (1,3-propanediylbis(oxamato))cuprate(II): magneto-structural correlations
Joan Ribas, Auxiliadora Garcia, Ramon Costa, Montserrat Monfort, Santiago Alvarez, Claudia Zanchini, Xavier Solans, and Maria Victoria Domenech
pp 841 - 845; DOI:
10.1021/ic00004a044
PDF
Chemistry of iridium carbonyl cluster complexes. Synthesis and x-ray crystal structure determination of the [NMe3(CH2Ph)]3[Ir9(.mu.-CO)7(CO)13] complex containing a cofacial bioctahedral iridium cluster. Another example of different electron counting between isoskeletal rhodium and iridium carbonyl clusters
Roberto Della Pergola, Francesco Demartin, Luigi Garlaschelli, Mario Manassero, Secondo Martinengo, Norberto Masciocchi, and Donatella Strumolo
pp 846 - 849; DOI:
10.1021/ic00004a045
PDF
X-ray powder diffraction studies of alkalides and electrides that contain 15-crown-5
Sylvie Doeuff, Kuo Lih Tsai, and James L. Dye
pp 849 - 851; DOI:
10.1021/ic00004a046
PDF
Structure of disodium trans-bis(2,6-pyridinedicarboxylato-O,N)platinate(II) hexahydrate
A. M. Herring, L. Henling, J. A. Labinger, and J. E. Bercaw
pp 851 - 853; DOI:
10.1021/ic00004a047
PDF
NMR assignments of alkylcyclopentadienyl ligands in zirconium and platinum complexes
Richard A. Newmark, Larry D. Boardman, and Allen R. Siedle
pp 853 - 856; DOI:
10.1021/ic00004a048
PDF
A new tetranuclear chromium(III) complex with a [Cr4O2] core: synthesis, structure, and magnetic properties of [Cr4O2()2CCH3)7(bpy)2]PF6 (bpy = 2,2'-bipyridine)
Avi Bino, Ruthie Chayat, Erik Pedersen, and Andreas Schneider
pp 856 - 858; DOI:
10.1021/ic00004a049
PDF
Photoluminescence properties of chloro amine complexes of platinum(IV)
Konstantin P. Balashev, Jerald Simon, and Peter C. Ford
pp 859 - 861; DOI:
10.1021/ic00004a050
PDF
Reactions of heptahydridobis(triphenylphosphine)rhenium with 1-(diphenylphosphino)-2-(diphenylarsino)ethane (arphos) and 1,2-bis(diphenylarsino)ethane (dpae). Structural characterization of ReH5(PPh3)2(arphos-As) and ReH5(PPh3)2(dpae-As)
Michael T. Costello, Phillip E. Fanwick, Mark A. Green, and Richard A. Walton
pp 861 - 864; DOI:
10.1021/ic00004a051
PDF
Pressure-induced isomerization of a heterometallic rhodium-gold cluster compound: [Rh2(.mu.-Cl)2(CNC8H9)4(.mu.-AuPPh3)]2(PF6)2
Kevin L. Bray, Harry G. Drickamer, D. Michael P. Mingos, Michael J. Watson, and John R. Shapley
pp 864 - 866; DOI:
10.1021/ic00004a052
PDF
Tin(II) poly(1-pyrazolyl)borates
M. N. Hansen, Kurt Niedenzu, J. Serwatowska, J. Serwatowski, and K. R. Woodrum
pp 866 - 868; DOI:
10.1021/ic00004a053
PDF
Studies on transition-metal oxo and nitrido complexes. 12. Synthesis, spectroscopic properties, and reactions of stable ruthenium(V) and osmium(V) oxo complexes containing .alpha.-hydroxy carboxylate and .alpha.-amino carboxylate ligands
Andrew C. Dengel and William P. Griffith
pp 869 - 871; DOI:
10.1021/ic00004a054
PDF
Synthesis and characterization of octaacetonitriledimolybdenum(II) tetrafluoroborate
F. Albert Cotton and Kenneth J. Wiesinger
pp 871 - 873; DOI:
10.1021/ic00004a055
PDF
Identification and characterization of trinuclear molybdenum-sulfur clusters by fast atom bombardment (FAB) mass spectrometry
Kaspar Hegetschweiler, Thomas Keller, Walter Amrein, and Walter Schneider
pp 873 - 876; DOI:
10.1021/ic00004a056
PDF

Issue 5


Structure and properties of tridecakis(benzoato)heptaoxobis(pyridine)nonamanganese: a novel manganese (111) nonanuclear oxo-carboxylate species synthesized by employing an oxygen atom transfer agent
Donald W. Low, David M. Eichhorn, Alexandra Draganescu, and William H. Armstrong
pp 877 - 878; DOI:
10.1021/ic00005a001
PDF
A functional analogy between crown ethers and metallacrowns
Myoung Soo Lah and Vincent L. Pecoraro
pp 878 - 880; DOI:
10.1021/ic00005a002
PDF
Synthesis and characterization of labile spherosilicates: [(Me3SnO)8Si8O12] and [(Me4SbO)8Si8O12]
Frank J. Feher and Keith J. Weller
pp 880 - 882; DOI:
10.1021/ic00005a003
PDF
Electron transfer in inorganic nitrogen fixation
T. Adrian George and Bharat B. Kaul
pp 882 - 883; DOI:
10.1021/ic00005a004
PDF
Palladium-1-methylcytosine chemistry: N3 and N3,N4 metal binding to 1-methylcytosine and an unexpected trans .fwdarw. cis isomerization of two diamminepalladium(II) entities
Michael Krumm, Ilpo Mutikainen, and Bernhard Lippert
pp 884 - 890; DOI:
10.1021/ic00005a005
PDF
Interconversion of mononuclear and quadruply bonded dinuclear dibenzotetraaza[14]annulene complexes of molybdenum
Jean Marc Giraudon, Jean Sala-Pala, Jacques E. Guerchais, and Loic Toupet
pp 891 - 899; DOI:
10.1021/ic00005a006
PDF
Iron(III) coordination chemistry of linear dihydroxyserine compounds derived from enterobactin
Robert C. Scarrow, David J. Ecker, Chiu Ng, Sylvia Liu, and Kenneth N. Raymond
pp 900 - 906; DOI:
10.1021/ic00005a007
PDF
Solution equilibria of enterobactin and metal-enterobactin complexes
Lawrence D. Loomis and Kenneth N. Raymond
pp 906 - 911; DOI:
10.1021/ic00005a008
PDF
Photochemical reduction of nitrate and nitrite by manganese and iron porphyrins
Kenneth S. Suslick and Randall A. Watson
pp 912 - 919; DOI:
10.1021/ic00005a009
PDF
X-ray spectroscopic studies of nickel complexes, with application to the structure of nickel sites in hydrogenases
Gerard J. Colpas, Michael J. Maroney, Csaba Bagyinka, Manoj Kumar, William S. Willis, Steven L. Suib, Pradip K. Mascharak, and Narayan Baidya
pp 920 - 928; DOI:
10.1021/ic00005a010
PDF
Pentacoordinated nickel(II) complexes with thiolato ligation: synthetic strategy, structures, and properties
Narayan Baidya, Marilyn Olmstead, and Pradip K. Mascharak
pp 929 - 937; DOI:
10.1021/ic00005a011
PDF
Molecular mechanics analysis of the stereochemical factors influencing monofunctional and bifunctional binding of cis-diamminedichloroplatinum(II) to adenine and guanine nucleobases in the sequences d(GpApGpG).cntdot.d(CpCpTpC) and d(GpGpApG).cntdot.d(CpTpCpC) of A- and B-DNA
Trevor W. Hambley
pp 937 - 942; DOI:
10.1021/ic00005a012
PDF
Coordination of the sexidentate macrocycle 6,13-dimethyl-1,4,8,11-tetraazacyclotetradecane-6,13-diamine to iron(III)
Paul V. Bernhardt, Peter Comba, Trevor W. Hambley, and Geoffrey A. Lawrance
pp 942 - 946; DOI:
10.1021/ic00005a013
PDF
Magnetic interactions and single-ion zero-field-splitting effects in the two-sublattice manganese chain MnMn(EDTA).cntdot.9H2O: magnetism and single-crystal EPR spectra
J. J. Borras-Almenar, R. Burriel, Eugenio Coronado, D. Gatteschi, C. J. Gomez-Garcia, and C. Zanchini
pp 947 - 950; DOI:
10.1021/ic00005a014
PDF
Dynamic processes in the solid state. Proton relaxation studies and potential energy barrier calculations for (arene)M(CO)3 species. X-ray crystal structures of (1,2,3-C6H3Me3)Cr(CO)3 and (1,2,4,5-C6H2Me4)Cr(CO)3
Silvio Aime, Dario Braga, Roberto Gobetto, Fabrizia Grepioni, and Alessandra Orlandi
pp 951 - 956; DOI:
10.1021/ic00005a015
PDF
X-ray crystallographic studies of nickel(II) complexes of tetradentate [N2S2]2- ligands. 3. A stepwise distortion from square-planar to pseudotetrahedral geometries
Eric M. Martin, Robert D. Bereman, and Pirthu Singh
pp 957 - 962; DOI:
10.1021/ic00005a016
PDF
Synthesis and structure of the novel chain compound niobium iodide sulfide (Nb6I9S) and its hydride
H. Juergen Meyer and John D. Corbett
pp 963 - 967; DOI:
10.1021/ic00005a017
PDF
Coordination chemistry of higher oxidation states. 37. Tellurato complexes of palladium(IV) and platinum(IV). Crystal structures of Na8K2H4[Pd2Te4O24H2].cntdot.20H2O and K6Na2[Pt(OH)2(HTeO6)2].cntdot.12H2O
William Levason, Mark D. Spicer, and Michael Webster
pp 967 - 971; DOI:
10.1021/ic00005a018
PDF
A new type of mixed-ligand complex with nitroxyl radicals
A. B. Burdukov, V. I. Ovcharenko, V. N. Ikorski, N. V. Pervukhina, N. V. Podberezskaya, I. A. Grigor'ev, S. V. Larionov, and L. B. Volodarskii
pp 972 - 976; DOI:
10.1021/ic00005a019
PDF
Disubstituted tungstosilicates. 2. .gamma.- and .beta.-isomers of tungstovanadosilicate, [SiV2W10O40]6-: syntheses and structure determinations by tungsten-183, vanadium-51 and silicon-29 NMR spectroscopy
Jacqueline Canny, Rene Thouvenot, Andre Teze, Gilbert Herve, Michele Leparulo-Loftus, and Michael T. Pope
pp 976 - 981; DOI:
10.1021/ic00005a020
PDF
Crystallographic and aluminum-27 NMR study on premelting phenomena in crystals of sodium tetrachloroaluminate
Bernt Krebs, Horst Greiwing, Claus Brendel, Francis Taulelle, Marcelle Gaune-Escard, and Rolf W. Berg
pp 981 - 988; DOI:
10.1021/ic00005a021
PDF
Heterobimetallic gold-palladium cluster complexes. X-ray crystal and molecular structures of [(CO)Pd(AuPPh3)8](NO3)2 and [(P(OCH3)3)Pd(AuPPh3)6(AuP(OCH3)3)2](NO3)2
Larry N. Ito, Anna Maria P. Felicissimo, and Louis H. Pignolet
pp 988 - 994; DOI:
10.1021/ic00005a022
PDF
Synthesis, structure, and pyrolysis of organoaluminum amides derived from the reactions of trialkylaluminum compounds with ethylenediamine in a 3:2 ratio
Zhiping Jiang, Leonard V. Interrante, Daekeun Kwon, Fook S. Tham, and Rudolph Kullnig
pp 995 - 1000; DOI:
10.1021/ic00005a023
PDF
Hydrochalcogenide and hydride hydrochalcogenide derivatives of rhodium
Massimo Di Vaira, Maurizio Peruzzini, and Piero Stoppioni
pp 1001 - 1007; DOI:
10.1021/ic00005a024
PDF
Cluster synthesis. 30. New platinum-osmium carbonyl cluster complexes from the reaction of Os3(CO)10(NCMe)2 with bis(cyclooctadiene)platinum
Richard D. Adams, Gong Chen, Jau Ching Lii, and Wengan Wu
pp 1007 - 1013; DOI:
10.1021/ic00005a025
PDF
Osmium(VI)-dioxo complexes derived from .beta.-diketone Schiff bases and their reactivity with arene- and alkanethiols. Synthesis, characterization, structures, and electrochemical data
W. E. Lynch, R. L. Lintvedt, and X. Q. Shui
pp 1014 - 1019; DOI:
10.1021/ic00005a026
PDF
Crystal and molecular structure of hexakis(tert-butoxo)dialuminum. Comments on the extent of M-O .pi. bonding in Group 6 and Group 13 alkoxides
Roger H. Cayton, Malcolm H. Chisholm, Ernest R. Davidson, Vincent F. DiStasi, Ping Du, and John C. Huffman
pp 1020 - 1024; DOI:
10.1021/ic00005a027
PDF
Site-selective oxygen exchange and substitution of organometallic groups in an amphiphilic quadruple-cubane-type cluster. Synthesis and molecular structure of [(MCp*)4V6O19] (M = rhodium, iridium)
Yoshihito Hayashi, Yoshiki Ozawa, and Kiyoshi Isobe
pp 1025 - 1033; DOI:
10.1021/ic00005a028
PDF
Control of intramolecular electron transfer by a chemical reaction. The 4,4'-azopyridine/1,2-bis(4-pyridyl)hydrazine system
Jean Pierre Launay, Myriam Tourrel-Pagis, Jean Francois Lipskier, Valerie Marvaud, and Christian Joachim
pp 1033 - 1038; DOI:
10.1021/ic00005a029
PDF
Electron transfer. 107. The chromium(VI)-uranium(IV) reaction: parallel one- and two-electron paths
M. C. Ghosh, E. Gelerinter, and E. S. Gould
pp 1039 - 1042; DOI:
10.1021/ic00005a030
PDF
Electron transfer. 108. Reductions of pyridinecarboxylic acids with vitamin B12s (Cob(I)alamin)
S. K. Ghosh, P. N. Balasubramanian, G. Chithambarathanu Pillai, M. C. Ghosh, and E. S. Gould
pp 1043 - 1045; DOI:
10.1021/ic00005a031
PDF
Boron analogs of valine, leucine, isoleucine, and phenylalanine: syntheses of amine-alkyl(N-ethylcarbamoyl)boranes
Wyatt J. Mills, Christopher H. Sutton, Mark W. Baize, and Lee J. Todd
pp 1046 - 1052; DOI:
10.1021/ic00005a032
PDF
Pentacoordinated molecules. 84. Conformational effects of ring fusion and heteroatom substitution in six-membered rings of spirocyclic oxyphosphoranes
Robert R. Holmes, K. C. Kumara Swamy, Joan M. Holmes, and Roberta O. Day
pp 1052 - 1062; DOI:
10.1021/ic00005a033
PDF
MNDO calculations on borazine derivatives. 2. Substitution of two [HNBH] fragments for two [HCCH] fragments in benzene to form the diazadiborines and the novel open structure of the 1,2,4,5-isomer
Scott T. Massey and Robert W. Zoellner
pp 1063 - 1066; DOI:
10.1021/ic00005a034
PDF
Ab initio calculation of harmonic force fields and vibrational spectra of the fluoroarsines AsHnF3-n (n = 0-3) and the fluoroarsoranes AsHnF5-n (n = 0-5)
Juergen Breidung, Walter Thiel, and Andrew Komornicki
pp 1067 - 1073; DOI:
10.1021/ic00005a035
PDF
Complexation, luminescence, and energy transfer of cerium(3+) with a series of multidentate aminophosphonic acids in aqueous solution
Steven T. Frey and William D. Horrocks
pp 1073 - 1079; DOI:
10.1021/ic00005a036
PDF
Nature of metal-metal interactions in systems with bridging ligands. 1. Electronic structure and bonding in octacarbonyldicobalt
Arthur A. Low, Kathryn L. Kunze, P. J. MacDougall, and Michael B. Hall
pp 1079 - 1086; DOI:
10.1021/ic00005a037
PDF
Electronic structure of a (cyclopentadienyl)tri-.mu.-oxoditechnetium polymer with a very short metal-metal bond
A. W. Edith Chan, Roald Hoffmann, and Santiago Alvarez
pp 1086 - 1093; DOI:
10.1021/ic00005a038
PDF
Time-resolved resonance Raman study of the .sigma..sigma.* excited state of octachlorodirhenate(2-) and octabromodirhenate(2-)
Jon R. Schoonover, Richard F. Dallinger, Patrick M. Killough, Alfred P. Sattelberger, and William H. Woodruff
pp 1093 - 1098; DOI:
10.1021/ic00005a039
PDF
A high-pressure micro-Raman study of crystalline tricarbonyl(.eta.5-cyclopentadienyl)rhenium(I), (.eta.5-C5H5)Re(CO)3
Yining Huang, Ian S. Butler, and Denis F. R. Gilson
pp 1098 - 1102; DOI:
10.1021/ic00005a040
PDF
Phosphorus-31 solid-state NMR studies of cyclic and acyclic phosphine-metal complexes. Determination of chemical shift anisotropy, scalar coupling 1JM-P (M = manganese-55, molybdenum-95/97, tungsten-183), and 55Mn quadrupolar coupling constants
Ekkehard Lindner, Riad Fawzi, Hermann August Mayer, Klaus Eichele, and Klaus Pohmer
pp 1102 - 1107; DOI:
10.1021/ic00005a041
PDF
The transient radical tris(dimethylphenylphosphine)trihydridoiridium(1+): a Bronsted acid
D. Eric Westerberg, Larry F. Rhodes, Joseph Edwin, William E. Geiger, and Kenneth G. Caulton
pp 1107 - 1112; DOI:
10.1021/ic00005a042
PDF
High-pressure NMR kinetics. 47. Solvent-exchange mechanisms of nonaqueous square-planar tetrasolvates: a high-pressure proton NMR investigation
Noel Hallinan, Valerie Besancon, Marc Forster, Gilles Elbaze, Yves Ducommun, and Andre E. Merbach
pp 1112 - 1114; DOI:
10.1021/ic00005a043
PDF
Ligand dynamics in pentacoordinate copper(I) and zinc(II) complexes
DeAnna K. Coggin, Jorge A. Gonzalez, Alan M. Kook, David M. Stanbury, and Lon J. Wilson
pp 1115 - 1125; DOI:
10.1021/ic00005a044
PDF
Electron self-exchange study of the coordination-number-invariant pentacoordinate copper(I/II) couple [CuI,II((5-meimidh)2DAP)]+/2+
DeAnna K. Coggin, Jorge A. Gonzalez, Alan M. Kook, Carmen Bergman, Theodore D. Brennan, W. Robert Scheidt, David M. Stanbury, and Lon J. Wilson
pp 1125 - 1134; DOI:
10.1021/ic00005a045
PDF
Oxidative homolysis of organochromium macrocycles
Carl R. Steffan, James H. Espenson, and Andreja Bakac
pp 1134 - 1137; DOI:
10.1021/ic00005a046
PDF
Further studies on the role of neighboring group participation in carbonyl substitution reactions of group 6 metal carboxylates
Donald J. Darensbourg, Jennifer A. Joyce, Christopher J. Bischoff, and Joseph H. Reibenspies
pp 1137 - 1142; DOI:
10.1021/ic00005a047
PDF
Formation of a terminal aryl-imido compound of titanium by cleavage of the nitrogen nitrogen double bond in benzo[c]cinnoline
John E. Hill, Phillip E. Fanwick, and Ian P. Rothwell
pp 1143 - 1144; DOI:
10.1021/ic00005a048
PDF
Water-soluble organometallic compounds. 1. The synthesis, characterization, and x-ray structure of (kryptofix-221)sodium pentacarbonyl[tris(m-sulfonatophenyl)phosphine]tungstate(3-)
Donald J. Darensbourg, Christopher J. Bischoff, and Joseph H. Reibenspies
pp 1144 - 1147; DOI:
10.1021/ic00005a049
PDF
Reaction enthalpies of atom transfer to electronically excited tetrakis(pyrophosphito)diplatinate(II)
Michael S. Herman and Joshua L. Goodman
pp 1147 - 1149; DOI:
10.1021/ic00005a050
PDF
Electrochemical reduction of dioxygen in room-temperature imidazolium chloride-aluminum chloride molten salts
Michael T. Carter, Charles L. Hussey, Sandra K. D. Strubinger, and Robert A. Osteryoung
pp 1149 - 1151; DOI:
10.1021/ic00005a051
PDF
Heme rotational isomerism is not required for the production of Q-band splitting in the spectra of iron-porphyrin proteins
Thomas J. DiFeo and Anthony W. Addison
pp 1151 - 1153; DOI:
10.1021/ic00005a052
PDF
Physical properties of a manganese tetramer with all-oxygen coordination
H. Holden Thorp, Joseph E. Sarneski, Robert J. Kulawiec, Gary W. Brudvig, Robert H. Crabtree, and G. C. Papaefthymiou
pp 1153 - 1155; DOI:
10.1021/ic00005a053
PDF
Synthesis and characterization of a dimeric molybdenum(V) anion [Br2OMo(.mu.-S)2MoOBr2]2-; conversion of tetrahydrofuran to [nBu3P(CH2)4PnBu3]2+
F. Albert Cotton, Rudy L. Luck, and Charla S. Miertschin
pp 1155 - 1157; DOI:
10.1021/ic00005a054
PDF
First catalytic sulfur atom transfer reaction by a novel (.mu.-persulfido)ruthenium(IV) complex, [(Edta-H)RuIV]2S22-
M. M. Taqui Khan and M. Rafiq H. Siddiqui
pp 1157 - 1159; DOI:
10.1021/ic00005a055
PDF
Insertion reaction of acetone-d6 into the osmium-hydrogen bond of [OsHCl(CO)(P-iso-Pr3)2]: experimental evidence for the hydrogen-transfer mechanism from alcohols to ketones
Miguel A. Esteruelas, Cristina Valero, Luis A. Oro, Uwe Meyer, and Helmut Werner
pp 1159 - 1160; DOI:
10.1021/ic00005a056
PDF

Issue 6


X-ray crystal structure and reactivity of an N-phosphonio-substituted nitrilimine: a stable electrophilic nitrilimine
Michel Granier, Antoine Baceiredo, Volker Huch, Michel Veith, and Guy Bertrand
pp 1161 - 1162; DOI:
10.1021/ic00006a001
PDF
Oxidation by elemental sulfur and coupling of iron/sulfur complexes. Synthesis and structural characterization of tetrakis(tetraethylammonium) tetrakis(ethanethiolato)hexasulfidotetraferrate, a new Fe/S cluster with a linear Fe4 backbone
S. A. Al-Ahmad, J. W. Kampf, R. W. Dunham, and D. Coucouvanis
pp 1163 - 1164; DOI:
10.1021/ic00006a002
PDF
Synthesis and characterization of alkaline-earth-metal .beta.-diketonate complexes used as precursors for chemical vapor deposition of thin film superconductors
S. B. Turnipseed, R. M. Barkley, and R. E. Sievers
pp 1164 - 1170; DOI:
10.1021/ic00006a003
PDF
Chemistry and catalytic properties of ruthenium and osmium complexes. 6. Synthesis and reactivity of [RuH(CO)(NCMe)2(PPh3)2][BF4], including the catalytic hydroformylation of hex-1-ene
Roberto A. Sanchez-Delgado, Merlin Rosales, and Antida Andriollo
pp 1170 - 1173; DOI:
10.1021/ic00006a004
PDF
Dialkylamino phosphorus metal carbonyls. 9. Acylation rather than Wittig olefination in reactions of the phosphorus-bridging carbonyl derivative (iso-Pr2NP)2COFe2(CO)6 with phosphonium methylides
R. B. King, N. K. Bhattacharyya, and E. M. Holt
pp 1174 - 1178; DOI:
10.1021/ic00006a005
PDF
Capping considerations in main-group/transition-metal clusters: synthetic, structural, and theoretical discussions of [E2Co4(CO)10(.mu.-CO)-/2- (E = Sb, Bi)
Thomas A. Albright, Kyeong Ae Yee, Jean Yves Saillard, Samia Kahlal, Jean Francois Halet, J. S. Leigh, and Kenton H. Whitmire
pp 1179 - 1190; DOI:
10.1021/ic00006a006
PDF
Preparation and redox chemistry of novel carbonato-bridged cobalt(II) complexes with 1,4,8,11-tetrakis(2-aminoethyl)-1,4,8,11-tetraazacyclotetradecane and 1,4,8,11-tetrakis(pyridylmethyl)-1,4,8,11-tetraazacyclotetradecane
Hirotaka Harada, Masahito Kodera, Gordana Vuckovic, Naohide Matsumoto, and Sigeo Kida
pp 1190 - 1194; DOI:
10.1021/ic00006a007
PDF
Synthesis and NMR investigation of dirhodium(4+) formamidinate complexes containing 2-(diphenylphosphino)pyridine as a bridging ligand. X-ray crystal structure of the complex Rh2(form)2(.mu.-PPh2Py)2(O2CCF3)2 (form = N,N'-di-p-tolylformamidinate)
Enrico Rotondo, Giuseppe Bruno, Francesco Nicolo, Sandra Lo Schiavo, and Pasquale Piraino
pp 1195 - 1200; DOI:
10.1021/ic00006a008
PDF
Synthesis and reactivity of carbonylbis(triphenylphosphine)rhodium(I) complexes of water and weakly coordinating anions
Daniel M. Branan, Norris W. Hoffman, E. Andrew McElroy, Nicholas Prokopuk, Anna B. Salazar, Martha J. Robbins, W. E. Hill, and Thomas R. Webb
pp 1200 - 1207; DOI:
10.1021/ic00006a009
PDF
Structural features of silver(I) and copper(I) bis(thiophene-2-carbaldehyde imine) trifluoromethanesulfonate complexes in the solid state and in solution: crystal structures of [Ag{Th-2-CH:N-(S)-CHMePh}2](O3SCF3) and [Cu{5-Me-Th-2-CH:N-iso-Pr}2](O3SCF3) and a proton, fluorine-19 and silver-109 NMR study
Johan F. Modder, Jan Meine Ernsting, Kees Vrieze, Martin De Wit, Caspar H. Stam, and Gerard Van Koten
pp 1208 - 1214; DOI:
10.1021/ic00006a010
PDF
Synthesis of oxometals from carbonylmetal complexes by oxidative decarbonylation with dioxirane
S. Wolowiec and J. K. Kochi
pp 1215 - 1221; DOI:
10.1021/ic00006a011
PDF
Synthesis and structure of seven-coordinate rhenium(III) mixed halo-phosphine isocyanide complexes
Steve Warner, Linda K. Cheatham, Thomas H. Tulip, Ian D. Williams, and Stephen J. Lippard
pp 1221 - 1226; DOI:
10.1021/ic00006a012
PDF
Mixed carboxylate-bis(dimethylphosphino)methane complexes of dirhenium(II,II) and -(III,II)
Irene Ara, Phillip E. Fanwick, and Richard A. Walton
pp 1227 - 1230; DOI:
10.1021/ic00006a013
PDF
Models for the binding site in bromoperoxidase: mononuclear vanadium(V) phenolate complexes of the hydridotris(3,5-dimethylpyrazolyl)borate ligand
Stephen Holmes and Carl J. Carrano
pp 1231 - 1235; DOI:
10.1021/ic00006a014
PDF
Reaction of symmetrically and asymmetrically substituted derivatives of cisplatin with r(ApG). Influence of the nonleaving groups on structures and kinetics
Maarten Alink, Hideaki Nakahara, Takayoshi Hirano, Kenji Inagaki, Mamoru Nakanishi, Yoshinori Kidani, and Jan Reedijk
pp 1236 - 1241; DOI:
10.1021/ic00006a015
PDF
Electrochemical properties of copper(II)/copper(I)-macrocyclic polythia ether complexes: determination of formal potential values and cyclic voltammetric behavior
M. Margarida Bernardo, Ronald R. Schroeder, and D. B. Rorabacher
pp 1241 - 1247; DOI:
10.1021/ic00006a016
PDF
Substituent effects in the protonation and complexation with copper(II) ions of organic monophosphate esters. A potentiometric and calorimetric study
Ulrike Kramer-Schnabel and Peter W. Linder
pp 1248 - 1254; DOI:
10.1021/ic00006a017
PDF
Photoredox and photocatalytic characteristics of various iron meso-tetraarylporphyrins
Carlo Bartocci, Andrea Maldotti, Graziano Varani, Pierrette Battioni, Vittorio Carassiti, and Daniel Mansuy
pp 1255 - 1259; DOI:
10.1021/ic00006a018
PDF
Modulation of valence orbital levels of metalloporphyrins by .beta.-substitution: evidence from spectroscopic and electrochemical studies of 2-substituted metallo-5,10,15,20-tetraphenylporphyrins
Robert A. Binstead, Maxwell J. Crossley, and Noel S. Hush
pp 1259 - 1264; DOI:
10.1021/ic00006a019
PDF
Synthesis of nonionic gadolinium chelates useful as contrast agents for magnetic resonance imaging: 1,4,7-tris(carboxymethyl)-10-substituted-1,4,7,10-tetraazacyclododecanes and their corresponding gadolinium chelates
D. D. Dischino, E. J. Delaney, J. E. Emswiler, G. T. Gaughan, J. S. Prasad, S. K. Srivastava, and M. F. Tweedle
pp 1265 - 1269; DOI:
10.1021/ic00006a020
PDF
Thermodynamic and kinetic studies of lanthanide complexes of 1,4,7,10,13-pentaazacyclopentadecane-N,N',N'',N''',N''''-pentaacetic acid and 1,4,7,10,13,16-hexaazacyclooctadecane-N,N',N'',N''',N'''',N'''''-hexaacetic acid
Mutsuo Kodama, Tohru Koike, Anung Budhi Mahatma, and Eiichi Kimura
pp 1270 - 1273; DOI:
10.1021/ic00006a021
PDF
Reactivity of molecules containing element-element bonds. 2. Transition elements
Fausto Calderazzo, Alberto Juris, Rinaldo Poli, and Fausto Ungari
pp 1274 - 1279; DOI:
10.1021/ic00006a022
PDF
Kinetics and mechanisms of the reaction of oxalacetic acid with (H2O)5CrCH2CN2+
M. J. Sisley and Robert B. Jordan
pp 1279 - 1284; DOI:
10.1021/ic00006a023
PDF
Electrochemistry and infrared spectroelectrochemistry of [(.eta.5-C5R5)Fe(CO)2]2 (R = H, Me): generation and characterization of [(.eta.5-C5R5)Fe(CO)2]2(PF6) complexes
John P. Bullock, Michael C. Palazotto, and Kent R. Mann
pp 1284 - 1293; DOI:
10.1021/ic00006a024
PDF
Kinetic behavior of diazene in aqueous solution
David M. Stanbury
pp 1293 - 1296; DOI:
10.1021/ic00006a025
PDF
Palladium(II) and platinum(II) complexes with 1,5-dithiacyclooctane (dtco): structures of [Pd(dtco)Cl2] and [Pd(dtco)2](NO3)2 and kinetics of ligand substitution in [Pd(dtco)2]2+ by bidentate ligands
Christoph Drexler, Helmut Paulus, and Horst Elias
pp 1297 - 1302; DOI:
10.1021/ic00006a026
PDF
Ligation-induced changes in metal-metal bonding in luminescent binuclear complexes containing gold(I) and iridium(I)
Alan L. Balch and Vincent J. Catalano
pp 1302 - 1308; DOI:
10.1021/ic00006a027
PDF
Analysis of a siroheme model compound: core-size dependence of resonance Raman bands and the siroheme spin state in sulfite reductase
Dan Melamed, Eric P. Sullivan, Jr., Kristine Prendergast, Steven H. Strauss, and Thomas G. Spiro
pp 1308 - 1319; DOI:
10.1021/ic00006a028
PDF
Redox reactions of mixed-valence complexes: kinetic and thermodynamic considerations in the (.mu.-pyrazine)((ethylenediaminetetraacetato)ruthenato)pentaammineruthenium RuIIRuII, RuII, RuIII, and RuIII,RuIII systems
M. S. Ram and Albert Haim
pp 1319 - 1325; DOI:
10.1021/ic00006a029
PDF
The first phosphorus closo complex of the dicarborane systems: synthesis and characterization of 1-(2,4,6-tri-tert-butylphenyl)-2,3-bis(trimethylsilyl)-2,3-dicarba-1-phospha-closo-heptaborane
Narayan S. Hosmane, Kai Juan Lu, Alan H. Cowley, and Miguel A. Mardones
pp 1325 - 1327; DOI:
10.1021/ic00006a030
PDF
Synthesis of K4M3Te17 (M = zirconium, hafnium) and the structure of potassium hafnium telluride, K4Hf3Te17, a new one-dimensional solid-state ternary polytelluride
Patricia M. Keane and James A. Ibers
pp 1327 - 1329; DOI:
10.1021/ic00006a031
PDF
Toward stabilizing rectangular-pyramidal geometries in non-metals: polycyclic phosphorus esters
R. V. Davis, D. J. Wintergrass, M. N. Janakiraman, E. M. Hyatt, R. A. Jacobson, L. M. Daniels, A. Wroblewski, J. Padmakumari Amma, S. K. Das, and J. G. Verkade
pp 1330 - 1341; DOI:
10.1021/ic00006a032
PDF
Synthesis and characterization of heterobimetallic complexes with bridging acyl groups: (CO)4Fe(.mu.-C(R)O)M(CO)4 (R = Ph, Me; M = Re, Mn)
Daqiang Xu, Herbert D. Kaesz, and Saeed I. Khan
pp 1341 - 1344; DOI:
10.1021/ic00006a033
PDF
Complexes of the lanthanide(III) ions with an aromatic six-nitrogen-donor macrocyclic ligand
F. Benetollo, G. Bombieri, K. K. Fonda, A. Polo, J. R. Quagliano, and L. M. Vallarino
pp 1345 - 1353; DOI:
10.1021/ic00006a034
PDF
Unusual reversible dimerization of a .mu.-pyridine-2-thiolato (pyS) complex: crystal structure of Pd2(.mu.-N-S-.eta.2-pyS)2Cl2(PMe3)2
John H. Yamamoto, Wesley Yoshida, and Craig M. Jensen
pp 1353 - 1357; DOI:
10.1021/ic00006a035
PDF
Synthesis and characterization of dinuclear copper(II) complexes of the dinucleating ligand 2,6-bis[(bis((1-methylimidazol-2-yl)methyl)amino)methyl]-4-methylphenol
Kenneth J. Oberhausen, John F. Richardson, Robert M. Buchanan, James K. McCusker, David N. Hendrickson, and Jean Marc Latour
pp 1357 - 1365; DOI:
10.1021/ic00006a036
PDF
Synthesis of 3- and 4-coordinate coinage metal [ML3][X], [MXL3], and [ML4][X] complexes: crystal structures of [Cu{P(p-C6H4OCMe)3}3][ClO4] and [Cu{Sb(p-C6H4F)3}4][BF4]
Anthony Baiada, Fred H. Jardine, Roger D. Willett, and Kenneth Emerson
pp 1365 - 1370; DOI:
10.1021/ic00006a037
PDF
Gas-phase molecular structure of (.eta.5-cyclopentadienyl)tris(tetrahydroborato)zirconium: electron-diffraction and EHMO study
Attila G. Csaszar, Lise Hedberg, Kenneth Hedberg, Robert C. Burns, Alex T. Wen, and Michael J. McGlinchey
pp 1371 - 1376; DOI:
10.1021/ic00006a038
PDF
Phase transitions in cesium 7,8-dicarbaundecaborate(12): a new one-dimensional cesium solid electrolyte at 210 .degree.C
Jordi Rius, Antonio Romerosa, Francesc Teixidor, Jaume Casabo, and Carles Miravitlles
pp 1376 - 1379; DOI:
10.1021/ic00006a039
PDF
Polymetallic chromium alkoxides: synthesis and crystal structures of (iso-PrO)8Cr2Na4(THF)4 and (.mu.3-OPh)10Cr4(.mu.3-O)3Na4(TMEDA)4
Jilles J. H. Edema, Sandro Gambarotta, Wilberth J. J. Smeets, and Anthony L. Spek
pp 1380 - 1384; DOI:
10.1021/ic00006a040
PDF
Synthesis, separation, and equilibrium characterization of racemic and meso forms of a new multidentate ligand: N,N'-trimethylenebis[2-(2-hydroxy-3,5-dimethylphenyl)glycine], TMPHPG
Christopher J. Bannochie and Arthur E. Martell
pp 1385 - 1392; DOI:
10.1021/ic00006a041
PDF
Synthesis and structure of the norbornene adduct of 1,3,5,2,4,6-trithiatriazinium tetrachloroaluminate [C7H10.cntdot.S3N3][AlCl4]
Allen Apblett, Tristram Chivers, A. Wallace Cordes, and Rainer Vollmerhaus
pp 1392 - 1396; DOI:
10.1021/ic00006a042
PDF
Dioxygen adducts of nickel(II) and cobalt(II) dioxopentaazamacrocyclic complexes: kinetics, stabilities, and hydroxylation of the ligands in the nickel dioxygen complexes
Dian Chen, Ramunas J. Motekaitis, and Arthur E. Martell
pp 1396 - 1402; DOI:
10.1021/ic00006a043
PDF
Polyazamacrocycles. 9. Characterization of diastereoisomeric trans-[Co(Me8[14]ane)Cl2]+ complexes
Ramesh Bembi, Michael G. B. Drew, Randhir Singh, and Tapashi G. Roy
pp 1403 - 1406; DOI:
10.1021/ic00006a044
PDF
Diastereoselective synthesis of the bis(phosphinoenolato)nickel(II) complex cis-{Ni[Ph2PCH:C(O)Fe(.eta.-C5H5)(CO)(PPh3)]2} derived from (.eta.-C5H5)Fe(CO)(PPh3)C(O)CH2PPh2, and the corresponding crystal structures
Pietro Berno, Pierre Braunstein, Carlo Floriani, Angiola Chiesi-Villa, and Carlo Guastini
pp 1407 - 1410; DOI:
10.1021/ic00006a045
PDF
Influence of hydrogen bonding on the molecular geometry and solution-state NMR properties of tetramethylpiperidinium dichlorotrimethylstannate
Stephen E. Johnson, Kurt Polborn, and Heinrich Noeth
pp 1410 - 1412; DOI:
10.1021/ic00006a046
PDF
Intramolecular entropy changes for transition-metal complex redox couples: hexaamine ruthenium(III/II) and -cobalt(III/II) couples
David E. Richardson and Paul Sharpe
pp 1412 - 1414; DOI:
10.1021/ic00006a047
PDF
X-ray diffraction study of pentacarbonyl(.mu.-hydrido)(nonacarbonyldimanganese)rhenium, HMn2Re(CO)14
Alberto Albinati, R. Morris Bullock, Brian J. Rappoli, and Thomas F. Koetzle
pp 1414 - 1417; DOI:
10.1021/ic00006a048
PDF
Kinetic studies of triphenylphosphine substitution of sulfur-coordinated thiophenes in Cp'(CO)2Re(Th): a model for thiophene adsorption onto hydrodesulfurization catalysts
Moon Gun Choi and Robert J. Angelici
pp 1417 - 1419; DOI:
10.1021/ic00006a049
PDF
Crystallographic study of the stretching of the copper-nitrogen bond in the complex of a large-cavity reinforced macrocycle
Gary Pattrick and Robert D. Hancock
pp 1419 - 1422; DOI:
10.1021/ic00006a050
PDF
Are internal flips of M-M multiple bonds within cubic or octahedral ligand fields symmetry allowed?
Roger H. Cayton and Malcolm H. Chisholm
pp 1422 - 1425; DOI:
10.1021/ic00006a051
PDF
Synthesis and characterization of the mixed-valence [molybdenum] complex LMoVOCl(.mu.-O)MoVIO2L (L = hydrotris(3,5-dimethyl-1-pyrazolyl)borate)
Aston A. Eagle, Maureen F. Mackay, and Charles G. Young
pp 1425 - 1428; DOI:
10.1021/ic00006a052
PDF
New hexaaza macrocyclic binucleating ligands. Oxygen insertion with a dicopper(I) Schiff base macrocyclic complex [Erratum to document cited in CA113(24):223409t]
Rached Menif, Arthur E. Martell, Philip J. Squattrito, and Abraham Clearfield
pp 1428 - 1428; DOI:
10.1021/ic00006a053
PDF

Issue 7


Thermodynamics of multielectron transfer: variable-temperature UV-vis and IR spectroelectrochemical studies of the disproportionation of d7-d8 binuclear rhodium complexes
Michael G. Hill and Kent R. Mann
pp 1429 - 1431; DOI:
10.1021/ic00007a001
PDF
[Na9Fe20Se38]9-: a [sodium-iron-selenium] high-nuclearity bicyclic cluster constructed by the fusion of Fe2Se2 rhombs
Jing Feng You and R. H. Holm
pp 1431 - 1433; DOI:
10.1021/ic00007a002
PDF
Shape-selective intercalation reactions of layered zinc and cobalt phosphonates
Guang Cao and Thomas E. Mallouk
pp 1434 - 1438; DOI:
10.1021/ic00007a003
PDF
Intercalation of ammonia into zinc and cobalt phenylphosphonates
Karen J. Frink, Ren Chain Wang, Jorge L. Colon, and A. Clearfield
pp 1438 - 1441; DOI:
10.1021/ic00007a004
PDF
Inclusion of a small molecule in a big cage: preparation and structure of catena-[catena-(.alpha.,.omega.-diaminooctane)cadmium-.mu.-tetracyanonickelate]-toluene(1/1)
Tai Hasegawa, Stefan Franzen, David Lambright, Dennis H. Oh, Sriram Balasubramanian, Britt Hedman, and Keith O. Hodgson
pp 1441 - 1444; DOI:
10.1021/ic00007a005
PDF
Macrocycle complexation chemistry. 35. Survey of the complexation of the open chain 15-crown-5 analog tetraethylene glycol with the lanthanide chlorides
Robin D. Rogers, Russell D. Etzenhouser, James S. Murdoch, and Edgar Reyes
pp 1445 - 1455; DOI:
10.1021/ic00007a006
PDF
Synthesis, x-ray structure determination, and spectroscopy of the silver(I) polyselenides [(Ph4P)Ag(Se4)]n, [(Me4N)Ag(Se5)]n, [(Et4N)Ag(Se4)]4, and (Pr4N)2[Ag4(Se4)3]. Extreme structure dependence on counterion size
Song Ping Huang and Mercouri G. Kanatzidis
pp 1455 - 1466; DOI:
10.1021/ic00007a007
PDF
Heterometallic condensed cluster compounds: Pr4I5Z (Z = Co, Ru, Os) and lanthanum ruthenium iodide (La4I5Ru). Synthesis, structure, and bonding
Martin W. Payne, Peter K. Dorhout, and John D. Corbett
pp 1467 - 1472; DOI:
10.1021/ic00007a008
PDF
Crystal structure of a novel copper(I) cyanide complex with hexamethylenetetramine, (CuCN)3(C6H12N4)2
Fred B. Stocker
pp 1472 - 1475; DOI:
10.1021/ic00007a009
PDF
A new hydrogen-bonded dinuclear complex involving copper(II) ions in a pseudotetrahedral N3O environment: molecular and crystal structure and magnetic and spectroscopic properties
Enrique Colacio, Jean Pierre Costes, Raikko Kivekas, Jean Pierre Laurent, Jose Ruiz, and Markku Sundberg
pp 1475 - 1479; DOI:
10.1021/ic00007a010
PDF
Preparation and structural characterization of new derivatives of digermane bearing tris(trimethylsilyl)silyl substituents
S. P. Mallela and Russell A. Geanangel
pp 1480 - 1482; DOI:
10.1021/ic00007a011
PDF
Reactions of bis(nitro)(.alpha.,.alpha.,.alpha.,.alpha.-tetrakis(o-pivalamidophenyl)porphinato)ferrate(III) with pyridine and imidazole. EPR and Moessbauer spectra and molecular structures of the mixed-ligand species
Habib Nasri, Yaning Wang, Huynh Boi Hanh, F. Ann Walker, and W. Robert Scheidt
pp 1483 - 1489; DOI:
10.1021/ic00007a012
PDF
Use of solid-state carbon-13 NMR spectroscopy to quantify the degree of asymmetry of bonding for semibridging carbonyl groups in iron carbonyl complexes
Geoffrey E. Hawkes, Keith D. Sales, Silvio Aime, Roberto Gobetto, and Lu Yun Lian
pp 1489 - 1493; DOI:
10.1021/ic00007a013
PDF
Formation of carbonyl-carbonate complexes of molybdenum by reductive disproportionation of carbon dioxide. X-ray structure of Mo4(.mu.4-CO3)(CO)2(O)2(.mu.2-O)2(.mu.2-OH)4(PMe3)6
Rafael Alvarez, Jerry L. Atwood, Ernesto Carmona, Pedro J. Perez, Manuel L. Poveda, and Robin D. Rogers
pp 1493 - 1499; DOI:
10.1021/ic00007a014
PDF
Synthesis and molecular structure of a mononuclear barium aryloxide-ethanolamine complex, Ba(2,6-tert-Bu2C6H3O)2(HOCH2CH2NMe2)4.cntdot.2C7H8, exhibiting extensive hydrogen bonding
Kenneth G. Caulton, Malcolm H. Chisholm, Simon R. Drake, and Kirsten Folting
pp 1500 - 1503; DOI:
10.1021/ic00007a015
PDF
Tetradentate dithiooxamide ligands and their nickel complexes. Synthesis, characterization, and crystal structure of a mononuclear neutral complex, Ni((c-C5H9)NHC(S)C(S)N(CH2)2NC(S)C(S)NH(c-C5H9))
Qiu Yun Ye, Yoshiharu Nakano, Greg R. Frauenhoff, David R. Whitcomb, Fusao Takusagawa, and Daryle H. Busch
pp 1503 - 1510; DOI:
10.1021/ic00007a016
PDF
Structure and bonding in bis(quinone) complexes of ruthenium. Synthesis and characterization of the Ru(PPh3)2(SQ)2 (SQ = 3,5-tert-butylsemiquinone, tetrachloro-1,2-semiquinone) series
Samaresh Bhattacharya and Cortlandt G. Pierpont
pp 1511 - 1516; DOI:
10.1021/ic00007a017
PDF
Synthesis and structural characterization of an organotitanium complex containing a planar bis(.mu.-oxo)dititanium core
Jun Okuda and Eberhardt Herdtweck
pp 1516 - 1520; DOI:
10.1021/ic00007a018
PDF
Carbon dioxide coordination chemistry. 1. Vibrational study of trans-bis(carbon dioxide)tetrakis (trimethylphosphine)molybdenum and (carbon dioxide) tetrakis(trimethylphosphine)iron
Corine Jegat, Monique Fouassier, and Joelle Mascetti
pp 1521 - 1529; DOI:
10.1021/ic00007a019
PDF
Carbon dioxide coordination chemistry. 2. Synthesis and FTIR study of (carbon dioxide)bis(cyclopentadienyl)(trimethylphosphine)titanium
Corine Jegat, Monique Fouassier, Michel Tranquille, and Joelle Mascetti
pp 1529 - 1536; DOI:
10.1021/ic00007a020
PDF
Synthesis and characterization of tin(IV) porphyrins with sulfide and selenide axial ligands
R. Guilard, C. Ratti, J. M. Barbe, D. Dubois, and K. M. Kadish
pp 1537 - 1542; DOI:
10.1021/ic00007a021
PDF
Effect of pyridine binding and spin state on spectroscopic and electrochemical properties of phenyl- and (perfluorophenyl)iron(III) porphyrins
K. M. Kadish, A. Tabard, W. Lee, Y. H. Liu, C. Ratti, and R. Guilard
pp 1542 - 1549; DOI:
10.1021/ic00007a022
PDF
Water exchange of the (o-phenylenediamine-N,N,N',N'-tetraacetato)ferrate(III) complex in aqueous solution as studied by variable-temperature, -pressure, and -frequency oxygen-17 NMR techniques
Masafumi Mizuno, Shigenobu Funahashi, Noriyuki Nakasuka, and Motoharu Tanaka
pp 1550 - 1553; DOI:
10.1021/ic00007a023
PDF
New multidentate ligands. 29. Stabilities of iron(III) and gallium(III) complexes of a tris(hydroxamate) cryptand and two open-chain analogs
Ramunas J. Motekaitis, Yizhen Sun, and Arthur E. Martell
pp 1554 - 1556; DOI:
10.1021/ic00007a024
PDF
Ligand-exchange reactions of chromium(V): characterization of the ligand-exchange equilibria of bis(2-ethyl-2-hydroxybutanoato(2-))oxochromate(V) in aqueous 1,2-ethanediol and the solution structure of bis(1,2-ethanediolato(2-))oxochromate(V)
Richard Bramley, Ji Ying Ji, and Peter A. Lay
pp 1557 - 1564; DOI:
10.1021/ic00007a025
PDF
Factors influencing the nitrogen vs oxygen bonding mode of amides bound to pentaamminecobalt(III) and the kinetics and mechanism of rearrangement
David P. Fairlie, Patricia M. Angus, M. David Fenn, and W. Gregory Jackson
pp 1564 - 1569; DOI:
10.1021/ic00007a026
PDF
The use of carbon-13 NMR isotopomer distributions for following proton exchange and unambiguously assigning the carbons and coordinated amine protons in multidentate chelate complexes of cobalt(III)
W. Gregory Jackson
pp 1570 - 1574; DOI:
10.1021/ic00007a027
PDF
Kinetic studies on the terminal-ligand-substitution reactions of acetate-bridged trinuclear molybdenum and tungsten cluster complexes, [Mo3(.mu.3-CCH3)(.mu.3-O)(.mu.-CH3COO)6(L)3]+ (L = H2O or pyridine) and [W3(.mu.3-O)(.mu.-CH3COO)6(H2O)3]2+
Kou Nakata, Akira Nagasawa, Nobuyuki Soyama, Yoichi Sasaki, and Tasuku Ito
pp 1575 - 1579; DOI:
10.1021/ic00007a028
PDF
Variable-pressure kinetic and equilibrium study of the complexation of the beryllium(II) ion with 4-isopropyltropolone in acidic aqueous solution
Masahiko Inamo, Koji Ishihara, Shigenobu Funahashi, Yves Ducommun, Andre E. Merbach, and Motoharu Tanaka
pp 1580 - 1583; DOI:
10.1021/ic00007a029
PDF
Rate of displacement of guanosine by cyanide from cis-diamminebis(guanosine)platinum(II) chloride determined by using carbon-13 NMR spectroscopy
Mark M. Jones and Julie A. Beaty
pp 1584 - 1587; DOI:
10.1021/ic00007a030
PDF
Preparation and spectral and electrochemical characterization of the tetrakis eight-coordinate molybdenum(IV) and tungsten(IV) complexes containing tert-butyl- and 2-hydroxy-, 2-mercapto-, and 2-(hydroseleno)-substituted pyridine and pyrimidine ligands
Craig J. Donahue, Van A. Martin, Barry A. Schoenfelner, and Ellen C. Kosinski
pp 1588 - 1594; DOI:
10.1021/ic00007a031
PDF
Conversion of hydroxo-bridged diplatinum(II) complexes to amido-bridged diplatinum(II) complexes. X-ray crystal structure of trans-[Pt2(.mu.-NH2)2(Ph2PO)2(PPh2Me)2].cntdot.CH3CH2OH
Nathaniel W. Alcock, Paola Bergamini, Terence J. Kemp, Paul G. Pringle, Silvana Sostero, and Orazio Traverso
pp 1594 - 1598; DOI:
10.1021/ic00007a032
PDF
Calculations for various structural forms of dodecahydrododecaborate(2-) as clues to the possible mechanisms for the isomerizations of dicarbadodecaborane(12)
Benjamin M. Gimarc, D. Scott Warren, Jane J. Ott, and Carl Brown
pp 1598 - 1605; DOI:
10.1021/ic00007a033
PDF
Interactions of chromium(III) complexes with hydrous .delta.-alumina: rearrangements in the coordination sphere studied by electron spin resonanace and electron spin-echo spectroscopies
R. Karthein, H. Motschi, A. Schweiger, S. Ibric, B. Sulzberger, and W. Stumm
pp 1606 - 1611; DOI:
10.1021/ic00007a034
PDF
Spectroscopic evidence for a centrosymmetric dithionite anion in the solid state: vibrational spectroscopy of tetraethylammonium dithionite
William C. Hodgeman, Jeffrey B. Weinrach, and Dennis W. Bennett
pp 1611 - 1614; DOI:
10.1021/ic00007a035
PDF
Proton spin-lattice NMR relaxation studies of hydride carbonyl clusters: a method to evaluate distances involving hydrido ligands
Silvio Aime, Marco Cisero, Roberto Gobetto, Domenico Osella, and Alejandro J. Arce
pp 1614 - 1617; DOI:
10.1021/ic00007a036
PDF
Structure and bonding in cationic cyclopentadienyliron complexes containing thio-, seleno-, and telluroethers as ligands
Hans Schumann, Atta M. Arif, Arnold L. Rheingold, Christoph Janiak, Roald Hoffmann, and Norbert Kuhn
pp 1618 - 1625; DOI:
10.1021/ic00007a037
PDF
Magnetostructural correlations in magnetically coupled (.mu.-oxo)diiron(III) complexes
Sergiu M. Gorun and Stephen J. Lippard
pp 1625 - 1630; DOI:
10.1021/ic00007a038
PDF
EPR and structural investigations on single crystals of potassium niobium peroxide fluoride hydrate, K2NbO2F5.cntdot.H2O
Ramakrishnan Geetha, Pillutla Sambasiva Rao, Varghese Babu, and Sankaran Subramanian
pp 1630 - 1635; DOI:
10.1021/ic00007a039
PDF
Reactions of coordinated imidazole. Oxidation products and ring cleavage in the reactions of RImH3+ (R = pentaamminecobalt) with acetyl hypobromite and hypobromous acid
Allan G. Blackman, David A. Buckingham, Charles R. Clark, and Jim Simpson
pp 1635 - 1642; DOI:
10.1021/ic00007a040
PDF
Models of cytochromes b. Attempts to control axial ligand orientation with a "hindered" porphyrin system
Keiichiro Hatano, Martin K. Safo, F. Ann Walker, and W. Robert Scheidt
pp 1643 - 1650; DOI:
10.1021/ic00007a041
PDF
N-(arylsulfonyl)glycines as cyclometalating ligands. Crystal and molecular structures of disodium bis(.mu.-chloro)bis[.mu.-N-(phenylsulfonyl)glycinato-O,N,C]bis[.mu.-N-(phenylsulfonyl)glycinato-O,O']tetrapalladate(II) hexahydrate and disodium bis(.mu.-chloro)bis(.mu.-N-tosylglycinato-O,N,C)bis(.mu.-N-tosylglycinato-O,O')tetrapalladate(II)-4.5-water-2-N-tosylglycine
Ledi Menabue and Monica Saladini
pp 1651 - 1655; DOI:
10.1021/ic00007a042
PDF
Selective excitation of titanium(2+) dimers and trimers in magnesium chloride
Markus Herren, Stuart M. Jacobsen, and Hans U. Guedel
pp 1656 - 1660; DOI:
10.1021/ic00007a043
PDF
Metal-metal bonds in thallium(I)-thallium(I) compounds: fact or fiction?
Peter Schwerdtfeger
pp 1660 - 1663; DOI:
10.1021/ic00007a044
PDF
Thermochemical and kinetic studies of the electron-transfer catalysis of arene replacement by trimethyl phosphite ligands in (.eta.5-cyclopentadienyl)(.eta.6-arene)iron(II) cations
Philippe Boudeville and Andre Darchen
pp 1663 - 1665; DOI:
10.1021/ic00007a045
PDF
Complete carboxylate removal from [Mn12O12(OAc)16(H2O)4].cntdot.2HOAc.cntdot.4H2O) with chlorotrimethylsilane: synthesis and characterization of polymeric (2,2'-bipyridine)trichloromanganese and an improved synthesis of bis(tetraethylammonium) pentachloromanganate(2-)
Spiros P. Perlepes, Allan G. Blackman, John C. Huffman, and George Christou
pp 1665 - 1668; DOI:
10.1021/ic00007a046
PDF
Role of osmium in the reaction of the hydrazinium cation with chlorate in acid solution
Simeen Sattar and Kenneth Kustin
pp 1668 - 1670; DOI:
10.1021/ic00007a047
PDF
Reinvestigation of the vanadium-oxygen stretch in the IR spectrum of bis[N-(4-chlorophenyl)salicylideneiminato]oxovanadium(IV)
Dorothy E. Hamilton
pp 1670 - 1671; DOI:
10.1021/ic00007a048
PDF
Reaction of bis[.mu.-bis(diphenylphosphino)methane]dichloro(.mu.-sulfur dioxide)dirhodium with trimethylphosphine and nitrosonium tetrafluoroborate: Solid-state structures of [Rh2(.mu.-Cl)2(NO)2(.mu.-dppm)2](BF4)2 and RhCl(PMe3)(dppm)
Yuan Wen Ge and Paul R. Sharp
pp 1671 - 1674; DOI:
10.1021/ic00007a049
PDF
Metallo-oxo complex formation from photochemical cleavage of bis(cyclopentadienyl)molybdenum carbonate
Maher Henary, William C. Kaska, and Jeffrey I. Zink
pp 1674 - 1676; DOI:
10.1021/ic00007a050
PDF
A new electronegativity scale. 12. Intrinsic Lewis acid strength for main-group elements
Yu Ran Luo and Sidney W. Benson
pp 1676 - 1677; DOI:
10.1021/ic00007a051
PDF
Synthetic analog approach to metallobleomycins: possibility of coordination of the carboxamide group of the .beta.-aminoalaninamide moiety of bleomycin to copper in copper(II) bleomycin at physiological pH
Larry A. Scheich, Patricia Gosling, Steven J. Brown, Marilyn M. Olmstead, and Pradip K. Mascharak
pp 1677 - 1680; DOI:
10.1021/ic00007a052
PDF
Synthesis and characterization of heptarhenium carbido clusters with (.eta.2-olefin)iridium capping moieties [Erratum to document cited in CA114(3):24140u]
Linqing Ma, John R. Shapley, and Scott R. Wilson
pp 1680 - 1680; DOI:
10.1021/ic00007a053
PDF

Issue 8


Is chromium hexafluoride octahedral? Theory suggests not!
Colin J. Marsden and P. Peter Wolynec
pp 1681 - 1682; DOI:
10.1021/ic00008a001
PDF
Steady-state voltammetry with microelectrodes: determination of heterogeneous charge transfer rate constants for metalloporphyrin complexes
Y. Zhang, C. D. Baer, C. Camaioni-Neto, P. O'Brien, and D. A. Sweigart
pp 1682 - 1685; DOI:
10.1021/ic00008a002
PDF
A new synthetic route to the preparation of a series of strong photoreducing agents: fac-tris-ortho-metalated complexes of iridium(III) with substituted 2-phenylpyridines
K. Dedeian, P. I. Djurovich, F. O. Garces, G. Carlson, and R. J. Watts
pp 1685 - 1687; DOI:
10.1021/ic00008a003
PDF
Sulfur-bridged incomplete cubane-type mixed-metal cluster compounds of molybdenum(IV) and tungsten(IV). Syntheses, characterization, and x-ray structures of [Mo2WS4H2O)9](CH3C6H4SO3)4.9H2O) and [MoW2S4(H2O)9](CH3C6H4SO3)4.9H2O
Takashi Shibahara and Mikio Yamasaki
pp 1687 - 1688; DOI:
10.1021/ic00008a004
PDF
Synthesis and characterization of vanadium-containing silsesquioxanes
Frank J. Feher and John F. Walzer
pp 1689 - 1694; DOI:
10.1021/ic00008a005
PDF
Dawson type heteropolyanions. 1. Multinuclear (phosphorus-31, vanadium-51, tungsten-183) NMR structural investigations of octadeca(molybdotungstovanado)diphosphates .alpha.-1,2,3-[P2MM'2W15O62]n- (M, M' = Mo, V, W): syntheses of new related compounds
Mostefa Abbessi, Roland Contant, Rene Thouvenot, and Gilbert Herve
pp 1695 - 1702; DOI:
10.1021/ic00008a006
PDF
Nucleophilic discrimination in a mixed-metal phosphinidene-capped cluster. Formation of phosphido and cobalt-acyl derivatives
Ming Jaw Don and Michael G. Richmond
pp 1703 - 1709; DOI:
10.1021/ic00008a007
PDF
Low-temperature phosphorus-31 NMR studies of metal phosphine clusters
R. P. F. Kanters, P. P. J. Schlebos, J. Bour, J. J. Steggerda, W. E. J. R. Maas, and R. Janssen
pp 1709 - 1714; DOI:
10.1021/ic00008a008
PDF
Ruthenium in an oxygen donor environment: properties and reactions of .eta.3-(RPO(C6H4O)2)2-, .eta.3-(CpCo(PO(OEt)2)3)1- and .eta.3-HC(POPh2)3 complexes of ruthenium
Robin S. Tanke, Elizabeth M. Holt, and Robert H. Crabtree
pp 1714 - 1719; DOI:
10.1021/ic00008a009
PDF
Nature of the phase change in solid bis(isopropyl alcohol)octakis(isopropoxo)dicerium, as determined by variable-temperature x-ray diffraction and deuterium NMR spectroscopy
Beth A. Huggins, Paul D. Ellis, Peter S. Gradeff, Brian A. Vaartstra, Kenan Yunlu, John C. Huffman, and Kenneth G. Caulton
pp 1720 - 1722; DOI:
10.1021/ic00008a010
PDF
Yttrium and lanthanum silyloxide complexes
Michael J. McGeary, Paul S. Coan, Kirsten Folting, William E. Streib, and Kenneth G. Caulton
pp 1723 - 1735; DOI:
10.1021/ic00008a011
PDF
Preparations, structures and reactions of molybdenum complexes of triorgano silylated pyridine-2-thiols
Eric Block, Michael Gernon, Hyunkyu Kang, Gabriel Ofori-Okai, and Jon Zubieta
pp 1736 - 1747; DOI:
10.1021/ic00008a012
PDF
cis-Mo(CO)4{Ph2P(CH2CH2O)nCH2CH2PPh2} (n = 3-5) metallacrown ethers. X-ray crystal structure of cis-Mo(CO)4{Ph2P(CH2CH2O)3CH2CH2PPh2}
Ashima Varshney and Gary M. Gray
pp 1748 - 1754; DOI:
10.1021/ic00008a013
PDF
Poly(pyrazolyl)borate complexes of tin(II). Crystal and molecular structures of [H2B(pz)2]SnCl and [B(pz)4]2Sn (pz = pyrazolyl ring)
Daniel L. Reger, Steven J. Knox, Mark F. Huff, Arnold L. Rheingold, and Brian S. Haggerty
pp 1754 - 1759; DOI:
10.1021/ic00008a014
PDF
Reactions of the phenyl(m-carboran-9-yl)chloronium cation with nucleophiles. Influence of the nature of the onium halogen atom on the reactivity and the reaction pathways of phenyl(m-carboran-9-yl)halonium compounds
V. V. Grushin, I. I. Demkina, and T. P. Tolstaya
pp 1760 - 1765; DOI:
10.1021/ic00008a015
PDF
Organotransition-metal metallacarboranes. 18. .eta.6,.eta.5-Benzyltetramethylcyclopentadienide(1-) as a bridging ligand in multilevel iron-cobalt sandwich complexes
James H. Davis, Mark A. Benvenuto, and Russell N. Grimes
pp 1765 - 1770; DOI:
10.1021/ic00008a016
PDF
Synthesis of the tetraphenylphosphonium and tetraethylammonium salts of tetrakis(benzeneselenolato)metalate(2-) [M(SePh)42], (M = manganese, iron, cobalt, nickel) and the structure of [NEt4]2[Fe(SePh)4].MeCN
Jonathan M. McConnachie and James A. Ibers
pp 1770 - 1773; DOI:
10.1021/ic00008a017
PDF
Synthesis and characterization of tetrabutylammonium (2-aminobenzenethiolato(2-)-S,N)tetrachlorotechnetate(V)
Jessica Cook, William M. Davis, Alan Davison, and Alun G. Jones
pp 1773 - 1776; DOI:
10.1021/ic00008a018
PDF
Synthesis of cyclic phosphazenes with isothiocyanato, thiourethane, and thiourea side groups: x-ray crystal structure of N3P3(NMe2)3(NCS)3
Harry R. Allcock, J. Steven Rutt, and Masood Parvez
pp 1776 - 1782; DOI:
10.1021/ic00008a019
PDF
Reactions of low-coordinate transition-metal amides with secondary phosphanes and arsanes: synthesis, structural, and spectroscopic studies of [M{N(SiMe3)2}(.mu.-PMes2)]2 (M = manganese, iron), [Mn{N(SiMe3)2}(.mu.-AsMes2)]2 and Mes2AsAsMes2
Hong Chen, Marilyn M. Olmstead, Doris C. Pestana, and Philip P. Power
pp 1783 - 1787; DOI:
10.1021/ic00008a020
PDF
Preparation and characterization of two new isomorphous heteropoly oxofluorotungstate anions [CoW17O56F6NaH4]9- and [FeW17O56F6NaH4]8-
Sadiq H. Wasfi, Catherine E. Costello, Arnold L. Rheingold, and Brian S. Haggerty
pp 1788 - 1792; DOI:
10.1021/ic00008a021
PDF
Metal ion control of organic reactivity: electrophilic and nucleophilic reactions of coordinated 2-iminopropanoate
J. M. Harrowfield, Alan M. Sargeson, and P. O. Whimp
pp 1792 - 1800; DOI:
10.1021/ic00008a022
PDF
Oxidation of bis(1,2-ethanediamine)(sarcosinato)cobalt(III) ion with thionyl chloride
Lisbeth Groendahl, Anders Hammershoei, Richard M. Hartshorn, and Alan M. Sargeson
pp 1800 - 1805; DOI:
10.1021/ic00008a023
PDF
Structural studies of metalloporphyrins. 10. Complexes of water-soluble cobalt(III) porphyrins with amino acids: NMR study of the conformation of the complexes with cobalt(III) tetrakis[4-(N-methylpyridiniumyl)]porphine (CoTMPyP) and cobalt(III) tetrakis(4-carboxylatophenyl)porphine (CoTCPP)
Emmanouil Mikros, Francoise Gaudemer, and Alain Gaudemer
pp 1806 - 1815; DOI:
10.1021/ic00008a024
PDF
Modeling the heteroleptic equilibria of organized molecular systems by using a double-titration technique: a novel determination of the fundamental equilibrium constants in a ternary system involving a macrocyclic cobalt(II) complex, dioxygen, and competing axial ligands
Naidong Ye and Daryle H. Busch
pp 1815 - 1819; DOI:
10.1021/ic00008a025
PDF
Syntheses, characterization, and reactivity of manganese and rhenium dioxime complexes. X-ray crystal structure of MnII(CDO)(CDOH)2(BPh(OCH3))2, an unusual pseudoclathrochelate complex, and ReIIICl(CDO)(CDOH)2BPh
S. Jurisson, L. Francesconi, K. E. Linder, E. Treher, M. F. Malley, J. Z. Gougoutas, and A. D. Nunn
pp 1820 - 1827; DOI:
10.1021/ic00008a026
PDF
Coordinated nitrosyl as a source of oxygen: reactivity of the dinitrosyliron moiety in the presence of the bidentate phosphane 1,2-bis(diphenylphosphino)ethane (dppe) and 1,2-bis(diphenylphosphino)ethene (dppen)
P. Guillaume, H. Li Kam Wah, and Michele Postel
pp 1828 - 1831; DOI:
10.1021/ic00008a027
PDF
Electrochemical and spectroscopic studies of iron porphyrin nitrosyls and their reduction products
In Kyu Choi, Yanming Liu, DiWei Feng, Ki Jung Paeng, and Michael D. Ryan
pp 1832 - 1839; DOI:
10.1021/ic00008a028
PDF
Raman-scattering properties of Mo(V)=O and Mo(V)=S complexes as probes for molybdenum-containing enzymes
Gabriele Backes, John H. Enemark, and Thomas M. Loehr
pp 1839 - 1842; DOI:
10.1021/ic00008a029
PDF
Interaction of "long" open-chain polyazaalkanes with hydrogen and copper(II) ions
Juan Arago, Andrea Bencini, Antonio Bianchi, Enrique Garcia-Espana, Mauro Micheloni, Piero Paoletti, Jose A. Ramirez, and Paola Paoli
pp 1843 - 1849; DOI:
10.1021/ic00008a030
PDF
Mechanism of oxidation of the 2-hydroxycyclohexyl radical to cyclopentanecarbaldehyde by copper ions in aqueous solutions
Mohamad Masarwa, Haim Cohen, and Dan Meyerstein
pp 1849 - 1854; DOI:
10.1021/ic00008a031
PDF
Thermodynamics of chloro complexation of lanthanide(III) ions in N,N-dimethylformamide
Shinichi Ishiguro and Ryouta Takahashi
pp 1854 - 1858; DOI:
10.1021/ic00008a032
PDF
Pressure effects on the self-exchange rates of cobalt(III/II) couples: evidence for adiabatic electron transfer in the bis(1,4,7-trithiacyclononane) and sepulchrate complexes
H. Doine and Thomas W. Swaddle
pp 1858 - 1862; DOI:
10.1021/ic00008a033
PDF
4- and 3-Cyanopyridine-bridged binuclear complexes of pentacyanoferrate and pentaammineruthenium
Hung Yi Huang, Wen Jang Chen, Chang Chau Yang, and Andrew Yeh
pp 1862 - 1868; DOI:
10.1021/ic00008a034
PDF
Important factors in oxygen atom transfer to metal carbonyls. Rate of carbonyl substitution of chromium hexacarbonyl and iron pentacarbonyl in the presence of para-methoxyphenol chalcogenide oxide (p-CH3OC6H4)2EO (E = selenium, tellurium) and of triphenyl metal oxide (C6H5)3EO (E = arsenic, antimony). Syntheses and x-ray structure of Cr(CO)5E(p-CH3OC6H4)2
Jian Kun Shen, Yici Gao, Qizhen Shi, Arnold L. Rheingold, and Fred Basolo
pp 1868 - 1873; DOI:
10.1021/ic00008a035
PDF
Selenium-77 NMR spectroscopic and x-ray crystallographic characterization of bis(cyclopentadienyl)titanium selenide sulfide mixtures [Ti(C5H5)2SexS5x]
Pentti Pekonen, Yrjo Hiltunen, Risto S. Laitinen, and Jussi Valkonen
pp 1874 - 1878; DOI:
10.1021/ic00008a036
PDF
Hydrogen bonding in alkylammonium chlorometalates of the first transition metals
Kenneth Emerson, Pascual Roman, Antonio Luque, Juan Manuel Gutierrez-Zorilla, and Martin Martinez-Ripoll
pp 1878 - 1881; DOI:
10.1021/ic00008a037
PDF
One-dimensional antiferromagnetism in a linear chain containing zinc(II) and a nitronyl nitroxide
A. Caneschi, Dante Gatteschi, R. Sessoli, C. I. Cabello, P. Rey, A. L. Barra, and L. C. Brunel
pp 1882 - 1886; DOI:
10.1021/ic00008a038
PDF
New route to bimetallic imidazolate-bridged complexes. 6. Structural and magnetic consequences of steric effects in mono- and dinuclear nickel(II) and copper(II) complexes involving 4-methylimidazole as ligand
Jean Pierre Costes, Francoise Dahan, and Jean Pierre Laurent
pp 1887 - 1892; DOI:
10.1021/ic00008a039
PDF
Pyridine-based macrocycles containing N, O, and S and their use as ion-selective electrodes. Crystal structures of 15-aza-6-oxa-3,9-dithiabicyclo[9.3.1]pentadeca-1(15),11,13-triene and (15-aza-6-oxa-3,9-dithiabicyclo[9.3.1]pentadeca-1(15),11,13-triene)dichlorocopper(II)
J. Casabo, L. Escriche, S. Alegret, C. Jaime, C. Perez-Jimenez, J. Rius, E. Molins, C. Miravitlles, F. Teixidor, and L. Mestres
pp 1893 - 1898; DOI:
10.1021/ic00008a040
PDF
Studies of micellar metalloporphyrins. Synthesis and spectroscopic characterization of [(P)H2]+ and [(P)MII]+ where P = the dianion of 5-(4-N-hexadecylpyridiniumyl-10,15,20-triphenylporphyrin bromide and M = vanadyl, nickel or copper
R. Guilard, N. Senglet, Y. H. Liu, D. Sazou, E. Findsen, D. Faure, T. Des Courieres, and K. M. Kadish
pp 1898 - 1905; DOI:
10.1021/ic00008a041
PDF
Experimental and theoretical investigation of the electronic structure of two isoelectronic binuclear clusters. UV-PES and DV-X.alpha. study of ruthenium ethanediyldiamido carbonyl, Ru2(CO)6[.mu.,.mu.'-N(R)CH2CH2N(R)], and iron ruthenium ethanediyldiamido carbonyl, FeRu(CO)6[.mu.,.mu.'-N(R)CH2CH2N(R)]
M. Casarin, A. Gulino, M. J. A. Kraakman, G. A. Rizzi, A. Vittadini, and K. Vrieze
pp 1906 - 1911; DOI:
10.1021/ic00008a042
PDF
Electronic spectra, formation constants, and geometries of HgX3- in methanol
Trevor R. Griffiths and Richard A. Anderson
pp 1912 - 1918; DOI:
10.1021/ic00008a043
PDF
Comparison of isoelectronic aluminum-nitrogen and silicon-carbon double bonds using valence bond methods
Mary M. Lynam, Leonard V. Interrante, Charles H. Patterson, and Richard P. Messmer
pp 1918 - 1922; DOI:
10.1021/ic00008a044
PDF
Single-crystal EPR and optical absorption investigations of the ozonide radical in crystalline solids alkali metal and ammonium ozonides, MO3 (M = potassium(1+), rubidium(1+), cesium(1+), tetramethylammonium(1+), and tetraethylammonium(1+))
G. Steffen, W. Hesse, M. Jansen, and D. Reinen
pp 1923 - 1926; DOI:
10.1021/ic00008a045
PDF
Disulfanido ligands: preparation and reactions of Cp2Ti(SSR)X, where X = SR, phthalimido, and Cl and R = alkyl and aryl groups
Alan Shaver and Stephen Morris
pp 1926 - 1930; DOI:
10.1021/ic00008a046
PDF
Carbon-13 and phosphorus-31 CP/MAS NMR studies of the polytopal ligand rearrangement process of tungsten tris(trimethylphosphine) hexahydride in the solid state
Stephen J. Heyes, Malcolm L. H. Green, and Christopher M. Dobson
pp 1930 - 1937; DOI:
10.1021/ic00008a047
PDF
Models for diiron-oxo proteins: the peroxide adduct of Fe2(HPTB)(OH)(NO3)4
Bridget A. Brennan, Qiuhao Chen, Carlos Juarez-Garcia, Anne E. True, Charles J. O'Connor, and Lawrence Que
pp 1937 - 1943; DOI:
10.1021/ic00008a048
PDF
Chelating modes of 3-substituted 2,4-pentanediones. Crystal and electronic structure of bis(3-cyano-2,4-pentanedionato)cobalt(II)
O. Angelova, I. Matsichek, M. Atanasov, and G. Petrov
pp 1943 - 1949; DOI:
10.1021/ic00008a049
PDF
Facile .alpha./.beta. diastereomerism in organocobalt corrins. Generality of the phenomenon and characterization of additional .alpha.-diastereomers
Kenneth L. Brown, Xiang Zou, and Laurent Salmon
pp 1949 - 1953; DOI:
10.1021/ic00008a050
PDF
Synthesis and reactivity of ruthenium hydride complexes containing chelating triphosphines. 6. Reactions of ruthenium hydride complexes with carbon dioxide-like molecules
Guochen Jia and Devon W. Meek
pp 1953 - 1955; DOI:
10.1021/ic00008a051
PDF
Hydrazinophosphine complexes of iron: metallacycle formation via attack on coordinated carbon monoxide
C. Jeff Harlan, Thomas C. Wright, Jerry L. Atwood, and Simon G. Bott
pp 1955 - 1957; DOI:
10.1021/ic00008a052
PDF
Reaction between [(TPP)Ru(CO)].bul.- and methyl iodide. Evidence for formation of a ruthenium(II) carbonyl methylated tetraphenylchlorin derivative
Y. J. Deng, X. H. Mu, P. Tagliatesta, and K. M. Kadish
pp 1957 - 1960; DOI:
10.1021/ic00008a053
PDF
Two-dimensional oxygen-17-vanadium-51 heteronuclear shift correlation NMR spectroscopy of the 17O-enriched inclusion complex [CH3CN.cntnd.(V12O324-)]. Relationship of cross-peak intensity to bond order
George W. Wagner
pp 1960 - 1962; DOI:
10.1021/ic00008a054
PDF
Intramolecular O-H.cntdot..cntdot..cntdot.Cl hydrogen bonding in titanium chloride alkoxides of the formula [TiCl2(OCH2CH2X)2.cntdot.HOCH2CH2X]2 (X = Cl, Br, I). Crystal structure of [TiCl2(OCH2CH2Cl)2.cntdot.HOCH2CH2Cl]2
Charles H. Winter, Philip H. Sheridan, and Mary Jane Heeg
pp 1962 - 1964; DOI:
10.1021/ic00008a055
PDF

Issue 9


Very high field magnetization and zero-field splitting within the excited state of a copper(II)-nickel(II) binuclear compound
Pierre Bergerat, Olivier Kahn, and Maurice Guillot
pp 1965 - 1966; DOI:
10.1021/ic00009a001
PDF
Synthesis and structural characterization of decaselenidoheptamercurate(4-) and [Hg7Se9]n4n-: novel metal-chalcogenide frameworks
Kang Woo Kim and Mercouri G. Kanatzidis
pp 1966 - 1969; DOI:
10.1021/ic00009a002
PDF
Volatile copper and barium-copper alkoxides. Crystal structure of a tricoordinate copper(II) complex, Ba(Cu[OCMe(CF3)2]3)2
Andrew P. Purdy and Clifford F. George
pp 1969 - 1970; DOI:
10.1021/ic00009a003
PDF
The synthesis and structural characterization of the europium sandwich [1,1-(THF)2-commo-1,1'-Eu(1,2,4-EuC2B10H12)2]2-
Rajesh Khattar, Carolyn B. Knobler, M. Frederick Hawthorne, and Stephen E. Johnson
pp 1970 - 1972; DOI:
10.1021/ic00009a004
PDF
A cobalt(III) sulfato chelate. Synthesis and structure of (.eta.2-sulfato)(tris(aminopropyl)amine)cobalt perchlorate hydrate
M. Banaszczyk, Jeng Jong Lee, and F. M. Menger
pp 1972 - 1973; DOI:
10.1021/ic00009a005
PDF
A triply bonded dirhenium complex containing a nitrosyl ligand
Irene Ara, Phillip E. Fanwick, and Richard A. Walton
pp 1973 - 1974; DOI:
10.1021/ic00009a006
PDF
Photochemistry and photophysics of cis- and trans-diammine(1,4,8,11-tetraazacyclotetradecane)chromium(III) ions in acidified aqueous media under different pressure and temperature conditions
Duane A. Friesen, Sang H. Lee, Jochen Lilie, William L. Waltz, and Laszlo Vincze
pp 1975 - 1980; DOI:
10.1021/ic00009a007
PDF
Electrochemical parametrization of rhenium redox couples
A. B. P. Lever
pp 1980 - 1985; DOI:
10.1021/ic00009a008
PDF
Valence trapping of mixed-valence solvated hexakis(acetato)oxotris(pyridine)triiron complex at high pressure
James K. McCusker, Ho G. Jang, Maruta Zvagulis, Walter Ley, Harry G. Drickamer, and David N. Hendrickson
pp 1985 - 1990; DOI:
10.1021/ic00009a009
PDF
Role of large but defective deltahedra in the structural chemistry of very complex solid borides and gallides
Jeremy K. Burdett and Enric Canadell
pp 1991 - 1998; DOI:
10.1021/ic00009a010
PDF
Mechanistic studies of the catalytic reduction of nitric oxide by carbon monoxide in the presence of platinum(II), copper(I), and copper(II)
K. S. Sun, K. C. Kong, and C. H. Cheng
pp 1998 - 2004; DOI:
10.1021/ic00009a011
PDF
Protonation of phosphine complexes of zerovalent nickel, palladium, platinum, and ruthenium with fluorocarbon acids
A. R. Siedle, R. A. Newmark, and W. B. Gleason
pp 2005 - 2009; DOI:
10.1021/ic00009a012
PDF
Metallacarborane complexes that incorporate the lanthanides. Synthesis, molecular structure, and spectroscopic characterization of dicarbollide complexes of samarium and ytterbium
Mark J. Manning, Carolyn B. Knobler, Rajesh Khattar, and Frederick M. Hawthorne
pp 2009 - 2017; DOI:
10.1021/ic00009a013
PDF
Chemistry of tris(2,4,6-trimethoxyphenyl)phosphine (TMPP) with dirhodium tetraacetate: synthesis, spectroscopic, electrochemical, and structural characterization of a binuclear complex that contains an unusual phenoxy-phosphine ligand
S. J. Chen and Kim R. Dunbar
pp 2018 - 2023; DOI:
10.1021/ic00009a014
PDF
Syntheses of charge-compensated dicarbollide ligand precursors and their use in the preparation of novel metallacarboranes
Han Chyul Kang, Sharon S. Lee, Carolyn B. Knobler, and M. Frederick Hawthorne
pp 2024 - 2031; DOI:
10.1021/ic00009a015
PDF
Investigations of the technetium-hydrazido core. Synthesis and structural characterization of [(n-C4H9)4N][Tc2(NNPh2)2(C6Cl4O2)4].cntdot.CH2Cl2.cntdot.2CH3OH, a Tc(V)/Tc(VI) catecholate complex with the hydrazido ligands adopting the unusual *1 bridging mode
Michael J. Abrams, Scott K. Larsen, and Jon Zubieta
pp 2031 - 2035; DOI:
10.1021/ic00009a016
PDF
Fluoride as a terminal and bridging ligand for copper: isolation and x-ray crystallographic characterization of copper monomeric and dimeric complexes [CuII(TMPA)F]nn+ (n = 1 or 2; TMPA = tris[(2-pyridyl)methyl]amine)
Richard R. Jacobson, Zoltan Tyeklar, Kenneth D. Karlin, and Jon Zubieta
pp 2035 - 2040; DOI:
10.1021/ic00009a017
PDF
Preparation and x-ray structure of tetraphenylphosphonium amminebis(tetrasulfido)nitrosylruthenate, (PPh4)[Ru(NO)(NH3)(S4)2]: the first polysulfido nitrosyl complex of ruthenium
A. Mueller, M. Ishaque Khan, E. Krickemeyer, and H. Boegge
pp 2040 - 2043; DOI:
10.1021/ic00009a018
PDF
Crystal structures and characterization of a new manganese(III) arsenate, MnAsO4.cntdot.1.2H2O and manganese(II) pyroarsenate, Mn2As2O7
Miguel A. G. Aranda, Sebastian Bruque, and J. Paul Attfield
pp 2043 - 2047; DOI:
10.1021/ic00009a019
PDF
Reactivity of 16- and 18-electron mixed platinum-gold clusters with halides. Crystal and molecular structures of [Pt(PPh3)(AuPPh3)6(AuCl3].cntdot.2C4H10O
M. F. J. Schoondergang, J. J. Bour, G. P. F. Van Strijdonck, P. P. J. Schlebos, W. P. Bosman, J. M. M. Smits, P. T. Beurskens, and J. J. Steggerda
pp 2048 - 2052; DOI:
10.1021/ic00009a020
PDF
Low-temperature synthesis of vanadium sulfides
A. Bensalem and D. M. Schleich
pp 2052 - 2055; DOI:
10.1021/ic00009a021
PDF
Role of the ligand in the formation of short vanadium-vanadium contacts. Preparation and crystal structure of monomeric {[(Ph2P)2CH]3V}[Li(THF)4](THF)2 and [PhNC(H)NPh]2V(TMEDA) and dimeric {[PhNC(Me)O]2V}2(TMEDA) (TMEDA = N,N,N',N'-tetramethylethylenediamine)
Jilles J. H. Edema, Auke Meetsma, Fre Van Bolhuis, and Sandro Gambarotta
pp 2056 - 2061; DOI:
10.1021/ic00009a022
PDF
Synthesis and structural features of novel vanadium(II) amides. X-ray structures of the octahedral [(2-C5H4N)(CH3)N]2V(TMEDA) (TMEDA = N,N,N',N'-tetramethylethylenediamine) and the square-pyramidal [2,5-(CH3)2C4H2N]2V(pyridine)3 (py = pyridine)
Jilles J. H. Edema, Sandro Gambarotta, Auke Meetsma, Anthony L. Spek, and Nora Veldman
pp 2062 - 2066; DOI:
10.1021/ic00009a023
PDF
Small heteroborane cluster systems. 3. Characterization, deprotonation, and transition-metal chemistry of the small phosphorus-bridged pentaborane(9) system (.mu.-diphenylphosphino)pentaborane
Bruce H. Goodreau, Robert L. Ostrander, and James T. Spencer
pp 2066 - 2073; DOI:
10.1021/ic00009a024
PDF
Preparation of the macrobicyclic ligand 17-oxa-1,5,8,12-tetraazabicyclo[10.5.2]nonadecane: characterization of copper(II) intermediates in a template synthesis
Kathy A. Beveridge, Alexander McAuley, and Chao Xu
pp 2074 - 2082; DOI:
10.1021/ic00009a025
PDF
Effects of a bridging dicarboxylate ligand on the synthesis and physical properties of (.mu.-oxo)bis(.mu.-carboxylato)diiron(III) complexes
Robert H. Beer, William B. Tolman, Simon G. Bott, and Stephen J. Lippard
pp 2082 - 2092; DOI:
10.1021/ic00009a026
PDF
Synthesis, equilibrium, and kinetic properties of the gadolinium(III) complexes of three triazacyclodecanetriacetate ligands
E. Brucher, S. Cortes, F. Chavez, and A. D. Sherry
pp 2092 - 2097; DOI:
10.1021/ic00009a027
PDF
Nickel(II) bis(phosphine) complexes
Penelope S. Jarrett and Peter J. Sadler
pp 2098 - 2104; DOI:
10.1021/ic00009a028
PDF
Reactions of bis(1,4,7-triazacyclononane)nickel(3+/2+) with the components of nitrous acid
M. M. DeMaine and D. M. Stanbury
pp 2104 - 2109; DOI:
10.1021/ic00009a029
PDF
Macrocyclic polyamino polythiaether ligands with NxS4-x and NxS5-x donor sets: protonation constants, stability constants, and kinetics of complex formation with the aquocopper(II) ion
Bryan C. Westerby, Kerri L. Juntunen, Gregory H. Leggett, Virginia B. Pett, Michael J. Koenigbauer, Mark D. Purgett, Michael J. Taschner, L. A. Ochrymowycz, and D. B. Rorabacher
pp 2109 - 2120; DOI:
10.1021/ic00009a030
PDF
Evaluation of the .pi.-bonding ability of imidazole: structure determination and characterization of catena-(H2O)2(1-CH3im)2Mg(.mu.-CN)(CN)4(1-CH3im)Fe(III).cntdot.H2O (1-CH3im = 1-methylimidazole)
Craig R. Johnson, Colleen M. Jones, Sanford A. Asher, and Jaime E. Abola
pp 2120 - 2129; DOI:
10.1021/ic00009a031
PDF
Aluminum(3+) binding by adenosine 5'-phosphates: AMP, ADP, and ATP
Tamas Kiss, Imre Sovago, and R. Bruce Martin
pp 2130 - 2132; DOI:
10.1021/ic00009a032
PDF
Platinum DNA intercalator-mononucleotide adduct formation. Cooperativity between aromatic ring stacking and electrostatic interactions
Akira Odani, Reiko Shimata, Hideki Masuda, and Osamu Yamauchi
pp 2133 - 2138; DOI:
10.1021/ic00009a033
PDF
Oxygen atom transfer from a phosphine oxide to tungsten(II) compounds
Stephanie L. Brock and James M. Mayer
pp 2138 - 2143; DOI:
10.1021/ic00009a034
PDF
Formation of dihelicate and mononuclear complexes from ethane-bridged dimeric bipyridine or phenanthroline ligands with copper(I), cobalt(II), and iron(II) cations
Marie Therese Youinou, Raymond Ziessel, and Jean Marie Lehn
pp 2144 - 2148; DOI:
10.1021/ic00009a035
PDF
Syntheses, redox behavior, and magnetic and spectroscopic properties of copper(II)copper(II)copper(II), copper(II)nickel(II)copper(II), and copper(II)palladium(II)copper(II) species. Crystal structure of [L2Cu2Cu(dmg)2Br]ClO4.cntdot.CH3OH (L = 1,4,7-trimethyl-1,4,7-triazacyclononane; dmg = dimethylglyoximato(2-))
Phalguni Chaudhuri, Manuela Winter, Beatriz P. C. Della Vedova, Eckhard Bill, Alfred Trautwein, Stefan Gehring, Peter Fleischhauer, Bernhard Nuber, and Johannes Weiss
pp 2148 - 2157; DOI:
10.1021/ic00009a036
PDF
Preparation of the nitryl salts ON(Cl)F+AsF6-, ON(CF3)F+AsF6-, and HON(CH2)CF3+SbF6- and crystal structure of HON(CH2)CF3+AsF6-
Rolf Minkwitz, Dirk Bernstein, Hans Preut, and Peter Sartori
pp 2157 - 2161; DOI:
10.1021/ic00009a037
PDF
Structural, magnetic, and charge transport properties of bis[(5,10,15,20-tetramethylporphyrinato)palladium(II)] perrhenate, [Pd(tmp)]2[ReO4]
Ellen M. McGhee, Brian M. Hoffman, and James A. Ibers
pp 2162 - 2165; DOI:
10.1021/ic00009a038
PDF
Multiple bonds between main-group elements and transition metals. 91. High-oxidation-state rhenium complexes containing the hydridotris(1-pyrazolyl)borato ligand
Ian A. Degnan, Joachim Behm, Malcolm R. Cook, and Wolfgang A. Herrmann
pp 2165 - 2170; DOI:
10.1021/ic00009a039
PDF
Primary alkynylphosphines and allenylphosphines
Jean Claude Guillemin, Philippe Savignac, and Jean Marc Denis
pp 2170 - 2173; DOI:
10.1021/ic00009a040
PDF
Study of a variety of O-methyl, O-ethyl, O-isopropyl, and O-n-butyl dithiocarbonate (xanthate) derivatives of mono-, di-, and triphenylgermane. Crystal structures of Ph2Ge[S2CO(iso-Pr)]2 and Ph3Ge[S2COR], where R = Me and iso-Pr
John E. Drake, Anil G. Mislankar, and Maria L. Y. Wong
pp 2174 - 2180; DOI:
10.1021/ic00009a041
PDF
Synthetic, spectroscopic, magnetic, and x-ray structural studies on a vitamin B6-amino acid Schiff base complex, aqua(5'-phosphopyridoxylidenetyrosinato)copper(II) tetrahydrate
I. I. Mathews, P. A. Joy, S. Vasudevan, and H. Manohar
pp 2181 - 2185; DOI:
10.1021/ic00009a042
PDF
Photoaquation of cis-bis(azine)tetraammineruthenium(II) complexes, cis-Ru(NH3)4(L)(L')n+1
Luiz Alfredo Pavanin, Zenis Novais da Rocha, Ernesto Giesbrecht, and Elia Tfouni
pp 2185 - 2190; DOI:
10.1021/ic00009a043
PDF
Kinetic and equilibrium studies of complexes of aqueous iron(III) and squaric acid
M. J. Sisley and R. B. Jordan
pp 2190 - 2195; DOI:
10.1021/ic00009a044
PDF
New di- and trinuclear complexes of ruthenium with octahedra joined on faces or edges. 2. New compounds with Ru(II)Ru(II), Ru(II)Ru(III), and Ru(III)Ru(III) in face-sharing bioctahedra: structures, magnetism, and electrochemistry
F. Albert Cotton and Raymund C. Torralba
pp 2196 - 2207; DOI:
10.1021/ic00009a045
PDF
Solvent, temperature, and pressure dependence of the oxidative-addition of iodomethane to rhodium(I) diketonato carbonyl triphenylphosphino complexes of the type RhI(.beta.-diketonate)(CO)(PPh3)
J. A. Venter, J. G. Leipoldt, and Rudy Van Eldik
pp 2207 - 2209; DOI:
10.1021/ic00009a046
PDF
High-pressure EPR studies and an explanation of the atypical temperature dependence of the weak interdimer exchange coupling in bis[tris(ethylenediamine)cobalt(3+)] octachlorodicuprate(2-) dichloride dihydrate
S. K. Hoffmann and W. Hilczer
pp 2210 - 2213; DOI:
10.1021/ic00009a047
PDF
Pulsed photoacoustic microcalorimetry in aqueous solutions. Intersystem crossing efficiencies and bond dissociation energies of chromium(III) ammines
Xiaoqing Song and John F. Endicott
pp 2214 - 2221; DOI:
10.1021/ic00009a048
PDF
Common emissive intermediates in the thermal and photochemical reactions of nonemissive cyclopentadienylruthenium(II) complexes of coumarin laser dyes
Robert S. Koefod and Kent R. Mann
pp 2221 - 2228; DOI:
10.1021/ic00009a049
PDF
Borane isonitriles and carboxylates. Synthesis and characterization of the 2-carboxylic acid derivative of 1,1,4,4-tetramethyl-1,4-diazonia-2,5-diboratacyclohexane
Norman E. Miller
pp 2228 - 2231; DOI:
10.1021/ic00009a050
PDF
Crystal and molecular structure of (2,2,2-crypt)potassium telluridoplumbate, (2,2,2-crypt-K+)2Pb2Te32-
Mar Bjorgvinsson, Jeffery F. Sawyer, and Gary J. Schrobilgen
pp 2231 - 2233; DOI:
10.1021/ic00009a051
PDF
Models of photosynthetic chromophores: molecular structure of the bacteriochlorin (2,3,12,13-tetrahydro-5,10,15,20-tetraphenylporphinato)(pyridine)zinc(II)
K. M. Barkigia, M. Miura, M. A. Thompson, and J. Fajer
pp 2233 - 2236; DOI:
10.1021/ic00009a052
PDF
Vapor pressure of pentacarbonylruthenium, Ru(CO)5
R. Koelliker and G. Bor
pp 2236 - 2237; DOI:
10.1021/ic00009a053
PDF
Reaction of hydride with tricarbonyl(.eta.5-indenyl)rhenium. Facile formation of dodecacarbonylhexahydridotetrarhenate(2-) and indenide
Sang Woo Lee and Michael G. Richmond
pp 2237 - 2239; DOI:
10.1021/ic00009a054
PDF
Carbonate exchange for the complex tris(carbonato)dioxouranate(4-) in aqueous solution as studied by carbon-13-NMR spectroscopy
Erno Brucher, Julius Glaser, and Imre Toth
pp 2239 - 2241; DOI:
10.1021/ic00009a055
PDF
A planar binuclear tetrabenzoporphyrin and its dicopper derivative
Nagao Kobayashi, Masaharu Numao, Ryoko Kondo, Shinichiro Nakajima, and Tetsuo Osa
pp 2241 - 2244; DOI:
10.1021/ic00009a056
PDF
A convenient synthesis of the manganese and rhenium alkoxides and phenoxides fac-(CO)3(dppe)MOR (R = CH3, C2H5, C6H5; dppe = 1,2-bis(diphenylphosphino)ethane). X-ray structure of fac-(CO)3(dppe)ReOC6H5
Santosh K. Mandal, Douglas M. Ho, and Milton Orchin
pp 2244 - 2248; DOI:
10.1021/ic00009a057
PDF
Metalloporphyrins containing .sigma.-bonded nitrogen axial ligands. 1. Synthesis and characterization of indium(III) porphyrin complexes. Molecular structures of (4-phenyltetrazolato)- and (5-methyltetrazolato)(2,3,7,8,12,13,17,18-octaethylporphinato)indium(III) [Erratum to document cited in CA114(12):113930u]
R. Guilard, N. Jagerovic, A. Tabard, P. Richard, L. Courthaudon, A. Louati, C. Lecomte, and Karl M. Kadish
pp 2248 - 2248; DOI:
10.1021/ic00009a058
PDF

Issue 10


One-dimensional migration of 3MLCT (metal-to-ligand charge transfer) excitation energy in chloro(6-phenyl-2,2'-bipyridine)palladium(+)
Thomas Karlen, Andreas Ludi, Hans U. Guedel, and Hans Riesen
pp 2249 - 2250; DOI:
10.1021/ic00010a001
PDF
Bond angle of calcium fluoride in several host matrices
Ian R. Beattie, Peter J. Jones, and Nigel A. Young
pp 2250 - 2251; DOI:
10.1021/ic00010a002
PDF
Heterometallic yttrium-copper complexes. Synthesis and crystal structure of Y2Cu8(.mu.-PyO)12(.mu.-Cl)2(.mu.4-O)2(NO3)4(H2O)2.cntdot.2H2O (PyO- = deprotonated 2-hydroxypyridine)
Suning Wang
pp 2252 - 2253; DOI:
10.1021/ic00010a003
PDF
Synthesis and structural characterization of spontaneously resolved [(M(aet)3)4M'4O]6+ (M = rhodium(III), iridium(III); M'4 = zinc(II)4-x cobalt(II)x; aet = 2-aminoethanethiolate): conversion of linear- to a cage-type sulfur-bridged polynuclear structure
Takumi Konno, Kenichi Okamoto, and Jinsai Hidaka
pp 2253 - 2256; DOI:
10.1021/ic00010a004
PDF
Octatelluridohexakis(triethylphosphine)hexacobalt and a connection between Chevrel clusters and the NiAs structure
M. L. Steigerwald, T. Siegrist, and S. M. Stuczynski
pp 2256 - 2257; DOI:
10.1021/ic00010a005
PDF
High-nuclearity platinum-osmium alloy cluster complexes. Synthesis and structural characterizations of Pt4Os6(CO)22(COD) and Pt5Os6(CO)21(COD)2
Richard D. Adams, Jau Ching Lii, and Wengan Wu
pp 2257 - 2258; DOI:
10.1021/ic00010a006
PDF
Synthesis and properties of a tris(2,2'-bipyridine)ruthenium(II) dimer directly coupled at the C4 carbon
Alison J. Downard, Gene E. Honey, Leon F. Phillips, and Peter J. Steel
pp 2259 - 2260; DOI:
10.1021/ic00010a007
PDF
Absorption bands of the S3- and S62- polysulfide ions in liquid-ammonia solutions
V. Pinon and J. P. Lelieur
pp 2260 - 2264; DOI:
10.1021/ic00010a008
PDF
Metal-metal bonds involving the f elements. 4. Molecular orbital studies of metal-metal and metal-ligand interactions in dinuclear uranium(V) systems
Roger H. Cayton, Kevin J. Novo-Gradac, and Bruce E. Bursten
pp 2265 - 2272; DOI:
10.1021/ic00010a009
PDF
Synthesis and spectroscopic properties of praseodymium(III) acetate hydrate
Markus P. Hehlen, Hans Riesen, and Hans U. Guedel
pp 2273 - 2277; DOI:
10.1021/ic00010a010
PDF
Electronic and geometrical structures of nitroso ligands coordinated to transition-metal atoms. A nonempirical theoretical study of bis(phosphino)(nitrosotrifluoromethane)platinum and bis(phosphine)(nitrosomethane)platinum
P. Fantucci, M. Pizzotti, and F. Porta
pp 2277 - 2282; DOI:
10.1021/ic00010a011
PDF
Vibrational spectra of the .mu.2-hydride ligands in [H4M4(CO)12] (M = osmium, ruthenium)
Christopher E. Anson, Upali A. Jayasooriya, Sidney F. A. Kettle, Pier Luigi Stanghellini, and Rosanna Rossetti
pp 2282 - 2286; DOI:
10.1021/ic00010a012
PDF
Investigation of the redox states of .mu.-cyanodicyanotetrakis(2,2'-bipyridine)diruthenium(+): evidence of valence delocalization of the singly oxidized complex
J. B. Cooper, T. M. Vess, W. A. Kalsbeck, and D. W. Wertz
pp 2286 - 2290; DOI:
10.1021/ic00010a013
PDF
Quantum-mechanical studies of model peroxidase compound I complexes
Gilda H. Loew, Frank U. Axe, Jack R. Collins, and Ping Du
pp 2291 - 2294; DOI:
10.1021/ic00010a014
PDF
Metal phthalocyanine ground states: covalence and ab initio calculation of spin and charge densities
Philip A. Reynolds and Brian N. Figgis
pp 2294 - 2300; DOI:
10.1021/ic00010a015
PDF
Photochemical, electrochemical, and chemical formation of the .pi.-cation-radical species of magnesium phthalocyanine. Analysis of the absorption and MCD spectra of [MgPc(-1)].bul.+
Edward Ough, Zbigniew Gasyna, and Martin J. Stillman
pp 2301 - 2310; DOI:
10.1021/ic00010a016
PDF
Structure and photochemistry of manganese porphyrin sulfate complexes
Kenneth S. Suslick, Randall A. Watson, and Scott R. Wilson
pp 2311 - 2317; DOI:
10.1021/ic00010a017
PDF
Photoreduction of cerium(IV) in octakis(isopropoxo)bis(2-propanol)dicerium. Characterization and structure of Ce4O(OPr-iso)13(iso-PrOH)
Kenan Yunlu, Peter S. Gradeff, Norman Edelstein, W. Kot, G. Shalimoff, William E. Streib, Brian A. Vaartstra, and Kenneth G. Caulton
pp 2317 - 2321; DOI:
10.1021/ic00010a018
PDF
Utility of semilocalized bonding schemes in extended systems: three-center metal-metal bonding in molybdenum sulfide (MoS2), niobium tantalum sulfide bronze (Hx(Nb,Ta)S2), and zirconium sulfide (ZrS)
Kyeong Ae Yee and Timothy Hughbanks
pp 2321 - 2328; DOI:
10.1021/ic00010a019
PDF
Preparation of zinc sulfide and cadmium sulfide by thermal degradation of (methanethiolato)zinc and cadmium complexes, [M(SMe)2]n (M = Zn, Cd)
Kohtaro Osakada and Takakazu Yamamoto
pp 2328 - 2332; DOI:
10.1021/ic00010a020
PDF
Uranium(IV) complexes with the oxygen tripod ligand L- = CpCo[P(O)(OEt)2]3-. X-ray crystal structure of L2UCl2
Denise Baudry, Michel Ephritikhine, Wolfgang Klaeui, Monique Lance, Martine Nierlich, and J. Vigner
pp 2333 - 2336; DOI:
10.1021/ic00010a021
PDF
Borohydride complexes of europium(II) and ytterbium(II) and their conversion to metal borides. Structures of (L)4Yb[BH4]2 (L = CH3CN, C5H5N)
James P. White, Haibin Deng, and Sheldon G. Shore
pp 2337 - 2342; DOI:
10.1021/ic00010a022
PDF
New classes of skeletally stabilized tri- and tetraphosphazanes
Joseph M. Barendt, R. Curtis Haltiwanger, Christopher A. Squier, and Arlan D. Norman
pp 2342 - 2349; DOI:
10.1021/ic00010a023
PDF
Structure and reactivity of ruthenium half-sandwich compounds: crystal and molecular structure and acetonitrile exchange kinetics and mechanism of tris(acetonitrile)(.eta.6-benzene)ruthenium(2+) and tris(acetonitrile)(.eta.5-cyclopentadienyl)ruthenium(+)
Werner Luginbuehl, Pascal Zbinden, Pierre A. Pittet, Thomas Armbruster, Hans Beat Buergi, Andre E. Merbach, and Andreas Ludi
pp 2350 - 2355; DOI:
10.1021/ic00010a024
PDF
Mechanistic study of the complex formation of boric acid
Koji Ishihara, Yasuko Mouri, Shigenobu Funahashi, and Motoharu Tanaka
pp 2356 - 2360; DOI:
10.1021/ic00010a025
PDF
Reduction of the tetrahydroxoargentate(III) ion by thiocyanate in aqueous alkaline media
Louis J. Kirschenbaum and Yunfu Sun
pp 2360 - 2365; DOI:
10.1021/ic00010a026
PDF
Synthesis and structures of the [MoFe6S6(CO)16]2-, [MoFe4S3(CO)13(PEt3)]2-, and [Mo2Fe2S2(CO)12]2- ions: high-nuclearity molybdenum-iron-sulfur clusters as potential precursors to models for the FeMo-cofactor of nitrogenase
P. A. Eldredge, K. S. Bose, D. E. Barber, R. F. Bryan, E. Sinn, A. Rheingold, and Bruce A. Averill
pp 2365 - 2375; DOI:
10.1021/ic00010a027
PDF
Kinetics and mechanism of the sulfite-induced autoxidation of cobalt(II) in aqueous azide medium
Nina Coichev and Rudi Van Eldik
pp 2375 - 2380; DOI:
10.1021/ic00010a028
PDF
Solid-state phosphorus-31 NMR and x-ray crystallographic studies of tertiary phosphines and their derivatives
Julian A. Davies, Sylvain Dutremez, and A. Alan Pinkerton
pp 2380 - 2387; DOI:
10.1021/ic00010a029
PDF
Theoretical investigation of the ground and the lowest excited states of Co(SB) complexes (SB = Schiff Base)
Alessandro Fortunelli, Renato Colle, Nazzareno Re, and Oriano Salvetti
pp 2388 - 2393; DOI:
10.1021/ic00010a030
PDF
Characterization of manganese(III) dihydrogen triphosphate dihydrate, H2MnP3O10.cntdot.2H2O
Miguel A. G. Aranda, Jesus Chaboy, and Sebastian Bruque
pp 2394 - 2397; DOI:
10.1021/ic00010a031
PDF
Luminescence studies of tris[dihydrobis(1-pyrazolyl)borato]terbium(III)
Daniel L. Reger, Pi Tai Chou, Shannon L. Studer, Steven J. Knox, Marty L. Martinez, and William E. Brewer
pp 2397 - 2402; DOI:
10.1021/ic00010a032
PDF
Control of orbital mixing in ruthenium complexes containing quinone-related ligands
Hitoshi Masui, A. B. P. Lever, and Pamela R. Auburn
pp 2402 - 2410; DOI:
10.1021/ic00010a033
PDF
Subsite-differentiated analogs of biological [4Fe-4S] clusters effected by binding of a macrocyclic polyether trithiol
M. A. Whitener, Gang Peng, and R. H. Holm
pp 2411 - 2417; DOI:
10.1021/ic00010a034
PDF
Investigations into the steric influences on the reaction mechanism of carbon dioxide insertion into metal-oxygen bonds. Carbonyl sulfide activation as a model for CO2
Donald J. Darensbourg, Brian L. Mueller, Christopher J. Bischoff, Stephen S. Chojnacki, and Joseph H. Reibenspies
pp 2418 - 2424; DOI:
10.1021/ic00010a035
PDF
Cluster synthesis. 32. Hydrogen-rich metal cluster complexes from the reaction of octadecacarbonyltetraosmiumdiplatinum with hydrogen. Synthesis and molecular structures of PtOs5(CO)16(.mu.-H)6, Pt2Os5(CO)17(.mu.-H)6, PtOs6(CO)18(.mu.-H)8, and Pt2Os7(CO)23(.mu.-H)8
Richard D. Adams, Michael P. Pompeo, and Wengan Wu
pp 2425 - 2432; DOI:
10.1021/ic00010a036
PDF
Preparation and characterization of an (N-ethylcarbamoyl)borane cyclic dimer
M. R. M. D. Charandabi, D. A. Feakes, M. L. Ettel, and Karen W. Morse
pp 2433 - 2434; DOI:
10.1021/ic00010a037
PDF
Preparation of monosubstituted borane adducts of an NH-containing (aminomethyl)phosphonate
Mallaiah Mittakanti and Karen W. Morse
pp 2434 - 2437; DOI:
10.1021/ic00010a038
PDF
Nature of the catalytically inactive cobalt hydride formed upon hydrogenation of aromatic substrates. Structure and characterization of the binuclear cobalt hydride [{iso-Pr2P(CH2)3PPr-iso2}Co]2(H)(.mu.-H)3
Michael D. Fryzuk, Jesse B. Ng, Steven J. Rettig, John C. Huffman, and Klaus Jonas
pp 2437 - 2441; DOI:
10.1021/ic00010a039
PDF
Reactivity of .mu.-dimethylamidopentahydrodiborane toward the arsenic-nitrogen bond
D. K. Srivastava, L. K. Krannich, and C. L. Watkins
pp 2441 - 2444; DOI:
10.1021/ic00010a040
PDF
Electrochemistry of (octaethylporphinato)cobalt(II), (OEP)Co, under a carbon monoxide atmosphere. Electrogeneration and characterization of [(OEP)CoIII(CO)]+
Y. Hu, B. C. Han, L. Y. Bao, X. H. Mu, and K. M. Kadish
pp 2444 - 2446; DOI:
10.1021/ic00010a041
PDF
Syn and anti isomers of dichlorobis(.mu.-1,1-bis(diphenylphosphino)ethane)dipalladium
Gabor Besenyei, Chung Li Lee, Yun Xie, and Brian R. James
pp 2446 - 2448; DOI:
10.1021/ic00010a042
PDF
Synthesis, structure, and properties of potassium bis(L-cysteinato-N,S)nickelate(II) sesquihydrate
Narayan Baidya, Dije Ndreu, Marilyn M. Olmstead, and Pradip K. Mascharak
pp 2448 - 2451; DOI:
10.1021/ic00010a043
PDF
Ordering of ligand strengths for a series of dithiolate ligands attached to platinum(II)
Ray Colton and Vanda Tedesco
pp 2451 - 2452; DOI:
10.1021/ic00010a044
PDF

Issue 11


Ligand migration during photoaquation of bis(am(m)ine)(1,4,8,11-tetraazacyclotetradecane)chromium(III) complexes
Alexander David Kirk and Darrick Heyd
pp 2453 - 2457; DOI:
10.1021/ic00011a001
PDF
Electron transfer in mixed-valence biferrocenium salts: effect of zero-point energy difference and pronounced anion dependence
Teng Yuan Dong, Chi Chang Schei, Tsui Ling Hsu, Shyi Long Lee, and Shiang Jin Li
pp 2457 - 2462; DOI:
10.1021/ic00011a002
PDF
X-ray diffraction and electric dichroism studies on the adsorption of metal complexes by a clay
Masahiro Taniguchi, Akihiko Yamagishi, and Toshitake Iwamoto
pp 2462 - 2467; DOI:
10.1021/ic00011a003
PDF
Site-selective spectroscopy of luminescent square-planar platinum(II) complexes
LouAnn Sacksteder, Eduardo Baralt, B. A. DeGraff, C. M. Lukehart, and J. N. Demas
pp 2468 - 2476; DOI:
10.1021/ic00011a004
PDF
Excited-state annihilation process involving a cyclometalated platinum(II) complex
Mauro Maestri, Diana Sandrini, Alex Von Zelewsky, and Christine Deuschel-Cornioley
pp 2476 - 2478; DOI:
10.1021/ic00011a005
PDF
Surface-mediated organometallic synthesis: preparation of platinum carbonyl [Pt3(CO)6]n2- (n = 3, 4) by the carbonylation of platinum complexes on magnesium oxide under carbon monoxide and carbon monoxide + dihydrogen
Jose Puga, Renata Patrini, Kathryn M. Sanchez, and Bruce C. Gates
pp 2479 - 2483; DOI:
10.1021/ic00011a006
PDF
Matrix isolation spectroscopic studies of hydrogen-bonded complexes of titanocene dihalides with hydrogen chloride
Bruce S. Ault
pp 2483 - 2487; DOI:
10.1021/ic00011a007
PDF
Synthesis and structural characterization of manganese(II) derivatives of the bulky, chelating bis(amido) ligands [(NMes)2SiMe2]2- and [DippNCH2CH2NDipp]2-, their neutral amine precursors, and their lithium salts (Mes = 2,4,6-Me3C6H2; Dipp = 2,6-i-Pr2C6H3)
Hong Chen, Ruth A. Bartlett, H. V. Rasika Dias, Marilyn M. Olmstead, and Philip P. Power
pp 2487 - 2494; DOI:
10.1021/ic00011a008
PDF
Pyridine and related adducts, (silox)3ML (M = scandium, titanium, vanadium, tantalum): .eta.1-pyridine-N vs .eta.2-pyridine-N,C ligation
Katharine J. Covert, David R. Neithamer, Marjanne C. Zonnevylle, Robert E. LaPointe, Christopher P. Schaller, and Peter T. Wolczanski
pp 2494 - 2508; DOI:
10.1021/ic00011a009
PDF
Oxidative addition of halogens to the quadruple bond of bis[bis(diphenylphosphino)methane]tetrahalodimolybdenum (halo = chloro, iodo, bromo): synthesis, structural characterization, and magnetic properties of Mo2Cl4I2(dppm)2, Mo2Br6(dppm)2, and Mo2I6(dppm)2
F. Albert Cotton, Lee M. Daniels, Kim R. Dunbar, Larry R. Falvello, Charles J. O'Connor, and Andrew C. Price
pp 2509 - 2514; DOI:
10.1021/ic00011a010
PDF
Synthesis and structure of [M(N-methylimidazole)6]S8 (M = manganese, iron, nickel, magnesium). Polysulfide salts prepared by the reaction N-methylimidazole + metal powder + sulfur
Somanath Dev, Emannuel Ramli, Thomas B. Rauchfuss, and Scott R. Wilson
pp 2514 - 2519; DOI:
10.1021/ic00011a011
PDF
Polydentate ligands containing phosphorus. 13. Synthesis and molecular structure of (tri-n-butylphosphine)[tris(diphenylthiophosphinoyl)methanido]silver(I), (n-Bu)3PAg{[(S)PPh2]3C}
Samuel O. Grim, Samuel A. Sangokoya, Arnold L. Rheingold, William McFarlane, Ian J. Colquhoun, and Richard D. Gilardi
pp 2519 - 2522; DOI:
10.1021/ic00011a012
PDF
Anion binding and pentacoordination in zinc(II) complexes
Miquel Sola, Agusti Lledos, Miquel Duran, and Juan Bertran
pp 2523 - 2527; DOI:
10.1021/ic00011a013
PDF
Stepwise ligand-additivity effects on electrode potentials and charge-transfer spectra in hexahalide, mixed halide/nitrile, and hexakis(nitrile) complexes of ruthenium(IV), -(III), and -(II)
Colleen M. Duff and Graham A. Heath
pp 2528 - 2535; DOI:
10.1021/ic00011a014
PDF
Evidence for intermediate (S = 1) spin state stabilization in bis(4,4'-diphenyl-2,2'-bipyridyl)bis(isothiocyanato)iron and bis(4,4'-diphenyl-2,2'-bipyridyl)bis(isoselenocyanato)iron from susceptibility, infrared, and iron-57 Moessbauer data
D. C. Figg, R. H. Herber, and I. Felner
pp 2535 - 2540; DOI:
10.1021/ic00011a015
PDF
Homo- and heteropolychalcogenide anions Ch2-, HCh-, Ch22-, Ch32-, and Ch42- (Ch = selenium and/or tellurium): solution proton, selenium-77, tellurium-123 and -125 NMR study
Mar Bjoergvinsson and Gary J. Schrobilgen
pp 2540 - 2547; DOI:
10.1021/ic00011a016
PDF
Three-coordinate iron complexes: x-ray structural characterization of the iron amide-bridged dimers [Fe(NR2)2]2 (R = SiMe3, C6H5) and the adduct Fe[N(SiMe3)2]2(THF) and determination of the association energy of the monomer Fe{N(SiMe3)2}2 in solution
Marilyn M. Olmstead, Philip P. Power, and Steven C. Shoner
pp 2547 - 2551; DOI:
10.1021/ic00011a017
PDF
Further investigation of molecular, magnetic, and electronic structures of 2-hydroxypyridinate complexes of diruthenium(II)
F. Albert Cotton, Tong Ren, and Judith L. Eglin
pp 2552 - 2558; DOI:
10.1021/ic00011a018
PDF
Synthesis and characterization of a complex with a very long osmium-osmium triple bond, dichlorotetrakis(di-p-tolylformamidinato)diosmium
F. Albert Cotton, Tong Ren, and Judith L. Eglin
pp 2559 - 2563; DOI:
10.1021/ic00011a019
PDF
Chemical intercalation of sodium into niobium chloride, .alpha.-Nb3Cl8
John R. Kennedy and A. Simon
pp 2564 - 2567; DOI:
10.1021/ic00011a020
PDF
The possible existence of a heteronuclear octahedral hypercloso cluster: can nitrogen or an alkyne be complexed through a M4Ln square?
Samia Kahlal, Jean Francois Halet, and Jean Yves Saillard
pp 2567 - 2569; DOI:
10.1021/ic00011a021
PDF
Hydride locations and bonding studies in some silyl polyhydride rhenium complexes
Zhenyang Lin and Michael B. Hall
pp 2569 - 2572; DOI:
10.1021/ic00011a022
PDF
Dinuclear platinum(II), palladium(II), nickel(II), and copper(II) complexes of 3,5-pyrazoledicarboxylic acid
J. Carlos Bayon, Pedro Esteban, Gemma Net, Paul G. Rasmussen, Kenneth N. Baker, Carl W. Hahn, and Melanie M. Gumz
pp 2572 - 2574; DOI:
10.1021/ic00011a023
PDF
Halogenoargentate(I) with unusual coordination geometries. Synthesis and structure of potassium-crypt salts of chloro-, bromo- and iodoargentates(I), including the first example of a two-coordinated chloroargentate(I) in the solid state
Goeran Helgesson and Susan Jagner
pp 2574 - 2577; DOI:
10.1021/ic00011a024
PDF
Emission and photochemical reactivity in fluorescent arene complexes of cyclopentadienylruthenium(II). Requirements for an emissive CpRu(arene)+ complex [Erratum to document cited in CA114(11):102336d]
Robert S. Koefod and Kent R. Mann
pp 2578 - 2578; DOI:
10.1021/ic00011a025
PDF
Spin transition in iron Fe(py)2L(NCS)2 complexes where py = pyridine and L = 2,2'-bipyrimidine (bpym) and 1,10-phenanthroline (phen): magnetic, calorimetric, and Moessbauer-effect investigation. Crystal structure of [Fe(py)2bpym(NCS)2].cntdot.0.25py [Erratum to document cited in CA113(22):203847f]
Renee Claude, Jose Antonio Real, Jacqueline Zarembowitch, Olivier Kahn, Lahcene Ouahab, Daniel Grandjean, Kamel Boukheddaden, Francois Varret, and Ary Dworkin
pp 2578 - 2578; DOI:
10.1021/ic00011a026
PDF

Issue 12


"Colloidal bismuth subcitrate" (CBS): isolation and structural characterization of the active substance against Helicobacter pylori, a causal factor of gastric diseases
Wolfgang A. Herrmann, Eberhardt Herdtweck, and Liba Pajdla
pp 2579 - 2581; DOI:
10.1021/ic00012a001
PDF
Remarkable solvent effect on the shape-selective oxidation of olefins catalyzed by iron(III) porphyrins
Yoshihito Watanabe, Kazuya Yamaguchi, Isao Morishima, Katsuomi Takehira, Masao Shimizu, Takashi Hayakawa, and Hideo Orita
pp 2581 - 2582; DOI:
10.1021/ic00012a002
PDF
Mononuclear cis-carbonyloxotungsten(IV) complexes of hydrotris(3,5-dimethyl-1-pyrazolyl)borate
S. G. Feng, Li Luan, Peter White, M. S. Brookhart, Joseph L. Templeton, and Charles G. Young
pp 2582 - 2584; DOI:
10.1021/ic00012a003
PDF
Linear trimeric and monomeric octahedral vanadium(II) diphenylacetate complexes
Jilles J. H. Edema, Shoukang Hao, Sandro Gambarotta, and Corinne Bensimon
pp 2584 - 2586; DOI:
10.1021/ic00012a004
PDF
Superconductivity at 2.8 K and 1.5 kbar in .kappa.-(BEDT-TTF)2Cu2(CN)3: the first organic superconductor containing a polymeric copper cyanide anion
Urs Geiser, Hau H. Wang, K. Douglas Carlson, Jack M. Williams, Henry A. Charlier Jr., James E. Heindl, George A. Yaconi, Bradley J. Love, Michael W. Lathrop, and et al.
pp 2586 - 2588; DOI:
10.1021/ic00012a005
PDF
Tetraoxolene radical stabilization by the interaction with transition-metal ions
Andrea Dei, Dante Gatteschi, Luca Pardi, and Umberto Russo
pp 2589 - 2594; DOI:
10.1021/ic00012a006
PDF
Quasirelativistic effects in the electronic structure of the thiomolybdate and thiotungstate complexes of nickel, palladium, and platinum
B. D. El-Issa and M. M. Zeedan
pp 2594 - 2605; DOI:
10.1021/ic00012a007
PDF
Synthesis, structural characterization, and reactivity toward weak, protic electrophiles of di-.mu.-hydroxytetrakis(pentafluorophenyl)dipalladate(2-)
Gregorio Lopez, Jose Ruiz, Gabriel Garcia, Consuelo Vicente, Jaime Casabo, Elies Molins, and Carlos Miravitlles
pp 2605 - 2610; DOI:
10.1021/ic00012a008
PDF
Synthesis, characterization, and molecular structures of binary and ternary copper(I) complexes with 1,5-cyclooctadiene (cod): [Cu(cod)2]ClO4 and [cu(cod)(2,2'-bipyridine)]PF6
Megumu Munakata, Susumu Kitagawa, Hisao Shimono, and Hideki Masuda
pp 2610 - 2614; DOI:
10.1021/ic00012a009
PDF
Effects of phosphine on structure and reductive elimination reactions of (C5Me5)Rh(PR3)PhH complexes
William D. Jones and Valerie L. Kuykendall
pp 2615 - 2622; DOI:
10.1021/ic00012a010
PDF
Synthesis and characterization of mono- and bis(silyl)iridium bis(phosphine) complexes
Mary K. Hays and Richard Eisenberg
pp 2623 - 2630; DOI:
10.1021/ic00012a011
PDF
Rearrangement of a phosphorus-carbon-phosphorus bridge to a phosphorus-nitrogen-phosphorus bridge via organogermanium- or organotin-assisted cleavage of a phosphorus-carbon bond. Crystal and molecular structure of the imine salt (CH3)Ph2PNPPh2(NH2)+Cl-
Kattesh V. Katti, A. A. Pinkerton, and Ronald G. Cavell
pp 2631 - 2633; DOI:
10.1021/ic00012a012
PDF
Synthesis and characterization of the neutral three-coordinate [aluminum and gallium] thiolate complexes Al[S(2,4,6-tert-Bu3C6H2)]3 and Ga[S(2,4,6-tert-Bu3C6H2)]3
Karin Ruhlandt-Senge and Philip P. Power
pp 2633 - 2637; DOI:
10.1021/ic00012a013
PDF
Oxidation of ethylenediaminetetraacetic acid by permanganate ion: a kinetic study
Rathindra N. Bose, Charlene Keane, Anthony Xidis, John W. Reed, Ruiming Li, H. Tu, and Peter L. Hamlet
pp 2638 - 2642; DOI:
10.1021/ic00012a014
PDF
Cryoelectrochemical study of the cleavage of radical anions of diiron and diruthenium carbonyl dimers
E. F. Dalton, Stanton Ching, and Royce W. Murray
pp 2642 - 2648; DOI:
10.1021/ic00012a015
PDF
Reactivity of chloro- and aqua(diethylenetriamine)platinum(II) ions with glutathione, S-methylglutathione, and guanosine 5'-monophosphate in relation to the antitumor activity and toxicity of platinum complexes
Milos I. Djuran, Edwin L. M. Lempers, and Jan Reedijk
pp 2648 - 2652; DOI:
10.1021/ic00012a016
PDF
Synthesis and structure of transition-metal bis(porphyrinato) complexes. Characterization of Zr(TPP)2 and Zr(OEP)2
Kimoon Kim, Won S. Lee, Hee Joon Kim, Sung Hee Cho, Gregory S. Girolami, Philip A. Gorlin, and Kenneth S. Suslick
pp 2652 - 2656; DOI:
10.1021/ic00012a017
PDF
Models of amide-cysteine hydrogen bonding in rubredoxin: hydrogen bonding between amide and benzenethiolate in [(CH3)3NCH2CONH2]2[Co(SC6H5)4].cntdot.1/2CH3CN and [(CH3)3NCH2CONH2][SC6H5]
Marc Anton Walters, John C. Dewan, Caroline Min, and Shirley Pinto
pp 2656 - 2662; DOI:
10.1021/ic00012a018
PDF
Technetium(III) complexes with the tetradentate "umbrella" ligand tris(o-mercaptophenyl)phosphinate: x-ray structural characterization of Tc(P(o-C6H4S)3)(CNC3H7) and Tc(P(o-C6H4S)3)(CNC3H7)2
Nadine De Vries, Jessica Cook, Alun G. Jones, and Alan Davison
pp 2662 - 2665; DOI:
10.1021/ic00012a019
PDF
Structure of the linear trinuclear complex hexakis(acetato)bis(2,2'-bipyridine)trimanganese (II). Determination of the J electron-exchange parameter through magnetic susceptibility and high-field magnetization measurements
S. Menage, S. E. Vitols, P. Bergerat, E. Codjovi, O. Kahn, J. J. Girerd, M. Guillot, X. Solans, and T. Calvet
pp 2666 - 2671; DOI:
10.1021/ic00012a020
PDF
Synthesis and structural elucidation of novel uranyl-crown ether compounds isolated from nitric, hydrochloric, sulfuric, and acetic acids
Robin D. Rogers, Andrew H. Bond, William G. Hipple, Andrew N. Rollins, and Rodger F. Henry
pp 2671 - 2679; DOI:
10.1021/ic00012a021
PDF
Magnetic order and crystal chemistry of neodymium cerium copper oxide, Nd2-xCexCuO4-.delta.
Matthew J. Rosseinsky, Kosmas Prassides, and Peter Day
pp 2680 - 2687; DOI:
10.1021/ic00012a022
PDF
Effects of ligand planarity and peripheral charge on intercalative binding of Ru(2,2'-bipyridine)2L2+ to calf thymus DNA
Robert J. Morgan, Sanjoy Chatterjee, A. David Baker, and Thomas C. Strekas
pp 2687 - 2692; DOI:
10.1021/ic00012a023
PDF
Cubane-type mixed-metal clusters with molybdenum-nickel-sulfur Mo3NiS4 cores. Syntheses, characterization, and x-ray structures of [Mo3NiS4(H2O)10](CH3C6H4SO3)4.7H2O and Ca2.5[Mo3NiS4(Hnta)(nta)2Cl].14H2O
Takashi Shibahara, Mikio Yamasaki, Haruo Akashi, and Tsuneo Katayama
pp 2693 - 2699; DOI:
10.1021/ic00012a024
PDF
Reactions of polycyano compounds with chlorine fluoride
Jerry Foropoulos and Jeanne M. Shreeve
pp 2699 - 2701; DOI:
10.1021/ic00012a025
PDF
Crystal structure and magnetic properties of bis(isothiocyanato)bis(pyrazine)iron polymer, a 2D sheetlike polymer
Jose Antonio Real, Giovanni De Munno, M. Carmen Munoz, and Miguel Julve
pp 2701 - 2704; DOI:
10.1021/ic00012a026
PDF
Synthesis and characterization of cyanoiron(II) complexes bound to the bridging ligand tetrakis(2-pyridyl)-1,4-diazine (tpd) [Erratum to document cited in CA113(22):203865k]
Ronald R. Ruminski and Jaqueline L. Kiplinger
pp 2704 - 2704; DOI:
10.1021/ic00012a027
PDF

Issue 13


A butterfly cluster containing a bridging acetamidato ligand. Synthesis, structure, and bonding for [MnRu3(CO)12(.eta.2-.mu.3-NC(.mu.-O)CH3)]-
Eric J. Voss, Michal Sabat, and Duward F. Shriver
pp 2705 - 2707; DOI:
10.1021/ic00013a001
PDF
New synthetic route to the hydridospherosiloxanes Oh-H8Si8O12 and D5h-H10Si10O15
Pradyot A. Agaskar
pp 2707 - 2708; DOI:
10.1021/ic00013a002
PDF
Conformational features and coordination properties of functionalized cyclodextrins. Formation, stability, and structure of proton and copper(II) complexes of histamine-bearing .beta.-cyclodextrin in aqueous solution
Raffaele P. Bonomo, Vincenzo Cucinotta, Franca D'Alessandro, Giuseppe Impellizzeri, Giuseppe Maccarrone, Graziella Vecchio, and Enrico Rizzarelli
pp 2708 - 2713; DOI:
10.1021/ic00013a003
PDF
Sterically hindered nickel(II) and iron(II) lacunar cyclidene complexes containing gem-dimethyl groups on their saturated chelate rings
Peter A. Padolik, Alan J. Jircitano, Nathaniel W. Alcock, and Daryle H. Busch
pp 2713 - 2724; DOI:
10.1021/ic00013a004
PDF
Synthesis, electron spin resonance spectroscopy, and shape-determining angle analysis of superstructured copper(II) Schiff base complexes containing persistent voids
William M. Davis, Sharlene J. Dzugan, Mark W. Glogowski, Rita Delgado, and Daryle H. Busch
pp 2724 - 2731; DOI:
10.1021/ic00013a005
PDF
Oxygenation of a copper(I) complex of a binucleating macrocyclic Schiff base ligand derived from 1,4,7-triazaheptane and furan-2,5-dicarboxaldehyde
M. Patrick Ngwenya, Dian Chen, Arthur E. Martell, and Joseph Reibenspies
pp 2732 - 2736; DOI:
10.1021/ic00013a006
PDF
Stabilities of gallium(III), iron(III), and indium(III) chelates of hydroxyaromatic ligands with different overall charges
Ramunas Motekaitis, Yizhen Sun, Arthur E. Martell, and Michael J. Welch
pp 2737 - 2740; DOI:
10.1021/ic00013a007
PDF
Metallobiochemistry of magnesium. Coordination complexes with biological substrates: site specificity, kinetics and thermodynamics of binding, and implications for activity
J. A. Cowan
pp 2740 - 2747; DOI:
10.1021/ic00013a008
PDF
Structural, equilibrium, and kinetic study of the complexation of sodium(I) by the cryptand 4,7,13,16-tetraoxa-1,10-diazabicyclo[8.8.5]tricosane, C22C5
Philip Clarke, Stephen F. Lincoln, and Edward R. T. Tiekink
pp 2747 - 2751; DOI:
10.1021/ic00013a009
PDF
Reactions of nitroplatinum complexes. 1. Nitrogen-15 and platinum-195 NMR spectra of platinum(II) nitrite complexes
Trevor G. Appleton, Kevin J. Barnham, John R. Hall, and Michael T. Mathieson
pp 2751 - 2756; DOI:
10.1021/ic00013a010
PDF
Substitution of a nitrile by phosphorus-donor ligands in [Re3(.mu.-H)3(CO)11(NCMe)] and axial-equatorial isomerization of the entering ligands: a kinetic study
Tiziana Beringhelli, Giuseppe D'Alfonso, Anna P. Minoja, and Maria Freni
pp 2757 - 2763; DOI:
10.1021/ic00013a011
PDF
Base hydrolysis of acidato pentakis(methylamine) complexes of cobalt(III): evidence for the pentacoordinated intermediate Co(NH2CH3)4(NHCH3)2+ exhibiting a lifetime of .apprxeq. 1 ns
Francois P. Rotzinger
pp 2763 - 2772; DOI:
10.1021/ic00013a012
PDF
Near-infrared spectra of barium chloride bis(deuterium oxide) at 10 K. A local-mode approach
Paul J. McCarthy and Ian M. Walker
pp 2772 - 2776; DOI:
10.1021/ic00013a013
PDF
Comparative study of polyoxometalates and semiconductor metal oxides as catalysts. Photochemical oxidative degradation of thioethers
R. Carlisle Chambers and Craig L. Hill
pp 2776 - 2781; DOI:
10.1021/ic00013a014
PDF
MS X.alpha. studies on the colors of pentaphenylbismuth, hexachloroplumbate(2-) and tetrathiotungstate(2-): are relativistic effects on the LUMO important?
B. D. El-Issa, P. Pyykko, and H. M. Zanati
pp 2781 - 2787; DOI:
10.1021/ic00013a015
PDF
Syntheses and structures of the phenylbismuth/transition-metal carbonyl compounds [PPN][Ph2BiFe(CO)4], (Ph2Bi)2Fe(CO)4, [PhBiFe(CO)4]2 and Ph2BiMn(CO)5
Juanita M. Cassidy and Kenton H. Whitmire
pp 2788 - 2795; DOI:
10.1021/ic00013a016
PDF
Hydrotris[3,(2'-thienyl)pyrazol-1-yl]borate: a ligand of remarkably low steric requirements
Joseph C. Calabrese, Peter J. Domaille, Swiatoslaw Trofimenko, and Gary J. Long
pp 2795 - 2801; DOI:
10.1021/ic00013a017
PDF
Strong ferromagnetism between copper(II) ions separated by 6.7 .ANG. in a new phthalato-bridged copper(II) binuclear complex
Saleh K. Shakhatreh, Evangelos G. Bakalbassis, Irene Bruedgam, Hans Hartl, Jerzy Mrozinski, and Constantinos A. Tsipis
pp 2801 - 2806; DOI:
10.1021/ic00013a018
PDF
A new ferric orthoarsenate hydrate: structure and magnetic ordering of FeAsO4.cntdot.3/4H2O
R. J. B. Jakeman, M. J. Kwiecien, W. M. Reiff, A. K. Cheetham, and C. C. Torardi
pp 2806 - 2811; DOI:
10.1021/ic00013a019
PDF
New alkoxides of copper and the alkaline and alkaline-earth metals. Crystal structure of Na2Cu[OCH(CF3)2]4
A. P. Purdy, C. F. George, and J. H. Callahan
pp 2812 - 2819; DOI:
10.1021/ic00013a020
PDF
Role of solvent in photoredox reactions of cobalt(III) am(m)ine complexes
Scott K. Weit, Paul A. Grutsch, and Charles Kutal
pp 2819 - 2821; DOI:
10.1021/ic00013a021
PDF
An unsymmetrical binuclear ruthenium(II) complex of tris(2-pyridyl)-1,3,5-triazine and its identification by proton NMR spectroscopy
Sara Chirayil, Vidyadhar Hegde, Yurngdong Jahng, and Randolph P. Thummel
pp 2821 - 2823; DOI:
10.1021/ic00013a022
PDF
Oxidation of thiocyanate by thallium(III) in aqueous solution studied by multinuclear NMR spectroscopy. Evidence for a Tl(SCN)2+ intermediate
Johan Blixt, Raj K. Dubey, and Julius Glaser
pp 2824 - 2826; DOI:
10.1021/ic00013a023
PDF
Platinum(II) binding to the N1 and N7 ring nitrogens of guanosine. Kinetics of complexation of aquated (diethylenetriamine)platinum(II) with 1- and 7-methylguanosines
Mikko Ritala and Jorma Arpalahti
pp 2826 - 2828; DOI:
10.1021/ic00013a024
PDF
High-pressure mass spectrometric observation of metal carbonyl/alkyl adduct ions of novel structure
C. E. C. A. Hop and T. B. McMahon
pp 2828 - 2830; DOI:
10.1021/ic00013a025
PDF

Issue 14


Synthesis, structure, and electrochemistry of a novel dinickel(II) complex [Ni2L(CH3OH)2(ClO4)2].cntdot.2(C2H5)3NHClO4 derived from a tetraamino-diphenolic macrocyclic ligand (H2L) that exhibits stepwise two-electron oxidation and two-electron reduction
Ramprasad Das and Kamalaksha Nag
pp 2831 - 2833; DOI:
10.1021/ic00014a001
PDF
A high-valent oxomanganese dimer containing bridging and terminal inorganic phosphate ligands
Joseph E. Sarneski, Mary Didiuk, H. Holden Thorp, Robert H. Crabtree, Gary W. Brudvig, J. W. Faller, and Gayle K. Schulte
pp 2833 - 2835; DOI:
10.1021/ic00014a002
PDF
Preparation of phosphoraniminato complexes containing polypyridyl ligands. Nitrogen atom transfer from dichloronitrido(terpyridine)osmium(1+)
Mohammed Bakir, Peter S. White, Angelos Dovletoglou, and Thomas J. Meyer
pp 2835 - 2836; DOI:
10.1021/ic00014a003
PDF
Organotransition-metal metallacarboranes. 20. Fluoride-catalyzed carbon-silicon bond cleavage in Cp*Co(Me3Si)2C2B4H4. Synthesis of parent Cp*CoC2B4H6 and conversion to C-substituted Cp*CoRR'C2B4H4 derivatives
Mark A. Benvenuto and Russell N. Grimes
pp 2836 - 2838; DOI:
10.1021/ic00014a004
PDF
First easily reproduced solution-phase synthesis and confirmation of superconductivity in the fullerene KxC60 (Tc = 18.0 .+-. 0.1 K)
H. Hau Wang, Aravinda M. Kini, Brad M. Savall, K. Douglas Carlson, Jack M. Williams, Keith R. Lykke, Peter Wurz, Deborah Holmes Parker, Michael J. Pellin, and et al.
pp 2838 - 2839; DOI:
10.1021/ic00014a005
PDF
Ligand field of conjugated bidentate ligands parametrized by the angular overlap model
Claus E. Schaeffer and Hideo Yamatera
pp 2840 - 2853; DOI:
10.1021/ic00014a006
PDF
Steric constraints inside the metal-coordination sphere as revealed by diastereotopic splitting of methylene protons
Giuseppe Giannini and Giovanni Natile
pp 2853 - 2855; DOI:
10.1021/ic00014a007
PDF
Negative electron affinities of nonmetallic elements
Ralph G. Pearson
pp 2856 - 2858; DOI:
10.1021/ic00014a008
PDF
Pair potentials, electron-pair repulsions, and the geometries of molecules
Jeremy K. Burdett and Thomas F. Fassler
pp 2859 - 2868; DOI:
10.1021/ic00014a009
PDF
Photoluminescence and electronic structure of thallium(1+) dicyanoaurate(1-): evidence for relativistic effects in thallium-gold and gold-gold interactions
Zerihun Assefa, Frank DeStefano, Mohammad A. Garepapaghi, Joseph H. LaCasce, Steve Ouellete, Michael R. Corson, Jeffrey K. Nagle, and Howard H. Patterson
pp 2868 - 2876; DOI:
10.1021/ic00014a010
PDF
Extension of molecular mechanics to high-coordinate metal complexes. Calculation of the structures of aqua and nitrato complexes of lanthanide(III) metal ions
Benjamin P. Hay
pp 2876 - 2884; DOI:
10.1021/ic00014a011
PDF
Synthesis and spectroscopic and x-ray structural characterization of the first homoleptic transition-metal boryloxides [Mn(OBTrip2)(.mu.-OBTrip2)]2 and [Fe(OBMes2)(.mu.-OBMes2)]2
Hong Chen, Philip P. Power, and Steven C. Shoner
pp 2884 - 2888; DOI:
10.1021/ic00014a012
PDF
Synthesis and characterization of the homoleptic aryloxides [M{O(2,4,6-tert-Bu3C6H2)}2]2 (M = manganese, iron), the adducts [Mn(OCPh3)2(py)2] and [Fe(OCPh3)2(THF)2], and the mixed complex [Fe{N(SiMe3)2}{.mu.-O(2,4,6-tert-Bu3C6H2)}]2: evidence for primarily ionic metal-oxygen bonding
Ruth A. Bartlett, Jeffrey J. Ellison, Philip P. Power, and Steven C. Shoner
pp 2888 - 2894; DOI:
10.1021/ic00014a013
PDF
Structural and electrochemical properties of binuclear complexes containing 1,10-phenanthroline-5,6-diolate as a bridging ligand
Glenn A. Fox, Samaresh Bhattacharya, and Cortlandt G. Pierpont
pp 2895 - 2899; DOI:
10.1021/ic00014a014
PDF
Cluster synthesis. 33. New platinum-osmium carbonyl cluster complexes from Pt2Os5(CO)17(.mu.-H)6: synthesis and characterization of PtOs5(CO)15(.mu.3-S)(.mu.-H)6, PtOs5(CO)18(.mu.-H)4, and PtOs4(CO)15(.mu.-H)2
Richard D. Adams, Michael P. Pompeo, and Wengan Wu
pp 2899 - 2905; DOI:
10.1021/ic00014a015
PDF
Charge distribution in the quinone complexes of osmium: synthesis and characterization of the Os(PPh3)2(Q)Cl2 and Os(PPh3)2(Q)2 (Q = 3,5-di-tert-butyl-1,2-quinone, tetrachloro-1,2-quinone) series
Samaresh Bhattacharya and Cortlandt G. Pierpont
pp 2906 - 2911; DOI:
10.1021/ic00014a016
PDF
Vitamin B6 model reactions. 4. Stereoelectronic catalysis of carbon-hydrogen bond-breaking reactions and crystal and molecular structure of tetramethylammonium bis(pyridoxylideneglycinato)cobaltate(III)-4.5-water
Andrew G. Sykes, Raymond D. Larsen, James R. Fischer, and Edwin H. Abbott
pp 2911 - 2916; DOI:
10.1021/ic00014a017
PDF
A new type of divalent metal nucleosidate complex: crystal structure of trans-tetraaquobis(xanthosinato)zinc(II) dihydrate
Miguel Quiros, Juan M. Salas, M. Purificacion Sanchez, Juan R. Alabart, and Rene Faure
pp 2916 - 2921; DOI:
10.1021/ic00014a018
PDF
Electronic effects of bis(acetylacetone) in ruthenium(II) and ruthenium(III) complexes
Tai Hasegawa, T. C. Lau, Henry Taube, and W. P. Schaefer
pp 2921 - 2928; DOI:
10.1021/ic00014a019
PDF
Ligand tuning effects upon the multielectron reduction and single-electron oxidation of (bi)pyridyl complexes of cis- and trans-dioxorhenium(V): redox thermodynamics, preliminary electrochemical kinetics, and charge-transfer absorption spectroscopy
M. S. Ram, Lisa M. Jones, Howard J. Ward, Ying Hsiow Wong, Christopher S. Johnson, P. Subramanian, and Joseph T. Hupp
pp 2928 - 2938; DOI:
10.1021/ic00014a020
PDF
Synthesis and voltammetry of two series of isonitrile/halide complexes of ruthenium: RuX6-n(CNBu-tert)n (X = Cl, Br)
Colleen M. Duff and Roy A. Schmid
pp 2938 - 2941; DOI:
10.1021/ic00014a021
PDF
Formation of thin polymeric films by electropolymerization. Reduction of metal complexes containing bromomethyl-substituted derivatives of 2,2'-bipyridine
Sharon Gould, Geoffrey F. Strouse, Thomas J. Meyer, and B. Patrick Sullivan
pp 2942 - 2949; DOI:
10.1021/ic00014a022
PDF
Photochemistry of chlorochromium(III) tetraphenylporphyrinate in acetone. Studies on photodissociation of the axial acetone in the temperature range 180-295 K by laser photolysis
Minoru Yamaji
pp 2949 - 2952; DOI:
10.1021/ic00014a023
PDF
Reduction of borane THF by alkali metal (potassium, rubidium, cesium) and ytterbium mercury amalgams to form salts of octahydrotriborate(1-); a simple procedure for the synthesis of tetraborane(10)
Tara G. Hill, Robert A. Godfroid, James P. White, and Sheldon G. Shore
pp 2952 - 2954; DOI:
10.1021/ic00014a024
PDF
Intramolecular carbonylation of Ni(S2COR')2 in fused PR3. An improved preparation of nickel carboyl phosphine Ni(CO)2(PR3)2
Loreto Ballester, Angel Gutierrez-Alonso, Soledad Perez-Serrano, and M. Felisa Perpinan
pp 2954 - 2955; DOI:
10.1021/ic00014a025
PDF
Convenient syntheses of unsymmetrically B-substituted borazines
J. Bai and Kurt Niedenzu
pp 2955 - 2956; DOI:
10.1021/ic00014a026
PDF

Issue 15


Gas phase copper chalcogenide cluster ions, formed by laser-ablation
John H. El Nakat, Ian G. Dance, Keith J. Fisher, and Gary D. Willett
pp 2957 - 2958; DOI:
10.1021/ic00015a001
PDF
An isostructural series of molecular metamagnets: the organometallic charge-transfer salts decamethylmanganocenium bis[bis(trifluoromethyl)ethylenedithiolato]nickelate, -palladate, and -platinate
William E. Broderick, Julia A. Thompson, and Brian M. Hoffman
pp 2958 - 2960; DOI:
10.1021/ic00015a002
PDF
Unusual coordination properties of trialkoxysilyl groups in metal cluster complexes. Synthesis, structure, and reactivity of the osmium carbonyl hydrido cluster Os3(CO)9[.mu.3-.eta.3-Si(OEt)3](.mu.-H)
Richard D. Adams, Jeffrey E. Cortopassi, and Michael P. Pompeo
pp 2960 - 2961; DOI:
10.1021/ic00015a003
PDF
Superconductivity at 28.6 K in a rubidium-C60 fullerene compound, RbxC60, synthesized by a solution-phase technique
H. Hau Wang, Aravinda M. Kini, Brad M. Savall, K. Douglas Carlson, Jack M. Williams, Michael W. Lathrop, Keith R. Lykke, Deborah Holmes Parker, Peter Wurz, and et al.
pp 2962 - 2963; DOI:
10.1021/ic00015a004
PDF
Nonempirical study of the structure and stability of beryllium, magnesium, and calcium borohydrides
Rosanna Bonaccorsi, Oleg P. Charkin, and Jacopo Tomasi
pp 2964 - 2969; DOI:
10.1021/ic00015a005
PDF
Multiple bonding in perfluorodiphosphene (FPPF) and perfluorodiphosphinylidene (PPF2)
Suqian Jin, Brenda Thies Colegrove, and Henry F. Schaefer
pp 2969 - 2977; DOI:
10.1021/ic00015a006
PDF
Electronic structure of hexaamminechromium(3+) and substituted chromium(III) ammine compounds
L. G. Vanquickenborne, B. Coussens, D. Postelmans, A. Ceulemans, and K. Pierloot
pp 2978 - 2986; DOI:
10.1021/ic00015a007
PDF
Time-resolved resonance Raman spectroscopy of bis(2,9-dimethyl-1,10-phenanthroline)copper(1+) in solution
Keith C. Gordon and John J. McGarvey
pp 2986 - 2989; DOI:
10.1021/ic00015a008
PDF
Cocondensation reaction of arsine and fluorine: matrix infrared spectrum of fluoroarsine
Lester Andrews and Thomas C. McInnis
pp 2990 - 2993; DOI:
10.1021/ic00015a009
PDF
Luminescence and absorption spectroscopy of Re(O)I(RC.tplbond.CR)2 and [Re(O)PPh3(RC.tplbond.CR)2]SbF6 (R = CH3, C6H5)
Christian Reber and Jeffrey I. Zink
pp 2994 - 2996; DOI:
10.1021/ic00015a010
PDF
Solid-state phosphorus-31 NMR studies of mercury(II) phosphonates. Anisotropies of the phosphorus-31 chemical shift and the phosphorus-31-mercury-199 indirect spin-spin coupling
William P. Power, Michael D. Lumsden, and Roderick E. Wasylishen
pp 2997 - 3002; DOI:
10.1021/ic00015a011
PDF
Biomimetic oxidation studies. 5. Mechanistic aspects of alkane functionalization with iron and iron-oxygen (Fe2O and Fe4O2) complexes in the presence of hydrogen peroxide
Richard H. Fish, Mark S. Konings, Kenneth J. Oberhausen, Raymond H. Fong, Winnie M. Yu, George Christou, John B. Vincent, DeAnna K. Coggin, and Robert M. Buchanan
pp 3002 - 3006; DOI:
10.1021/ic00015a012
PDF
Spectroscopic studies of the copper sites in wild-type Pseudomonas stutzeri N2O reductase and in an inactive protein isolated from a mutant deficient in copper-site biosynthesis
David M. Dooley, Michele A. McGuirl, Amy C. Rosenzweig, Judith A. Landin, Robert A. Scott, Walter G. Zumft, Frank Devlin, and Philip J. Stephens
pp 3006 - 3011; DOI:
10.1021/ic00015a013
PDF
Stoichiometry of electron uptake and the effect of anions and pH on the molybdenum and heme reduction potentials of sulfite oxidase
Jack T. Spence, Cary A. Kipke, John H. Enemark, and Roger A. Sunde
pp 3011 - 3015; DOI:
10.1021/ic00015a014
PDF
Aqueous chemistry of mixed-amine cis- and transplatin analogues. Intramolecular preference for a kinetic six-membered ring over a thermodynamic five-membered ring ortho-platination product
Patrick J. Bednarski, Edmund Ehrensperger, Helmut Schoenenberger, and Thomas Burgemeister
pp 3015 - 3025; DOI:
10.1021/ic00015a015
PDF
Multidentate Lewis acids. Adducts of monodentate and bidentate vanadyl dichloride alkoxides with ketones
Viet Minh Tan Phan, Vijay Sharma, and James D. Wuest
pp 3026 - 3032; DOI:
10.1021/ic00015a016
PDF
A tetranuclear tervalent platinum complex with .alpha.-pyrrolidonate and deprotonated ammine bridging ligands, [(NO3)(NH3)2Pt(III)(C4H6NO)2Pt(III)(NH3)(.mu.-NH2)]2(NO3)4
Kazuko Matsumoto and Kazuo Harashima
pp 3032 - 3034; DOI:
10.1021/ic00015a017
PDF
Dithiocarbonate route to 1,2-dithiolene complexes of molybdenum and tungsten
Xiaoguang Yang, Gavin K. W. Freeman, Thomas B. Rauchfuss, and Scott R. Wilson
pp 3034 - 3038; DOI:
10.1021/ic00015a018
PDF
Electrochemical behavior of [Cp'2Fe2S4] and [Cp'2Fe2S4](PF6)2 (Cp' = .eta.5-C5Me5): structural change of the Fe2S4 core accompanied by a change of redox state
Shinji Inomata, Hiromi Tobita, and Hiroshi Ogino
pp 3039 - 3043; DOI:
10.1021/ic00015a019
PDF
Electrochemical and spectral characterization of the "square scheme" for the substitution of N-methylpyrazinium cation on the ethylenediaminetetraacetate complexes of ruthenium(III) and ruthenium(II)
Koiti Araki, Ching Fong Shu, and Fred C. Anson
pp 3043 - 3047; DOI:
10.1021/ic00015a020
PDF
Redox properties of tricarbonyl (3,5-di-tert-butylcatecholato) manganate(1-): formation and characterization of a four-membered redox series
Frantisek Hartl and Antonin Vlcek
pp 3048 - 3053; DOI:
10.1021/ic00015a021
PDF
Macrocycles incorporating sulfur and nidocarborane cages: reactivity toward nickel(II) and palladium(II). Molecular structures of Pd{7,8-.mu.-(S(CH2CH2OCH2CH2OCH2CH2OCH2CH2)S)C2B9H10}2 and Pd{P(C6H5)3}Cl{7,8-.mu.-(SCH2CH2S)C2B9H10}
F. Teixidor, Jaume Casabo, Clara Vinas, Eustaquio Sanchez, Raikko Kivekas, and Lluis Escriche
pp 3053 - 3058; DOI:
10.1021/ic00015a022
PDF
Influence of the amino substituents of potentially bis ortho chelating aryl ligands (2,6-{R1R2NCH2}2C6H3)- on the synthesis and properties of their organonickel(II) complexes
Johannus A. M. Van Beek, Gerard Van Koten, Maarten J. Ramp, Norbert C. Coenjaarts, David M. Grove, Kees Goubitz, Martin C. Zoutberg, Casper H. Stam, Wilberth J. J. Smeets, and Anthony L. Spek
pp 3059 - 3068; DOI:
10.1021/ic00015a023
PDF
Incorporation of barium for the synthesis of heterometallic alkoxides: synthesis and structures of [BaZr2(O-iso-Pr)10]2 and Ba{Zr2(O-iso-Pr)9}2
Brian A. Vaarstra, John C. Huffman, William E. Streib, and Kenneth G. Caulton
pp 3068 - 3072; DOI:
10.1021/ic00015a024
PDF
Ring opening of the [Au(CH2)2PPh2]2X4 (X = halogen) metallacycle. Cleavage of gold(III)-CH2 bonds
Raphael G. Raptis, John P. Fackler, John D. Basil, and Douglas S. Dudis
pp 3072 - 3075; DOI:
10.1021/ic00015a025
PDF
Influence of a phase transition in the solid state on the structure of a synthetic iron-sulfur cubane
P. Excoffon, J. Laugier, and B. Lamotte
pp 3075 - 3081; DOI:
10.1021/ic00015a026
PDF
Metal complexes of the new ligand 1,2,6,7-tetracyano-3,5-diimino-3,5-dihydropyrrolizinide, M(II)(C11N7H2)2, as basic units for molecular materials. Electrochemical and metal-phthalocyanine-like electronic properties of the nickel(II) complex and x-ray crystal structures of its adducts with dioxane and tetrathiafulvalene
Mario Bonamico, Vincenzo Fares, Alberto Flamini, and Nicola Poli
pp 3081 - 3087; DOI:
10.1021/ic00015a027
PDF
Vibrational modes of acetylenedicobalt hexacarbonyl studied by neutron spectroscopy
H. Jobic, C. C. Santini, and C. Coulombeau
pp 3088 - 3090; DOI:
10.1021/ic00015a028
PDF
Mesomorphic property and orientational order in the nematic phases of nickel(II) and oxovanadium(IV) complexes of N-salicylidene-n-propylamine derivatives
Naomi Hoshino, Akira Kodama, Tomoko Shibuya, Yoshio Matsunaga, and Seiichi Miyajima
pp 3091 - 3096; DOI:
10.1021/ic00015a029
PDF
Synthesis and structure of a new ternary telluride, Cu1.85Zr2Te6
Patricia M. Keane and James A. Ibers
pp 3096 - 3098; DOI:
10.1021/ic00015a030
PDF
Anion coordination by protonated tris(pyrazolyl)hydroborato derivatives: crystal structure of the host-guest complex [{.eta.3-HB(3-tert-Bu-pzH)3}Cl] [AlCl4]
Adrian Looney, Gerard Parkin, and Arnold L. Rheingold
pp 3099 - 3101; DOI:
10.1021/ic00015a031
PDF
Beryllium salicylate dihydrate
H. Schmidbaur, O. Kumberger, and J. Riede
pp 3101 - 3103; DOI:
10.1021/ic00015a032
PDF
Encapsulation of silver(I) by the crown thioether ligand 1,3,6,9,11,14-hexathiacyclohexadecane (16S6). Synthesis and structure of [Ag(16S6)][ClO4]
Broer De Groot and Stephen J. Loeb
pp 3103 - 3105; DOI:
10.1021/ic00015a033
PDF
Preparation and structure of a mixed niobium(I) isocyanide carbonyl complex with a bent C-N-C linkage
Ghazar Aharonian, Liliane G. Hubert-Pfalzgraf, Abdenasser Zaki, and Guy Le Borgne
pp 3105 - 3107; DOI:
10.1021/ic00015a034
PDF
On the origin of the antipodal effect in closo-heteroboranes
M. Buehl, Paul v. R. Schleyer, Z. Havlas, D. Hnyk, and S. Hermanek
pp 3107 - 3111; DOI:
10.1021/ic00015a035
PDF
Luminescence from the chair and cube isomers of tetrakis[(triphenylphosphine)iodosilver]
Maher Henary and Jeffrey I. Zink
pp 3111 - 3112; DOI:
10.1021/ic00015a036
PDF
Heterometallic condensed cluster compounds: Pr4I5Z (Z = Co, Ru, Os) and lanthanum ruthenium iodide (La4I5Ru). Synthesis, structure, and bonding [Erratum to document cited in CA114(18):177078e]
Martin W. Payne, Peter K. Dorhout, and John D. Corbett
pp 3112 - 3112; DOI:
10.1021/ic00015a037
PDF
Interconversion of mononuclear and quadruply bonded dinuclear dibenzotetraaza[14]annulene complexes of molybdenum [Erratum to document cited in CA114(12):113946d]
Jean Marc Giraudon, Jean Sala-Pala, Jacques E. Guerchais, Yves Le Mest, and Loic Toupet
pp 3112 - 3112; DOI:
10.1021/ic00015a038
PDF

Issue 16


Synthesis and structure of (Bu4N)[MoO(O2CC(S)Ph2)2]. The first mononuclear molybdenum(V) complex containing both coordinated thiolate and carboxylate groups
Vicente Sanz, Teresa Picher, Pedro Palanca, Pedro Gomez-Romero, Elisa Llopis, Jose A. Ramirez, Daniel Beltran, and Antonio Cervilla
pp 3113 - 3115; DOI:
10.1021/ic00016a001
PDF
Cluster of clusters. Structure of a new cluster [(p-Tol3P)10Au13Ag12Cl7](SbF6)2 containing a nearly staggered-eclipsed-staggered metal configuration and five doubly-bridging ligands
Boon K. Teo and Hong Zhang
pp 3115 - 3116; DOI:
10.1021/ic00016a002
PDF
Short spin-lattice relaxation times of hydride ligands. Proton-metal dipole-dipole interactions
D. G. Gusev, A. B. Vymenits, and V. I. Bakhmutov
pp 3116 - 3118; DOI:
10.1021/ic00016a003
PDF
New synthetic routes to azavinylidene half-sandwich type complexes
Thomas Daniel, Michael Mueller, and Helmut Werner
pp 3118 - 3120; DOI:
10.1021/ic00016a004
PDF
Transition-metal clusters as substituents. Synthesis, structure, and thermal decomposition of Zn4O[(CO)9Co3(.mu.3-CCO2)]6
Wei Cen, Kenneth J. Haller, and Thomas P. Fehlner
pp 3120 - 3121; DOI:
10.1021/ic00016a005
PDF
Cyclopentoxyditungsten compounds and crystal and molecular structures and dynamic solution behavior of W2(.mu.-H)(O-cyclo-C5H9)7(HNMe2)
Stephanie T. Chacon, Malcolm H. Chisholm, Kirsten Folting, Mark J. Hampden-Smith, and John C. Huffman
pp 3122 - 3125; DOI:
10.1021/ic00016a006
PDF
Pentacoordinated molecules. 87. Isolation of the first anionic five-coordinated silicates with six- and seven-membered oxygen-containing rings
K. C. Kumara Swamy, Channareddy Sreelatha, Roberta O. Day, Joan Holmes, and Robert R. Holmes
pp 3126 - 3132; DOI:
10.1021/ic00016a007
PDF
Pentacoordinated molecules. 88. Boat and chair forms for sulfur-containing cyclic oxyphosphoranes
Johannes Hans, Roberta O. Day, Lori Howe, and Robert R. Holmes
pp 3132 - 3140; DOI:
10.1021/ic00016a008
PDF
Stereochemical perturbations of the relaxation behavior of (2E)chromium(III). Ground-state x-ray crystal structure, photophysics, and molecular mechanics simulations of the quasi-cage complex [4,4',4''-ethylidynetris(3-azabutan-1-amine)]chromium tribromide
Marc W. Perkovic, Mary Jane Heeg, and John F. Endicott
pp 3140 - 3147; DOI:
10.1021/ic00016a009
PDF
NMR and crystallographic determination of stereoselectivity in the coordination of prochiral olefinic alcohols in mixed olefin-amino acid complexes of platinum(II)
Luther E. Erickson, Garth S. Jones, Jason L. Blanchard, and Kazi J. Ahmed
pp 3147 - 3155; DOI:
10.1021/ic00016a010
PDF
Trinuclear copper(II) hydroxo and hexanuclear copper(II) oxo complexes with the ligand 3-(benzylimino)butanone 2-oxime. Syntheses and spectral, structural and redox characteristics
Y. Agnus, R. Louis, B. Metz, C. Boudon, J. P. Gisselbrecht, and M. Gross
pp 3155 - 3161; DOI:
10.1021/ic00016a011
PDF
Structure and magnetic properties of a chain compound formed by copper(II) and a tridentate nitronyl nitroxide radical
Andrea Caneschi, Fabrizio Ferraro, Dante Gatteschi, Paul Rey, and Roberta Sessoli
pp 3162 - 3166; DOI:
10.1021/ic00016a012
PDF
EPR and NMR study of the spin-crossover transition in bis(4,4'-bi-1,2,4-triazole)bis(thiocyanato)iron hydrate and bis(4,4'-bi-1,2,4-triazole)bis(selenocyanato)iron hydrate. X-ray structure determination of Fe(4,4'-bi-1,2,4-triazole)2(SeCN)2.cntdot.H2O
Andrzej Ozarowski, Yu Shunzhong, Bruce R. McGarvey, Anil Mislankar, and John E. Drake
pp 3167 - 3174; DOI:
10.1021/ic00016a013
PDF
Pressure-induced spin-state crossovers in six-coordinate cobalt(II) complexes: a near-edge x-ray absorption study
C. Roux, J. Zarembowitch, J. P. Itie, M. Verdaguer, E. Dartyge, A. Fontaine, and H. Tolentino
pp 3174 - 3179; DOI:
10.1021/ic00016a014
PDF
Magnetic susceptibility, EPR, Moessbauer, and x-ray investigations of heteropolynuclear clusters containing iron(III) and copper(II) ions: {Cu(Mesalen)}2 Fe(acac) (NO3)2 and {Cu(Mesalen)}3 Fe(acac) (PF6)2
Irene Morgenstern-Badarau, Daniel Laroque, Eckhard Bill, Heiner Winkler, Alfred X. Trautwein, Francis Robert, and Yves Jeannin
pp 3180 - 3188; DOI:
10.1021/ic00016a015
PDF
Multinuclear NMR study of the interaction of the shift reagent lanthanide(III) bis(triphosphate) with alkali-metal ions in aqueous solution and in the solid state
Ravichandran Ramasamy, Duarte Mota de Freitas, Carlos F. G. C. Geraldes, and Joop A. Peters
pp 3188 - 3191; DOI:
10.1021/ic00016a016
PDF
Preparation and properties of mononuclear and ferromagnetically coupled dinuclear manganese complexes with 2,2'-biphenoxide
Ann R. Schake, Edward A. Schmitt, Andrew J. Conti, William E. Streib, John C. Huffman, David N. Hendrickson, and George Christou
pp 3192 - 3199; DOI:
10.1021/ic00016a017
PDF
Proton and vanadium-51 NMR investigation of the complexes formed between vanadate and nucleosides
Alan S. Tracey and Chui Har Leon-Lai
pp 3200 - 3204; DOI:
10.1021/ic00016a018
PDF
Synthesis, characterization, and electrochemistry of copper(II) and palladium(II) hydroporphyrins: the copper(I) octaethylisobacteriochlorin anion
Alan M. Stolzenberg and Leonard J. Schussel
pp 3205 - 3213; DOI:
10.1021/ic00016a019
PDF
Nickel(II) porphyrin binding to anionic biopolymers investigated by resonance Raman and optical spectroscopy
K. T. Yue, Mengfen Lin, Thomas A. Gray, and Luigi G. Marzilli
pp 3214 - 3222; DOI:
10.1021/ic00016a020
PDF
Reactions of the iron(III) tetraphenylporphyrin .pi. cation radical with triphenylphosphine and the nitrite anion. Formation of .beta.-substituted iron(III) porphyrins
Andrzej Malek, Lechoslaw Latos-Grazynski, Tadeusz J. Bartczak, and Andrzej Zadlo
pp 3222 - 3230; DOI:
10.1021/ic00016a021
PDF
Basicity of the solvent as the main factor determining the stability of iron/sulfido thiolato [Fe4S4(SR)4]- cluster ions in solution
H. L. Blonk, O. Kievit, E. K. H. Roth, J. Jordanov, J. G. M. Van der Linden, and J. J. Steggerda
pp 3231 - 3234; DOI:
10.1021/ic00016a022
PDF
Long-range antiferromagnetic coupling between two ruthenium(III) ions bridged by a 1,4-dicyanamidobenzene dianion ligand
Manuel A. S. Aquino, Florence L. Lee, Eric J. Gabe, J. E. Greedan, and Robert J. Crutchley
pp 3234 - 3236; DOI:
10.1021/ic00016a023
PDF
Stereochemistry of six-coordinated silicon complexes. 1. Stereoselectivity and CD spectra of tris(optically active .beta.-diketonato)silicon(IV) complexes
Takashi Shimizutani and Yuzo Yoshikawa
pp 3236 - 3238; DOI:
10.1021/ic00016a024
PDF

Issue 17


Binuclear compounds containing pendant electroactive groups: photophysical and electrochemical properties of tris(4-ferrocenyldibenzylideneacetone)dipalladium(0), Pd2[(C5H5)Fe(C5H4)(C6H4)CHCH(CO)CHCHC6H5]3
Pierre D. Harvey and Liangbing Gan
pp 3239 - 3241; DOI:
10.1021/ic00017a001
PDF
Reactions of molybdenum(0) tricarbonyl complexes with 8-azidoquinoline. Crystal structure of the phosphinimine complex Mo(CO)4[N(PPh3)(C9H6N)] and evidence for a bent nitrene
J. L. Fourquet, M. Leblanc, A. Saravanamuthu, M. R. M. Bruce, and A. E. Bruce
pp 3241 - 3243; DOI:
10.1021/ic00017a002
PDF
Synthesis of bimetallic barium titanium alkoxides as precursors for electrical ceramics. Molecular structure of the new barium titanium oxide alkoxide Ba4Ti13(.mu.3-O)12(.mu.5-O)6(.mu.1-.eta.1-OCH2CH2OCH3)12(.mu.1,.mu.3-.eta.2-OCH2CH2OCH3)12
Jean Florent Campion, David A. Payne, Hee K. Chae, Jan K. Maurin, and Scott R. Wilson
pp 3244 - 3245; DOI:
10.1021/ic00017a003
PDF
The bis(methylcyclopentadienyl)titanium(IV) molybdate dimer: a titanium(IV)-molybdenum(VI) eight-membered metal-oxo ring
Tommaso Carofiglio, Carlo Floriani, Marzio Rosi, Angiola Chiesi-Villa, and Corrado Rizzoli
pp 3245 - 3246; DOI:
10.1021/ic00017a004
PDF
Multiple bonds between main group elements and transition metals. 98. (.eta.5-Cyclopentadienyl)trioxorhenium
Wolfgang A. Herrmann, Marc Taillefer, Claude De Meric de Bellefon, and Joachim Behm
pp 3247 - 3248; DOI:
10.1021/ic00017a005
PDF
Diorganyltin(IV) bis[poly(1-pyrazolyl)borates] and related species
Kurt Niedenzu, H. Noeth, J. Serwatowska, and J. Serwatowski
pp 3249 - 3254; DOI:
10.1021/ic00017a006
PDF
Ene reactions of 1,2-dehydro-o-carborane
Qiurong Huang, Henry L. Gingrich, and Maitland Jones
pp 3254 - 3257; DOI:
10.1021/ic00017a007
PDF
Assignment by 2D NMR bond correlation spectroscopy of hyperfine-shifted and strongly relaxed protons in iron porphyrin and chlorin complexes
Kelly A. Keating, Jeffrey S. De Ropp, Gerd N. La Mar, Alan L. Balch, Fuu Yau Shiau, and Kevin M. Smith
pp 3258 - 3263; DOI:
10.1021/ic00017a008
PDF
Mononuclear and dinuclear ruthenium complexes with triazole containing ligands; fine-tuning of the spectroscopic properties
Ronald Hage, Jaap G. Haasnoot, Jan Reedijk, Renyi Wang, and Johannes G. Vos
pp 3263 - 3269; DOI:
10.1021/ic00017a009
PDF
Spectroscopic characterization of the europium(III) complexes of a series of N,N'-bis(carboxymethyl) macrocyclic ether bis(lactones)
Richard C. Holz, C. Allen Chang, and William DeW. Horrocks
pp 3270 - 3275; DOI:
10.1021/ic00017a010
PDF
Molecular structures, stabilities, and electronic states of the planar [sulfur-nitrogen] rings S3N2 + and S3N22+
Benjamin M. Gimarc and D. Scott Warren
pp 3276 - 3280; DOI:
10.1021/ic00017a011
PDF
Double excitations of titanium(2+)-manganese(2+) spin clusters in magnesium chloride and manganese dichloride and manganese dibromide
Markus Herren, Michael A. Aebersold, Bernard Briat, and Hans U. Guedel
pp 3280 - 3282; DOI:
10.1021/ic00017a012
PDF
Electrochemical assimilatory and dissimilatory reductions of nitrate and nitrite via a possible free nitric oxide intermediate
Koji Tanaka, Nobutoshi Komeda, and Tatsuji Matsui
pp 3282 - 3288; DOI:
10.1021/ic00017a013
PDF
Volume profile analysis of the formation and dissociation of carboxymyoglobin. Comparison with the corresponding oxymyoglobin system
Hans Dieter Projahn and Rudi Van Eldik
pp 3288 - 3293; DOI:
10.1021/ic00017a014
PDF
New di- and trinuclear complexes of ruthenium with octahedra joined on faces or edges. 3. New trinuclear compounds of the type [(R3P)2ClRuCl3RuCl3RuCl(PR3)2]n (n = 0, +1): structures, EPR spectroscopy, electrochemistry, and molecular orbitals
F. Albert Cotton and Raymund C. Torralba
pp 3293 - 3304; DOI:
10.1021/ic00017a015
PDF
Effects of ligands, solvent, and variable sulfonation on dimer formation of aluminum and zinc phthalocyaninesulfonates
Paul C. Martin, Martin Gouterman, Barry V. Pepich, George E. Renzoni, and Deborah C. Schindele
pp 3305 - 3309; DOI:
10.1021/ic00017a016
PDF
Synthesis and properties of trimeric ortho-chelated (arenethiolato)copper(I) complexes
D. Martin Knotter, Hendrik L. Van Maanen, David M. Grove, Anthony L. Spek, and Gerard Van Koten
pp 3309 - 3317; DOI:
10.1021/ic00017a017
PDF
Synthesis and characterization of the new quaternary one-dimensional chain materials, potassium copper niobium selenides, K2CuNbSe4 and K3CuNb2Se12
Yingjie Lu and James A. Ibers
pp 3317 - 3320; DOI:
10.1021/ic00017a018
PDF
Synthesis and properties of two novel line phases that contain linear scandium chains, lithium scandium iodide (LiScI3) and sodium scandium iodide (Na0.5ScI3)
Abdessedek Lachgar, Douglas S. Dudis, Peter K. Dorhout, and John D. Corbett
pp 3321 - 3326; DOI:
10.1021/ic00017a019
PDF
Bonding considerations in metal iodide chain compounds: alkali metal scandium iondids (AxScI3) and metal iodides (MI3) (A = lithium, sodium; M = zirconium, niobium)
Peter K. Dorhout and John D. Corbett
pp 3326 - 3333; DOI:
10.1021/ic00017a020
PDF
(Phosphinoalkyl)silyl complexes. 10. Formation of chelated bis[(diphenylphosphinoethyl)(diorgano)silyl]platinum(II) complexes. Precoordination through phosphorus, intermediacy of a platinum(IV) disilyl, and diastereoisomerism at planar platinum(II) in "chelate-assisted" hydrosilylation
Stephen L. Grundy, Rupert D. Holmes-Smith, Stephen R. Stobart, and Mark A. Williams
pp 3333 - 3337; DOI:
10.1021/ic00017a021
PDF
Kinetics of the electron-exchange reaction of the hexacyanoosmate(II/III) couple in aqueous media
Donal H. Macartney
pp 3337 - 3342; DOI:
10.1021/ic00017a022
PDF
Quantitative preparations of 1,3,2-dithiazolium, 1,3,2,4-dithiadiazolium, and 1-halo-1,2,4,3,5-trithiadiazolium cations by the general, symmetry-allowed cycloadditions of SNSAsF6 with alkynes, nitriles, and thiazyl halides. Kinetics of cycloadditions of the 1,3-dipolar-like SNS+ with aliphatic and aromatic nitriles and alkynes
Simon Parsons, Jack Passmore, Melbourne J. Schriver, and Xiaoping Sun
pp 3342 - 3348; DOI:
10.1021/ic00017a023
PDF
Iron-iridium mixed-metal carbonyl clusters. 3. Synthesis, chemical characterization, electrochemical behavior, and solid-state structures of [NEt4]3[FeIr5(CO)15], [NMe3(CH2Ph)]2[HFeIr5(CO)15], and [NMe3(CH2Ph)][FeIr5(CO)16]. Spectroscopic and chemical evidence for the existence of [HFe3Ir(CO)12]2-, [H2Fe3Ir(CO)12]-, and [H2FeIr5(CO)15]-
Alessandro Ceriotti, Roberto Della Pergola, Luigi Garlaschelli, Franco Laschi, Mario Manassero, Norberto Masciocchi, Mirella Sansoni, and Piero Zanello
pp 3349 - 3357; DOI:
10.1021/ic00017a024
PDF
Nickel(II) and cobalt(II) complexes with 2,4-pentanedionate and tetraamine ligands: synthesis and structural characterization
Jeffrey L. Moler and Sue C. Cummings
pp 3358 - 3361; DOI:
10.1021/ic00017a025
PDF
A theoretical study of the HP4 ion
Michael J. S. Dewar and Ya Jun Zheng
pp 3361 - 3362; DOI:
10.1021/ic00017a026
PDF
Role of Arg-143 in human Cu2Zn2SOD studied through anion binding
Ivano Bertini, Alessandro Lepori, Claudio Luchinat, and Paola Turano
pp 3363 - 3364; DOI:
10.1021/ic00017a027
PDF

Issue 18


Functionalized macrocycles incorporating phosphorus-nitrogen and phosphorus-oxygen bonds. Strategies of synthesis
Dominique Colombo, Anne Marie Caminade, and Jean Pierre Majoral
pp 3365 - 3367; DOI:
10.1021/ic00018a001
PDF
Magnetic phase diagram of the hole-doped T' phases Nd2-xSrxCuO4-.delta.
Matthew J. Rosseinsky, Kosmas Prassides, and Christopher A. Scott
pp 3367 - 3370; DOI:
10.1021/ic00018a002
PDF
Alkyl and hydrido phenoxo complexes of nickel(II), palladium(II), and platinum(II). Hydrido amido complexes of palladium
Allen L. Seligson, Robert L. Cowan, and William C. Trogler
pp 3371 - 3381; DOI:
10.1021/ic00018a003
PDF
Effects of mercuric chloride and pentacarbonyl tungsten coordination on the structure of a 1,2-dihydrophosphete (phosphacyclobutene)
Kenneth M. Doxsee, Erin M. Hanawalt, Gregory S. Shen, Timothy J. R. Weakley, Hakon Hope, and Carolyn B. Knobler
pp 3381 - 3389; DOI:
10.1021/ic00018a004
PDF
Synthesis and structural and spectroscopic characterization of the Germanazene [GeN(2,6-i-Pr2C6H3)]3 and the tin and lead tetramers [SnN(BMes2)]4, [SnN(2,6-i-Pr2C6H3)]4, and [PbN(2,6-i-Pr2C6H3)]4
Hong Chen, Ruth A. Bartlett, H. V. Rasika Dias, Marilyn M. Olmstead, and Philip P. Power
pp 3390 - 3394; DOI:
10.1021/ic00018a005
PDF
Assessing the effects of metal ion proximity on a trans-Ir(CO)Cl(phosphine)2 unit. Structural studies of potassium(I), Tin(II), and Lead(II) complexes of (crown-P2)Ir(CO)Cl
Alan L. Balch, Francesco Neve, and Marilyn M. Olmstead
pp 3395 - 3402; DOI:
10.1021/ic00018a006
PDF
Preparation of 1,1,5,5-tetraphenyl-3,7-diaryl-1,5-diphosphatetrazocines and 1,1,3,3,5-pentaphenyldiphosphatriazine and the x-ray structure of 1,5-Ph4P2N4C2(C6H4CH3-4)2
Vadapalli Chandrasekhar, Tristram Chivers, Santhanathan S. Kumaravel, Auke Meetsma, and Johan C. Van de Grampel
pp 3402 - 3407; DOI:
10.1021/ic00018a007
PDF
Molecular structure of a cobalt(I) complex lacking a carbonyl ligand. A unique example of cobalt-nitrogen bond shortening
Shu Shi, Lee M. Daniels, and James H. Espenson
pp 3407 - 3410; DOI:
10.1021/ic00018a008
PDF
Reduction-induced cleavage of the cobalt-carbon bond in macrocyclic organocobalt complexes
Shu Shi, Andreja Bakac, and James H. Espenson
pp 3410 - 3414; DOI:
10.1021/ic00018a009
PDF
Hydrogen bonding between guanosine 5'-monophosphate and coordinatively saturated cobalt(III) and platinum(II) ammine and ethylenediamine complex cations
Patrick J. Farmer, Jeffrey R. Cave, Terace M. Fletcher, James A. Rhubottom, and Judith A. Walmsley
pp 3414 - 3420; DOI:
10.1021/ic00018a010
PDF
Effects of axial ligation on the thermolysis of benzyl- and neopentylcobamides: analysis of the base-on effect
Kenneth L. Brown and Harold B. Brooks
pp 3420 - 3430; DOI:
10.1021/ic00018a011
PDF
Heteronuclear NMR studies of cobalamins. 12. Further studies of dicyanocobamides and the complete proton, carbon, and amide nitrogen NMR assignments of dicyanocobalamin
Kenneth L. Brown, Harold B. Brooks, B. D. Gupta, Mark Victor, H. M. Marques, D. C. Scooby, Warren J. Goux, and Russell Timkovich
pp 3430 - 3438; DOI:
10.1021/ic00018a012
PDF
Nonempirical calculations on dicopper(1+)-dioxygen: a possible model for oxyhemocyanin and oxytyrosinase active sites
J. Maddaluno and C. Giessner-Prettre
pp 3439 - 3445; DOI:
10.1021/ic00018a013
PDF
Synthesis, protonation constants, and copper(II) and cobalt(II) binding constants of a new octaaza macrobicyclic cryptand: (MX)3(TREN)2. Hydroxide and carbonate binding of the dicopper(II) cryptate and crystal structures of the cryptand and of the carbonato-bridged dinuclear copper(II) cryptate
Rached Menif, Joseph Reibenspies, and Arthur E. Martell
pp 3446 - 3454; DOI:
10.1021/ic00018a014
PDF
Preparation and structural characterization of dicopper(II) and dinickel(II) imidazolate-bridged macrocyclic Schiff base complexes
Carol A. Salata, Marie Therese Youinou, and Cynthia J. Burrows
pp 3454 - 3461; DOI:
10.1021/ic00018a015
PDF
Models for catechol dioxygenases. Structure of bromobis[2-(2'-hydroxyphenyl)benzothiazolato]iron(III) derived from the bromoiron(III) complex of 2,2'-bis((salicylideneamino)phenyl) disulfide
Joseph W. Pyrz, Xiangyang Pan, Doyle Britton, and Lawrence Que
pp 3461 - 3464; DOI:
10.1021/ic00018a016
PDF
Coordination chemistry of rhenium(V), -(IV), and -(III) with the macrocyclic ligands 1,4,7-triazacyclononane (L) and its N-methylated derivative (L'). Crystal structures of [LReCl3]Cl, [L2Re2Cl2(.mu.-Cl)(.mu.-OH)]I2.cntdot.2H2O, [L2Re2I2(.mu.-O)2]I2.cntdot.2H2O, and [L'2Re2Cl4(.mu.-O)]ZnCl4. Effect of .pi.-donors on the Re-Re bond distance
Georg Boehm, Karl Wieghardt, Bernhard Nuber, and Johannes Weiss
pp 3464 - 3476; DOI:
10.1021/ic00018a017
PDF
Comprehensive iron-selenium-thiolate cluster chemistry
Shi Bao Yu, G. C. Papaefthymiou, and R. H. Holm
pp 3476 - 3485; DOI:
10.1021/ic00018a018
PDF
Preparation and properties of models for the photosynthetic water oxidation center: spin frustration in the manganese [Mn4O2(O2CR)7(pic)2]- anion
Eduardo Libby, James K. McCusker, Edward A. Schmitt, Kirsten Folting, David N. Hendrickson, and George Christou
pp 3486 - 3495; DOI:
10.1021/ic00018a019
PDF
Hydrothermal synthesis and structural characteristics of two layered mixed-valence vanadyl phosphate hydrates Na0.50VOPO4.2.0.H2O and K0.50VOPO4.1.5.H2O
S. L. Wang, H. Y. Kang, C. Y. Cheng, and K. H. Lii
pp 3496 - 3499; DOI:
10.1021/ic00018a020
PDF
Redetermination of the crystal structure of hexaamminecobalt(II) chloride
Janet M. Newman, Malcolm Binns, Trevor W. Hambley, and Hans C. Freeman
pp 3499 - 3502; DOI:
10.1021/ic00018a021
PDF
Bis(dioxolene)bis(pyridine)ruthenium redox series
Pamela R. Auburn, Elaine S. Dodsworth, Masaaki Haga, Wei Liu, W. Andrew Nevin, and A. B. P. Lever
pp 3502 - 3512; DOI:
10.1021/ic00018a022
PDF
Crystal and solution structure of two dinuclear hexadentate macrocyclic complexes of palladium(II)
A. McAuley, T. W. Whitcombe, and M. J. Zaworotko
pp 3513 - 3520; DOI:
10.1021/ic00018a023
PDF
Divalent metal ion catalyzed hydrolysis of picolinanilides
K. Veera Reddy, Alan R. Jacobson, John I. Kung, and Lawrence M. Sayre
pp 3520 - 3525; DOI:
10.1021/ic00018a024
PDF
Effect of cyclohexylene bridges on the metal ion size based selectivity of ligands in aqueous solution
Alvaro S. De Sousa, Graeme J. B. Croft, Carl A. Wagner, Joseph P. Michael, and Robert D. Hancock
pp 3525 - 3529; DOI:
10.1021/ic00018a025
PDF
Complexation of sodium(I) and other monovalent ions by 4,7,13,16-tetraoxa-1,10-diazabicyclo[8.8.2]eicosane in a range of solvents. A potentiometric titration and sodium-23 nuclear magnetic resonance study
Stephen F. Lincoln and Ashley K. W. Stephens
pp 3529 - 3534; DOI:
10.1021/ic00018a026
PDF
Bidentate phosphine basicities as determined by enthalpies of protonation
John R. Sowa and Robert J. Angelici
pp 3534 - 3537; DOI:
10.1021/ic00018a027
PDF
Non-metal redox kinetics: hypobromite and hypobromous acid reactions with iodide and with sulfite and the hydrolysis of bromosulfate
Robert C. Troy and Dale W. Margerum
pp 3538 - 3543; DOI:
10.1021/ic00018a028
PDF
Time-resolved infrared spectrum of the MLCT excited state of pentacarbonyl(4-cyanopyridine)tungsten: photophysics and photochemistry
Paul Glyn, Frank P. A. Johnson, Michael W. George, Alistair J. Lees, and James J. Turner
pp 3543 - 3546; DOI:
10.1021/ic00018a029
PDF
A computational model for the chair-to-chair rearrangement in bis(cyclopentadienyl)pentasulfidotitanium(IV)
Michael S. Lawless and Dennis S. Marynick
pp 3547 - 3551; DOI:
10.1021/ic00018a030
PDF
Electronic absorption and MCD spectra for the octakis(triphenylphosphine)octagold(2+) ion
Huey Rong C. Jaw and W. Roy Mason
pp 3552 - 3555; DOI:
10.1021/ic00018a031
PDF
Inelastic neutron scattering and optical absorption spectroscopy of the Ti2+(Mn2+)6 spin cluster in titanium(2+)-doped manganese(2+) bromide and chloride
Michael A. Aebersold, Herma Blank, Bernard Briat, Albert Furrer, and Hans U. Guedel
pp 3556 - 3562; DOI:
10.1021/ic00018a032
PDF
Manganese(III) complexes of a binucleating Schiff-base ligand based on the 1,3-diaminopropan-2-ol backbone
Karen Bertoncello, Gary D. Fallon, Keith S. Murray, and Edward R. T. Tiekink
pp 3562 - 3568; DOI:
10.1021/ic00018a033
PDF
Synthesis and x-ray structure of a novel technetium(IV) complex with tris(hydroxymethyl)(trimethylammonio)methane iodide as a ligand
R. Alberto, A. Albinati, G. Anderegg, and G. Huber
pp 3568 - 3570; DOI:
10.1021/ic00018a034
PDF
Low-coordinate yttrium in an oxygen ligand environment. Solid-state and solution characterization of hexakis(triphenylsiloxo)diyttrium
Paul S. Coan, Michael J. McGeary, Emil B. Lobkovsky, and Kenneth G. Caulton
pp 3570 - 3572; DOI:
10.1021/ic00018a035
PDF
Gold(I) vs gold(III): stabilization of two gold(I) polyselenide complexes, [Au2(Se2)(Se3)]2- and [Au2(Se2)(Se4)]2-, by the diselenide unit
Song Ping Huang and Mercouri G. Kanatzidis
pp 3572 - 3575; DOI:
10.1021/ic00018a036
PDF
A mixed-metal chloro sulfido cluster complex of molybdenum and platinum [Mo3Pt2S4Cl4(PEt3)6]
Taro Saito, Toshio Tsuboi, Yoshimichi Kajitani, Tsuneaki Yamagata, and Hideo Imoto
pp 3575 - 3577; DOI:
10.1021/ic00018a037
PDF
Barium binding to carboxylate residues: synthesis and structure of a new form of barium malonate
Derek J. Hodgson and R. Owen Asplund
pp 3577 - 3580; DOI:
10.1021/ic00018a038
PDF
Concerted regulation of intermolecular carbon-nitrogen bond formation of .alpha.-aminomalonate with trans-[CoCl2(1,10-diamino-4,7-diazadecane)]+ by counteranion and dioxygen
Takahiko Kojima, Reiko Kuroda, Shigenobu Yano, and Masanobu Hidai
pp 3580 - 3582; DOI:
10.1021/ic00018a039
PDF
Laser flash photolysis and pulse radiolysis of aqueous solutions of the fluoroxysulfate ion, SO4F-
Ulrik K. Klaning, Knud Sehested, and Evan H. Appelman
pp 3582 - 3584; DOI:
10.1021/ic00018a040
PDF

Issue 19


Labile triangulo-trititanium(II) and trivanadium(II) clusters
Jilles J. H. Edema, Sandro Gambarotta, Robbert Duchateau, and Corinne Bensimon
pp 3585 - 3587; DOI:
10.1021/ic00019a001
PDF
Bis(4-imidazoleacetato)iron.bis(methanol): a 2D antiferromagnetic iron(II) system exhibiting 3D long-range ordering with a net magnetic moment at 15 K
Maria Angeles Martinez-Lorente, Vasili Petrouleas, Jean Michel Savariault, Richard Poinsot, Marc Drillon, and Jean Pierre Tuchagues
pp 3587 - 3589; DOI:
10.1021/ic00019a002
PDF
Dicarbollide complexes of thallium: structural and boron-11 NMR studies
Mark J. Manning, Carolyn B. Knobler, M. Frederick Hawthorne, and Youngkyu Do
pp 3589 - 3591; DOI:
10.1021/ic00019a003
PDF
Reversible coordination of diphenylacetylene in the dicarbidodecaruthenium framework. Substitution-induced metal-metal bond formation
Linqing Ma, Damian P. S. Rodgers, Scott R. Wilson, and John R. Shapley
pp 3591 - 3593; DOI:
10.1021/ic00019a004
PDF
Labile and coordinatively unsaturated molybdenum(III)-.mu.-sulfido dimers, Mo2(.mu.-S)(.mu.-Cl)Cl3(PMe3)4(L)(L = PMe3, MeCN, or vacant) formed by sulfur atom abstraction from SPMe3
Keith A. Hall, Susan C. Critchlow, and James M. Mayer
pp 3593 - 3594; DOI:
10.1021/ic00019a005
PDF
Osmium imido complexes: synthesis, reactivity, and SCF-X.alpha.-SW electronic structure
Mark H. Schofield, Terence P. Kee, Jens T. Anhaus, Richard R. Schrock, Keith H. Johnson, and William M. Davis
pp 3595 - 3604; DOI:
10.1021/ic00019a006
PDF
Cluster synthesis. 34. Unsaturation in a high-nuclearity platinum-osmium carbonyl cluster complex. Studies of the synthesis, structure, and reactivity of Pt2Os4(CO)11(COD)2
Richard D. Adams and Wengan Wu
pp 3605 - 3612; DOI:
10.1021/ic00019a007
PDF
Cluster synthesis. 35. On the way to high-nuclearity platinum-osmium cluster complexes. Synthesis and structural characterizations of Pt2Os3(CO)9(COD)2(.mu.-H)2 and Pt4Os6(CO)21(COD)(.mu.-H)2 (COD = cycloocta-1,5-diene)
Richard D. Adams, Jau Ching Lii, and Wengan Wu
pp 3613 - 3617; DOI:
10.1021/ic00019a008
PDF
Platinum-assisted addition of carbonyl-stabilized phosphorus ylides to benzonitrile to give iminophosphorane complexes of platinum(II). Crystal and molecular structure of trans-[PtCl2{E-N(:PPh3)C(Ph):CHCO2Et}(NCPh)].cntdot.1/2Me2CO
Jose Vicente, Maria Teresa Chicote, Juan Fernandez-Baeza, Fernando J. Lahoz, and Jose A. Lopez
pp 3617 - 3620; DOI:
10.1021/ic00019a009
PDF
Solvent-controlled equilibria of substitution and isomerization of .alpha.-ketoacyl complexes of platinum(II). X-ray single-crystal structure of cis-Pt(COCOPh)(Cl)(PPh2CH2CH2PPh2)
Yen Jeh You, Jwu Ting Chen, Ming Chu Cheng, and Yu Wang
pp 3621 - 3625; DOI:
10.1021/ic00019a010
PDF
Homogeneous catalytic carbonylation of nitroaromatics. 4. Preparation and characterization of ruthenium radical cations
Stephen J. Sherlock, David C. Boyd, Bahram Moasser, and Wayne L. Gladfelter
pp 3626 - 3632; DOI:
10.1021/ic00019a011
PDF
Dihydrogen complexes in catalysis: isotope exchange reactions
Ana C. Albeniz, D. Michael Heinekey, and Robert H. Crabtree
pp 3632 - 3635; DOI:
10.1021/ic00019a012
PDF
Synthesis and x-ray structures of two unprecedented heteropolymetalates [As3M3O15]3- (M = Mo, W) and [As6CoMo6O30]4-. First examples of linear triarsenate(III) and cyclic triarsenate(III)
J. Martin-Frere, Yves Jeannin, F. Robert, and J. Vaissermann
pp 3635 - 3639; DOI:
10.1021/ic00019a013
PDF
Ligand and alkali metal cation control on the molecular complexity of anionic chromium(II) aryloxides. Preparation and crystal structure of dimeric (PhO)10Cr2Li6(THF)6 and (2,6-Me2C6H3O)6Cr2Li2(THF)4 and trimeric (GuO)14Cr3Na9Cl [GuO = (o-CH3O)C6H4O] with an encapsulated chloride ion
Jilles J. H. Edema, Auke Meetsma, Sandro Gambarotta, Saeed I. Khan, Wilberth J. J. Smeets, and Anthony L. Spek
pp 3639 - 3646; DOI:
10.1021/ic00019a014
PDF
Synthesis and desulfurization of 2,5-dihydrothiophene transition-metal complexes: models for the hydrodesulfurization (HDS) of thiophene
Moon Gun Choi, Lee M. Daniels, and Robert J. Angelici
pp 3647 - 3651; DOI:
10.1021/ic00019a015
PDF
Synthesis and complexation studies of mesocyclic and macrocyclic polythioethers. 8. Synthesis and x-ray crystal structures of heavy-metal complexes of 1,5,9,13-tetrathiacyclohexadecane
William N. Setzer, Yaping Tang, Gregory J. Grant, and Donald G. VanDerveer
pp 3652 - 3656; DOI:
10.1021/ic00019a016
PDF
Alkaline-earth-metal complexes of 1,4,8,11-tetraazacyclotetradecane-1,4,8,11-tetraacetic acid, H4TETA, and crystal and molecular structure of H4TETA.cntdot.6H2O and [Mg(H2TETA)(H2O)4].cntdot.4H2O
M. R. Maurya, E. J. Zaluzec, S. F. Pavkovic, and Albert W. Herlinger
pp 3657 - 3662; DOI:
10.1021/ic00019a017
PDF
Electron transfer. 110. Oxidations of trinuclear aquomolybdenum(IV)
Sanchita Purohit Ghosh and Edwin S. Gould
pp 3662 - 3666; DOI:
10.1021/ic00019a018
PDF
Electronic structure and bonding in trinuclear molybdenum and tungsten cluster compounds of M3X13 type
F. Albert Cotton and Xuejun Feng
pp 3666 - 3670; DOI:
10.1021/ic00019a019
PDF
Synthesis and characterization of edge-sharing bioctahedral complexes of zirconium(III) and hafnium(III) that contain long metal-metal single bonds: Zr2I6(PMe3)4, Hf2I6(PMe2Ph)4, and Zr2I6(PMe2Ph)4
F. Albert Cotton, Maoyu Shang, and William A. Wojtczak
pp 3670 - 3675; DOI:
10.1021/ic00019a020
PDF
Preparation and molecular and electronic structures of a new diamagnetic diruthenium(II) complex, Ru2[(p-tol)NC(H)N(p-tol)]4
F. Albert Cotton and Tong Ren
pp 3675 - 3679; DOI:
10.1021/ic00019a021
PDF
Chalcogen ring interconversion pathways. Selenium-77 NMR spectroscopic study of the decomposition of 1,2,3,4,5-Se5S2 to 1,2,3,4,5,6-Se6S2 and 1,2,3,4-Se4S2
Pentti Pekonen, Yrjo Hiltunen, Risto S. Laitinen, and Tapani A. Pakkanen
pp 3679 - 3682; DOI:
10.1021/ic00019a022
PDF
Synthesis and structure of the neutral three-coordinate gallium selenolate Ga[Se(2,4,6-tert-Bu3C6H2)]3 and the monomeric lithium selenolate Li(THF)3Se(2,4,6-tert-Bu3C6H2)
Karin Ruhlandt-Senge and Philip P. Power
pp 3683 - 3686; DOI:
10.1021/ic00019a023
PDF
Lithium binder in aqueous solution. Synthesis and characterization of the new cage 4,10,15-trimethyl-1,4,7,10,15-pentaazabicyclo[5.5.5]heptadecane (L). Protonation and lithium complex formation. Crystal structures of [HL][BPh4] and [LiL][BPh4]
Andrea Bencini, Antonio Bianchi, Stefano Chimichi, Mario Ciampolini, Paolo Dapporto, Enrique Garcia-Espana, Mauro Micheloni, Nicoletta Nardi, Paola Paoli, and Barbara Valtancoli
pp 3687 - 3691; DOI:
10.1021/ic00019a024
PDF
Tetradentate macrocyclic complexes of platinum. X-ray crystal structures and redox behavior of complexes containing nitrogen or sulfur donor atoms
David Waknine, Mary Jane Heeg, John F. Endicott, and L. A. Ochrymowycz
pp 3691 - 3700; DOI:
10.1021/ic00019a025
PDF
Nickel template syntheses of pentadentate and macrocyclic nitrogen-sulfur ligands: single-crystal X-ray structure of (1,10-diaza-4,7,13,16-tetrathia-5,6:14,15-dibenzocyclooctadecane)nickel(II) bis(tetraphenylborate) acetonitrile
Nadine De Vries and Jan Reedijk
pp 3700 - 3703; DOI:
10.1021/ic00019a026
PDF
Carbon-13 NMR study of a [cobalt-nickel] Co2Ni tetrahedral cluster. Preferential .pi.-orbital overlap and reorientational dynamics in Co2NiCp(CO)6(.mu.3-CPh)
P. Yuan, M. J. Don, M. G. Richmond, and M. Schwartz
pp 3704 - 3707; DOI:
10.1021/ic00019a027
PDF
Solvent effects on the linkage isomerization of the N1-bonded pentaamminecobalt(III) complex of 5-methyltetrazole
S. Hubinger and W. L. Purcell
pp 3707 - 3710; DOI:
10.1021/ic00019a028
PDF
Kinetics and spectroscopic studies of transients produced by flash photolysis of M(CO)3(PR3)2X2 (M = molybdenum, tangsten, W; X = Cl, Br)
Richard S. Herrick, Melinda S. George, Ronald R. Duff, Felicitee Henry D'Aulnois, Ronald M. Jarret, and John L. Hubbard
pp 3711 - 3718; DOI:
10.1021/ic00019a029
PDF
Formation and decomposition of peroxovanadium(V) complexes in aqueous solution
Jaswinder S. Jaswal and Alan S. Tracey
pp 3718 - 3722; DOI:
10.1021/ic00019a030
PDF
Excited-state acid-base chemistry of (.alpha.-diimine)cyanotricarbonylrhenium(I) complexes
R. M. Leasure, LouAnn Sacksteder, D. Nesselrodt, G. A. Reitz, J. N. Demas, and B. A. DeGraff
pp 3722 - 3728; DOI:
10.1021/ic00019a031
PDF
Hexanuclear homo- and heterobridged ruthenium(II) polypyridine complexes: syntheses, absorption spectra, luminescence properties, and electrochemical behavior
Sebastiano Campagna, Gianfranco Denti, Scolastica Serroni, Mauro Ciano, and Vincenzo Balzani
pp 3728 - 3732; DOI:
10.1021/ic00019a032
PDF
Synthesis, spectroscopy, and electrochemistry of ruthenium(II) complexes of 6-(N-pyrazolyl)- and 6-(N-pyrazolylmethyl)-2,2'-bipyridines: new tridentate ligands
Alison J. Downard, Gene E. Honey, and Peter J. Steel
pp 3733 - 3737; DOI:
10.1021/ic00019a033
PDF
Evaluation of electron-transfer sites in ruthenium(II) octaethylporphyrin complexes of the type (OEP)Ru(CO)(L)
K. M. Kadish, P. Tagliatesta, Y. Hu, Y. J. Deng, X. H. Mu, and L. Y. Bao
pp 3737 - 3743; DOI:
10.1021/ic00019a034
PDF
Gold(I) phosphine complexes: mercaptooxopurine base interactions. Molecular and crystal structure of (8-mercaptotheophyllinato-S)(triphenylphosphine)gold(I)
Enrique Colacio, Antonio Romerosa, Jose Ruiz, Pascual Roman, Juan M. Gutierrez-Zomilla, Angel Vegas, and Martin Martinez-Ripoll
pp 3743 - 3749; DOI:
10.1021/ic00019a035
PDF
Synthesis and characterization of aziridine complexes of cobalt(III) and chromium(III) designed as hypoxia-selective cytotoxins. X-ray crystal structure of trans-[Co(Az)4(NO2)2]Br.cntdot.2H2O.cntdot.LiBr
David C. Ware, B. G. Siim, K. G. Robinson, W. A. Denny, P. J. Brothers, and G. R. Clark
pp 3750 - 3757; DOI:
10.1021/ic00019a036
PDF
Kinetics of iron removal from human serum monoferric transferrins by citrate
Helder M. Marques, Dawn L. Watson, and Timothy J. Egan
pp 3758 - 3762; DOI:
10.1021/ic00019a037
PDF
Coordination oligomers and a coordination polymer of zinc tetraarylporphyrins
Everly B. Fleischer and Amy M. Shachter
pp 3763 - 3769; DOI:
10.1021/ic00019a038
PDF
Size and shape characteristics of inorganic molecular ions and their relevance to crystallization problems
P. Michael D. Mingos and Andrew L. Rohl
pp 3769 - 3771; DOI:
10.1021/ic00019a039
PDF
Chemistry of (silica)zirconium dihydride
Steven A. King and Jeffrey Schwartz
pp 3771 - 3774; DOI:
10.1021/ic00019a040
PDF
Chiral metal complexes. 32. Use of an optically active complex for a nearly absolute chiral induction
Malcolm A. Anderson, Ewan F. Birse, Michael J. E. Hewlins, John P. G. Richards, Frederick S. Stephens, Robert S. Vagg, and Peter A. Williams
pp 3774 - 3778; DOI:
10.1021/ic00019a041
PDF
Deoxygenation of carbon dioxide to diethylformamide in the zinc/diethylamine/carbon dioxide system. Crystal and molecular structure of hexakis(diethylcarbamato)oxotetrazinc
Antonio Belforte, Fausto Calderazzo, Ulli Englert, and Joachim Straehle
pp 3778 - 3781; DOI:
10.1021/ic00019a042
PDF
Behavior of phosphoryl trifluoride toward dry trimethylamine oxide: complex formation and disproportionation and action of Lewis acids
Anton B. Burg
pp 3781 - 3783; DOI:
10.1021/ic00019a043
PDF
Phosphorus-31 and silicon-29 solid-state NMR studies of a phosphine-functionalized polysiloxane framework
Ekkehard Lindner, Armin Bader, and Hermann A. Mayer
pp 3783 - 3785; DOI:
10.1021/ic00019a044
PDF
Complex formation reactions of the chlorite ion
Istvan Fabian and Gilbert Gordon
pp 3785 - 3787; DOI:
10.1021/ic00019a045
PDF
The large range of uranyl bond lengths: ab initio calculations on simple uranium-oxygen clusters
Pekka Pyykko and Yongfang Zhao
pp 3787 - 3788; DOI:
10.1021/ic00019a046
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Issue 20


The tetranuclear ruthenium(IV) aqua ion: evidence in support of its formulation as Hn[Ru4O6(OH2)12](4+n)+ (n = 0-4)
Ayyub Patel and David T. Richens
pp 3789 - 3792; DOI:
10.1021/ic00020a001
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Tertiary amine adducts of gallane: gallane-rich [{GaH3}2(TMEDA)] (TMEDA = N,N,N',N'-tetramethylethylenediamine) and thermally robust [GaH3(quinuclidine)]
Jerry L. Atwood, Simon G. Bott, Fiona M. Elms, Cameron Jones, and Colin L. Raston
pp 3792 - 3793; DOI:
10.1021/ic00020a002
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Synthesis and x-ray crystal structure of the C2B4-carbons apart-carborane dianion 2,4-bis(trimethylsilyl)-2,4-dicarba-nido-hexaborate(2-): a new synthon in organometallics
Narayan S. Hosmane, Lei Jia, Hongming Zhang, Joseph W. Bausch, G. K. Surya Prakash, Robert E. Williams, and Thomas P. Onak
pp 3793 - 3795; DOI:
10.1021/ic00020a003
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Swapan Kumar Chandra and Animesh Chakravorty
pp 3795 - 3796; DOI:
10.1021/ic00020a004
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First stereospecific preparation of a polynuclear coordination compound. Use of .LAMBDA.-bis(o-phenanthroline)ruthenium(II) as a chiral building block
Xiao Hua and Alex Von Zelewsky
pp 3796 - 3798; DOI:
10.1021/ic00020a005
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Luminescent europium(3+), terbium(3+) and gadolinium(3+) complexes of a branched-triazacyclononane ligand containing three 2,2'-bipyridine units
Luca Prodi, Mauro Maestri, Raymond Ziessel, and Vincenzo Balzani
pp 3798 - 3802; DOI:
10.1021/ic00020a006
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Optical absorption and circular dichroism spectra, transition line strengths, and crystal-field analysis of the erbium(3+) 4f11 electronic energy-level structure in trigonal Na3[Er(C4H4O5)3].cntdot.2NaClO4.cntdot.6H2O
Karl A. Schoene, John R. Quagliano, and Frederick S. Richardson
pp 3803 - 3812; DOI:
10.1021/ic00020a007
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Polarized optical absorption spectra, crystal-field energy levels, and transition line strengths of erbium in tetragonal Er(C2O4)(C2O4H).cntdot.3H2O
Karl A. Schoene, Zameer Hasan, John R. Quagliano, and Frederick S. Richardson
pp 3813 - 3817; DOI:
10.1021/ic00020a008
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Closed-shell electronic structures for linear LnMXMLn dinuclear transition-metal complexes
Zhenyang Lin and Michael B. Hall
pp 3817 - 3822; DOI:
10.1021/ic00020a009
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Chemistry of the scandium-benzyne ion in the gas phase
Yongqing Huang, Y. Dorothy Hill, Mariona Sodupe, Charles W. Bauschlicher, and Ben S. Freiser
pp 3822 - 3829; DOI:
10.1021/ic00020a010
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Matrix infrared spectra of hydrogen chloride complexes with uranium hexafluoride, tungsten hexafluoride and molybdenum hexafluoride
Rodney D. Hunt, Lester Andrews, and L. Mac Toth
pp 3829 - 3832; DOI:
10.1021/ic00020a011
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Raman spectral study on the structure of a hydrolytic dimer of the aquavanadium(III) ion
Kan Kanamori, Yukari Ookubo, Kazuhito Ino, Kiyoyasu Kawai, and Hitoshi Michibata
pp 3832 - 3836; DOI:
10.1021/ic00020a012
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Kinetics of the water gas shift reaction catalyzed by rhodium(III) chloride in aqueous picoline studied by use of a continuous-flow stirred reactor
Benedito S. Lima Neto, Katherine Howland Ford, Alvaro J. Pardey, Robert G. Rinker, and Peter C. Ford
pp 3837 - 3842; DOI:
10.1021/ic00020a013
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Proton-induced switching of metal-metal interactions in dinuclear ruthenium and osmium complexes bridged by 2,2'-bis(2-pyridyl)bibenzimidazole
Masaaki Haga, Tomoaki Ano, Kenji Kano, and Shinichi Yamabe
pp 3843 - 3849; DOI:
10.1021/ic00020a014
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Kinetic analysis of the stereochemical nonrigidity of the triosmium .mu.3-arene/alkene complex Os3(CO)8(.eta.2-CH2CH2)(.mu.3:.eta.2:.eta.2:.eta.2-C6H6) in the solid state by carbon-13 CP/MAS NMR spectroscopy
Stephen J. Heyes, Christopher M. Dobson, Mark A. Gallop, Brian F. G. Johnson, and Jack Lewis
pp 3850 - 3856; DOI:
10.1021/ic00020a015
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Solvent-induced and polyether-ligand-induced redox isomerization within an asymmetrically coordinated mixed-valence ion: trans-tetraamminebis(2,2'-bipyridine)(.mu.-4-cyanopyridine)chloro(pyridine)diruthenium(4+), trans-(py)(NH3)4Ru(4-NCpy)Ru(2,2'-bpy)2Cl4+
Jeff C. Curtis, Jody A. Roberts, Robert L. Blackbourn, Yuhua Dong, Mohammed Massum, Christopher S. Johnson, and Joseph T. Hupp
pp 3856 - 3860; DOI:
10.1021/ic00020a016
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Photoisomerization and other reactions of dimethylplatinum(IV) complexes with iminodiacetate and (methylimino)diacetate
Trevor G. Appelton, Ron D. Berry, John R. Hall, and Jacqueline A. Sinkinson
pp 3860 - 3865; DOI:
10.1021/ic00020a017
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Pentacoordinate zinc: synthesis and structures of bis[1-(methylthio)-cis-stilbene-2-thiolato]zinc and of its adducts with mono- and bidentate nitrogen bases
Cheng Zhang, R. Chadha, H. K. Reddy, and G. N. Schrauzer
pp 3865 - 3869; DOI:
10.1021/ic00020a018
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A bis(terpyridine)ruthenium(II) catenate
Jean Pierre Sauvage and Michael Ward
pp 3869 - 3874; DOI:
10.1021/ic00020a019
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Intramolecular carbon-hydrogen bond activation: preparation, structure, and properties of a unique cobalt(III) complex, K[Co(III)(dacoda)(SO3).cntdot.5H2O, containing a weak agostic interaction in aqueous solution
William E. Broderick, Kan Kanamori, Roger D. Willett, and J. Ivan Legg
pp 3875 - 3881; DOI:
10.1021/ic00020a020
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Synthesis, structural characterization, and photoinduced hydrogenation of [PPN]2[Re6C(CO)19]
Gishun Hsu, Scott R. Wilson, and John R. Shapley
pp 3881 - 3886; DOI:
10.1021/ic00020a021
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Carbon-sulfur bond cleavage in tris(.mu.-thioether)ditungsten(III) complexes in reactions with anionic nucleophiles, including hydride: synthesis and structure of [PPh4][Cl3W(.mu.-THT)2(.mu.-S(CH2)4Cl)WCl3] and Na[Cl3W(.mu.-SEt2)2(.mu.-SEt)WCl3].cntdot.3THF
P. Michael Boorman, Xiaoliang Gao, James F. Fait, and Masood Parvez
pp 3886 - 3893; DOI:
10.1021/ic00020a022
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Stereochemical nonrigidity in six-coordinate monochelate complexes via polytopal rearrangement
C. Y. Lee, Y. Wang, and Chao Shiuan Liu
pp 3893 - 3899; DOI:
10.1021/ic00020a023
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Cationic control of spin dimensionality in infinite chains of (cation)2[MnIII(salicylate)2(CH3OH)2][MnIII(salicylate)2]
Martin L. Kirk, Myoung Soo Lah, Catherin Raptopoulou, Dimitris P. Kessissoglou, William E. Hatfield, and Vincent L. Pecoraro
pp 3900 - 3907; DOI:
10.1021/ic00020a024
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A molecular mechanics model of ligand effects. 1. Binding of phosphites to pentacarbonylchromium
Mary L. Caffery and Theodore L. Brown
pp 3907 - 3914; DOI:
10.1021/ic00020a025
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Synthesis, crystal structure, and solvolysis reaction of a H-T (head-to-tail) 3,3-dimethylglutarimidate-bridged binuclear platinum(II) complex, [Pt2(NH3)4(C7H10NO2)2](NO3)2.cntdot.H2O
Hiroshi Urata, Hiroshi Moriyama, and Kazuko Matsumoto
pp 3914 - 3919; DOI:
10.1021/ic00020a026
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Structure and bonding trends in two- and three-coordinate boron cations
William F. Schneider, Chaitanya K. Narula, Heinrich Noeth, and Bruce E. Bursten
pp 3919 - 3927; DOI:
10.1021/ic00020a027
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Pentacoordinated molecules. 89. Hydrogen-bonded chain and dimer formations of spirocyclic tetraoxyphosphoranes possessing phosphorinane chair conformations
Johannes Hans, Roberta O. Day, and Robert R. Holmes
pp 3928 - 3936; DOI:
10.1021/ic00020a028
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Structure and magnetic ordering of a ferrimagnetic helix formed by manganese(II) and a nitronyl nitroxide radical
Andrea Caneschi, Dante Gatteschi, Paul Rey, and roberta Sessoli
pp 3936 - 3941; DOI:
10.1021/ic00020a029
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A mixed-valence tetranuclear rhenium cluster with rhenium(I)-rhenium(III) dative bonds
Fausto Calderazzo, Rinaldo Poli, and Pier Francesco Zanazzi
pp 3942 - 3947; DOI:
10.1021/ic00020a030
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Reaction of tetraoxomolybdate(2-) and tetraoxotungstate(2-) with aqueous polysulfides: synthesis, structure, and electrochemistry of .eta.2-polysulfido complexes containing a bridging S,S {M2O2S2}2+ (M = molybdenum, tungsten) core
Ramgopal Bhattacharyya, Prasanta K. Chakrabarty, Pradip N. Ghosh, Alok K. Mukherjee, Debi Podder, and Monika Mukherjee
pp 3948 - 3955; DOI:
10.1021/ic00020a031
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Luminescence spectroscopy of dinuclear platinum complexes containing bridging alkenylidene ligands
LouAnn Sacksteder, Eduardo Baralt, B. A. DeGraff, C. M. Lukehart, and J. N. Demas
pp 3955 - 3957; DOI:
10.1021/ic00020a032
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Organotransition-metal metallacarboranes. 22. Small-carborane-stabilized iron-indole and iron-thiophene .pi.-complexes
Kevin J. Chase and Russell N. Grimes
pp 3957 - 3960; DOI:
10.1021/ic00020a033
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Structures and spectroscopic characteristics of iron(III) diethylenetriaminepentaacetic acid complexes. A non-heme iron(III) complex with relevance to the iron environment in lipoxygenases
Daniel C. Finnen, A. Alan Pinkerton, William R. Dunham, Richard H. Sands, and Max O. Funk
pp 3960 - 3964; DOI:
10.1021/ic00020a034
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Synthesis and spectroscopic and magnetic properties of a unique diamagnetic binuclear .mu.-oxo vanadium(IV) complex. Crystal structure of [(tpa)VO(.mu.-O)VO(tpa)](ClO4)2 (tpa = tris(2-pyridylmethyl)amine)
Hans Toftlund, Sine Larsen, and Keith S. Murray
pp 3964 - 3967; DOI:
10.1021/ic00020a035
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Structure and properties of bis(D-penicillaminato-N,S)nickelate(II) tetrahydrate: a monomeric nickel complex of D-penicillamine, the antidote for nickel toxicity
Narayan Baidya, Marilyn M. Olmstead, and Pradip K. Mascharak
pp 3967 - 3969; DOI:
10.1021/ic00020a036
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A new material with alternating metal-oxide and metal-phosphide layers: barium manganese phosphate (Ba2Mn3P2O2)
Ned T. Stetson and Susan M. Kauzlarich
pp 3969 - 3971; DOI:
10.1021/ic00020a037
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Synthesis and characterization of the triply bonded (rhenium) tetrakis(cyanotrihydroborato) complex Re2(NCBH3)4(.mu.-dppm)2
Keng Yu Shih, Phillip E. Fanwick, and Richard A. Walton
pp 3971 - 3973; DOI:
10.1021/ic00020a038
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Synthesis and x-ray crystal structure of [Fe2(CO)6(.mu.-CO)(.mu.-PhC:CPhH)(.mu.-AuPPh3)]: first example of a highly asymmetric triangular Fe2Au system
Roser Reina, Oriol Rossell, Miquel Seco, Josep Ros, Ramon Yanez, and Aurea Perales
pp 3973 - 3976; DOI:
10.1021/ic00020a039
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Issue 21


Optimization of a molecular-based [manganese copper] magnet: MnCu(pbaOH)(H2O)2 (pbaOH = 2-hydroxy-1,3-propylenebis(oxamato)) with Tc = 30 K
Keitaro Nakatani, Pierre Bergerat, Epiphane Codjovi, Corine Mathoniere, Yu Pei, and Olivier Kahn
pp 3977 - 3978; DOI:
10.1021/ic00021a001
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The lithium chloride adduct of monolithiated 5,10-dihydrophenazine: [Li2(.mu.-Cl)(.mu.-NC12H8NH)(THF)4]
Lutz M. Engelhardt, Geraldine E. Jacobsen, Allan H. White, and Colin L. Raston
pp 3978 - 3980; DOI:
10.1021/ic00021a002
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Accumulating evidence for the selective reactivity of the 6-6 ring fusion of fullerene, C60. Preparation and structure of (.eta.2-C60)Ir(CO)Cl(PPh3)2.cntdot.5C6H6
Alan L. Balch, Vincent J. Catalano, and Joong W. Lee
pp 3980 - 3981; DOI:
10.1021/ic00021a003
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Photoluminescence properties of the copper(I) chloride clusters Cu4Cl4L4 (L = pyridine, substituted pyridine, or saturated amine)
Chong Kul Ryu, Kevin R. Kyle, and Peter C. Ford
pp 3982 - 3986; DOI:
10.1021/ic00021a004
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Electronic structure of main-group-element-centered octahedral gold clusters
A. Goerling, N. Roesch, D. E. Ellis, and H. Schmidbaur
pp 3986 - 3994; DOI:
10.1021/ic00021a005
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Kinetics and mechanism of the complex formation of the chlorite ion and iron(III) in aqueous solution
Istvan Fabian and Gilbert Gordon
pp 3994 - 3999; DOI:
10.1021/ic00021a006
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Oxidation of thiosulfate by tris(phenanthroline)osmium(3+) and related complexes
Rajeshuni Sarala, Steven B. Rabin, and David M. Stanbury
pp 3999 - 4007; DOI:
10.1021/ic00021a007
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A new reaction pathway for the geometrical isomerization of monoalkyl complexes of platinum(II): kinetic behavior of cis-[Pt(PEt3)2(neopentyl)Cl]
Giuseppe Alibrandi, Luigi Monsu Scoloaro, and Raffaello Romeo
pp 4007 - 4013; DOI:
10.1021/ic00021a008
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Spectroscopy and electrochemistry of uranium(IV)/uranium(III) in basic aluminum chloride-1-ethyl-3-methylimidazolium chloride
Carolyn J. Anderson, Mark R. Deakin, Gregory R. Choppin, Willem D'Olieslager, Luk Heerman, and David J. Pruett
pp 4013 - 4016; DOI:
10.1021/ic00021a009
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Stabilization of the defect ("lacunary") complex polymolybdophosphate, PMo11O397-. Isolation, purification, stability characteristics, and metalation chemistry
Lucille A. Combs-Walker and Craig L. Hill
pp 4016 - 4026; DOI:
10.1021/ic00021a010
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Reduced rubredoxin models containing Z-Cys-Pro-Leu-Cys-Gly-NH-C6H4-p-X (X = MeO, H, F, CN): electronic influence by a distant para substituent through NH---S hydrogen bonds
Wei Yin Sun, Norikazu Ueyama, and Akira Nakamura
pp 4026 - 4031; DOI:
10.1021/ic00021a011
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Mononuclear manganese(IV) in tridentate ONO coordination. Synthesis, structure, and redox regulation via oxygen donor variation
Somnath Dutta, Partha Basu, and Animesh Chakravorty
pp 4031 - 4037; DOI:
10.1021/ic00021a012
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Synthesis and characterization of orthometalated rhodium(III) complexes containing substituted triazoles
John H. Van Diemen, Jaap G. Haasnoot, Ronald Hage, Jan Reedijk, Johannes G. Vos, and Renji Wang
pp 4038 - 4043; DOI:
10.1021/ic00021a013
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Synthesis and structure of tetrakis(benzenethiolato)(methylcyclopentadienyl)tantalum and an EHMO analysis of its distorted four-legged piano-stool structure
Owen J. Curnow, M. David Curtis, Arnold Rheingold, and Brian S. Haggerty
pp 4043 - 4047; DOI:
10.1021/ic00021a014
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Synthesis, structure, and reactivity of triplatinumgold and triplatinumdigold cluster complexes
Nicholas C. Payne, Ravindranath Ramachandran, Guy Schoettel, Jagadese J. Vittal, and Richard J. Puddephatt
pp 4048 - 4053; DOI:
10.1021/ic00021a015
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Synthesis and complexation studies of mesocyclic and macrocyclic polythioethers. 9. Synthesis and crystal structure of bis(1,4,7-trithiacyclodecane)palladium(II) hexafluorophosphate
Gregory J. Grant, Keith A. Sanders, William N. Setzer, and Donald G. VanDerveer
pp 4053 - 4056; DOI:
10.1021/ic00021a016
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Conductivity, thermal analysis, and phase diagram of the system cesium pyrosulfate-vanadium pentoxide. Spectroscopic characterization of cesium vanadyl sulfate disulfate Cs4(VO2)2(SO4)2S2O7
G. E. Folkmann, G. Hatem, Rasmus Fehrmann, M. Gaune-Escard, and N. J. Bjerrum
pp 4057 - 4061; DOI:
10.1021/ic00021a017
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Switching the mechanism of spin-exchange coupling in (.mu.-oxo)bis(.mu.-carboxylato)divanadium(III) complexes by protonation of the oxo bridge
Petra Knopp and Karl Wieghardt
pp 4061 - 4066; DOI:
10.1021/ic00021a018
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A binuclear manganese system with three isolated oxidation states: synthesis, structures, and properties of molecules with a Mn2(OR)2 bridge unit containing MnIIIMnIII, MnIIIMnII, and MnIIMnII
Shi Bao Yu, C. P. Wang, E. P. Day, and R. H. Holm
pp 4067 - 4074; DOI:
10.1021/ic00021a019
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A large-angle x-ray scattering, XAFS, and vibrational spectroscopic study of copper(I) halide complexes in dimethyl sulfoxide, acetonitrile, pyridine, and aqueous solutions
Ingmar Persson, Magnus Sandstroem, Andrew T. Steel, Maria J. Zapatero, and Ralf Aakesson
pp 4075 - 4081; DOI:
10.1021/ic00021a020
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Crystal structure and magnetic behavior of (tetramethylcyclotetraazatetradecatetraene) copper tetrachlorocuprate: an alternating-metal-site, alternating-exchange, spin 1/2 linear-chain system
Igor Vasilevesky, Norman R. Rose, Ronald Stenkamp, and Roger D. Willett
pp 4082 - 4084; DOI:
10.1021/ic00021a021
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Metal complexes with biologically important ligands. 62. Platinum(II) complexes of 3-(2-aminoethoxy)estrone and -estradiol
Janina Altman, Thais Castrillo, Wolfgang Beck, Guenther Bernhardt, and Helmut Schoenenberger
pp 4085 - 4088; DOI:
10.1021/ic00021a022
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EPR spectrum and metal-ligand bonding parameters of a low-spin (hexaamine)iron(III) complex
Horst Stratemeier, Michael A. Hitchman, Peter Comba, Paul V. Bernhardt, and Mark J. Riley
pp 4088 - 4093; DOI:
10.1021/ic00021a023
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Cysteine complexes of oxoruthenium(VI): synthesis and characterization of Ru(O)2L2{SCH2CHRC(O)O} (L = py, 1/2 bpy; R = H, NHCHO, NHCOMe)
W. Stuart Bigham and Patricia A. Shapley
pp 4093 - 4095; DOI:
10.1021/ic00021a024
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Preparation of novel low-coordinate chloro and azido phosphorus-nitrogen compounds. Attempted synthesis of cyclodiphosphazenes
Herve Rolland, Edgar Ocando-Mavarez, Philippe Potin, Jean Pierre Majoral, and Guy Bertrand
pp 4095 - 4098; DOI:
10.1021/ic00021a025
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A mononuclear zinc hydroxide complex stabilized by a highly substituted tris(pyrazolyl)hydroborato ligand: analogies with the enzyme carbonic anhydrase
Ralf Alsfasser, Swiatoslaw Trofimenko, Adrian Looney, Gerard Parkin, and Heinrich Vahrenkamp
pp 4098 - 4100; DOI:
10.1021/ic00021a026
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Palladium(I) .pi. complexes: an ESR study of (pentaphenylcyclopentadienyl)palladium dibenzocyclooctatetraene
Janice A. DeGray, William E. Geiger, Gregg A. Lane, and Philip H. Rieger
pp 4100 - 4102; DOI:
10.1021/ic00021a027
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Issue 22


Surface-enhanced Raman spectra of 5,10,15,20-tetrakis(4-carboxyphenyl)porphyrin/silver colloid system: what information about the porphyrin do we obtain?
Blanka Vlckova, Pavel Matejka, Petr Pancoska, Vladimir Baumruk, and Vladimir Kral
pp 4103 - 4105; DOI:
10.1021/ic00022a001
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High oxidation-state compounds containing hydrazine and hydrazido ligands bound to a W(N-2,6-C6H3-iso-Pr2)[2,6-NC5H3(CH2NTosyl)2] core
Shiang Cai and Richard R. Schrock
pp 4105 - 4106; DOI:
10.1021/ic00022a002
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Low-temperature spectroelectrochemical study of tetrabutylammonium chlorodirhenates (Bu4N)Re2Cl9 and (Bu4N)2Re2Cl8: discovery of Re2Cl93-
Graham A. Heath and Raphael G. Raptis
pp 4106 - 4108; DOI:
10.1021/ic00022a003
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Effect of tridentate phosphine ligand structure on the basicities of tungsten tricarbonyl complexes
John R. Sowa, Valerio Zanotti, and Robert J. Angelici
pp 4108 - 4110; DOI:
10.1021/ic00022a004
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A highly reactive triruthenium cluster complex bearing an alkyne coordinated in the .mu.3-.eta.2-perpendicular mode
Soa Rivomanana, Guy Lavigne, Noel Lugan, and Jean Jacques Bonnet
pp 4110 - 4112; DOI:
10.1021/ic00022a005
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Catalytic oxidation of the (hydroxymethyl)chromium(III) ion by the superoxochromium(III) ion
Susannah L. Scott, Andreja Bakac, and James H. Espenson
pp 4112 - 4117; DOI:
10.1021/ic00022a006
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The first gold(III) macrocyclic polyamine complexes and application to selective gold(III) uptake
Eiichi Kimura, Yasuhisa Kurogi, and Toshikazu Takahashi
pp 4117 - 4121; DOI:
10.1021/ic00022a007
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Two fluorinated fluoroxy compounds containing a fluorosulfonyl group
Werner Storzer and Darryl D. DesMarteau
pp 4122 - 4125; DOI:
10.1021/ic00022a008
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Reactions of N,N,N'-tris(trimethylsilyl)benzamidine with organochalcogen halides: formation of diazenes via the resonance-stabilized radicals PhCN2(EPh)2.bul. and the x-ray structure of PhCN2(SCCl3)3
Vadapalli Chandrasekhar, Tristram Chivers, Santhanathan S. Kumaravel, Masood Parvez, and M. N. Sudheendra Rao
pp 4125 - 4130; DOI:
10.1021/ic00022a009
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Halide-complexing characteristics of germa- and stannaimine cages
Michael Veith, Joachim Fischer, Timothy R. Prout, Martin Noetzel, Peter Hobein, and Volker Huch
pp 4130 - 4135; DOI:
10.1021/ic00022a010
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Reactions of gallium trichloride with bis(dialkylamino)dimethylsilanes and bis(alkylamino)dimethylsilanes
W. Rodger Nutt, Jeffrey S. Blanton, Anthony M. Boccanfuso, Louis A. Silks, Albert R. Garber, and Jerome D. Odom
pp 4136 - 4140; DOI:
10.1021/ic00022a011
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Multidentate Lewis acids. Synthesis and structure of complex aluminum chloride alkoxides
Francine Belanger-Gariepy, Karst Hoogsteen, Vijay Sharma, and James D. Wuest
pp 4140 - 4145; DOI:
10.1021/ic00022a012
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Multiply bonded octahalodiosmate(III) anions. 5. Cleavage of the electron-rich osmium-osmium triple bond by carbon monoxide and isocyanide ligands
Thomas W. Johnson, Stephen M. Tetrick, Phillip E. Fanwick, and Richard A. Walton
pp 4146 - 4152; DOI:
10.1021/ic00022a013
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Reactions of monoazadienes with metal carbonyl complexes. 6. Synthesis, separation, and structural characterization (x-ray) of the two diastereomers of Ru3(CO)6[CH3C:C(H)C(H):N-iso-Pr]2, an acyclic trinuclear complex that is isolobally related to Cp2Ru.
Wilhelmus P. Mul, Cornelis J. Elsevier, Wilberth J. J. Smeets, and Anthony L. Spek
pp 4152 - 4159; DOI:
10.1021/ic00022a014
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Oxidation of an o-aminophenol-derived Schiff-base component of a binucleating ligand to a benzoxazole and the crystal structures of a mononuclear palladium derivative and a tetranuclear [palladium-silver] Pd2Ag2 derivative with an unusually short silver-silver distance
B. F. Hoskins, R. Robson, G. A. Williams, and J. C. Wilson
pp 4160 - 4166; DOI:
10.1021/ic00022a015
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Phosphole complexes of silver(I). Investigations of structure and bonding by x-ray crystallography, infrared spectroscopy, and CP/MAS and solution phosphorus-31 NMR spectroscopy
Saeed Attar, Nathaniel W. Alcock, Graham A. Bowmaker, James S. Frye, William H. Bearden, and John H. Nelson
pp 4166 - 4176; DOI:
10.1021/ic00022a016
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Synthesis and reactivity of trans-tricarbonylfluorobis(triphenylphosphine)rhenium and trans-(Me3SiO)3V.tplbond.NRe(CO)3(PPh3)2
Norris W. Hoffman, Nicholas Prokopuk, Martha J. Robbins, Carolyn M. Jones, and Nancy M. Doherty
pp 4177 - 4181; DOI:
10.1021/ic00022a017
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Magic-angle-spinning carbon-13 NMR spectroscopy of molybdenum and tungsten carbonyls supported on X- and Y-type zeolites
William M. Shirley, Cynthia A. Powers, and James S. Frye
pp 4182 - 4185; DOI:
10.1021/ic00022a018
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Facile .alpha./.beta. diastereomerism in organocobalt corrins. Evidence for thermodynamic control in the synthesis of alkylcobamides
Kenneth L. Brown and Xiang Zou
pp 4185 - 4191; DOI:
10.1021/ic00022a019
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Vanadium(IV,V) salts as homogeneous catalysts for the oxygen oxidation of N-(phosphonomethyl)iminodiacetic acid to N-(phosphonomethyl)glycine
Dennis P. Riley, Donald L. Fields, and Willie Rivers
pp 4191 - 4197; DOI:
10.1021/ic00022a020
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Synthesis, crystal structure, and carbon-13 NMR spectra of .alpha.-pyrrolidonato-bridged head-to-head [PtIII2(NH3)4(C4H6NO)2(NO2)(NO3)](NO3)2.cntdot.H2O and electrochemical study on conversion of the binuclear platinum(III) complex into a tetranuclear platinum(III) complex
Takeya Abe, Hiroshi Moriyama, and Kazuko Matsumoto
pp 4198 - 4204; DOI:
10.1021/ic00022a021
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Design, synthesis, and structure of a macrocyclic tetraamide that stabilizes high-valent middle and later transition metals
Terrence J. Collins, Kimberly L. Kostka, Erich S. Uffelman, and Terry L. Weinberger
pp 4204 - 4210; DOI:
10.1021/ic00022a022
PDF
Synthesis, structure, and spectroscopic properties of bismuth citrate compounds. 1. Crystal structures of K5-x(NH4)x[Bi2(cit)2(Hcit)](H2O)y (x = 0.25, y = 13) and (NH4)8[Bi2(cit)2(Hcit)2(H2O)4](H2O)2
Eiji Asato, Willem L. Driessen, Rudolf A. G. De Graaff, Frans B. Hulsbergen, and Jan Reedijk
pp 4210 - 4218; DOI:
10.1021/ic00022a023
PDF
Ethylene, silene, and disilene coordinate bonds with platinum(0) and platinum(II). An ab initio MO/MP4 and SD-CI study
Shigeyoshi Sakaki and Masami Ieki
pp 4218 - 4224; DOI:
10.1021/ic00022a024
PDF
Chlorogallanes (GaClH2, GaCl2H, and GaCl3) and their dimer isomers
Brian J. Duke, Tracy P. Hamilton, and Henry F. Schaefer
pp 4225 - 4229; DOI:
10.1021/ic00022a025
PDF
Photoinduced processes in dyads and triads containing a ruthenium(II)-bis(terpyridine) photosensitizer covalently linked to electron donor and acceptor groups
Jean Paul Collin, Stephane Guillerez, Jean Pierre Sauvage, Francesco Barigelletti, Luisa De Cola, Lucia Flamigni, and Vincenzo Balzani
pp 4230 - 4238; DOI:
10.1021/ic00022a026
PDF
Crystal structures of potassium cryptated salts of the diselenotelluride(2-), pyramidal TeSe32-, and mixed compounds containing pyramidal TeSe32- and chain TexSe4-x2- anions and selenium-77 and tellurium-125 solution NMR studies of the pyramidal selenothiotellurite anions TeSmSe3-m2- (m = 0 - 3)
Mar Bjorgvinsson, Jeffery F. Sawyer, and Gary J. Schrobilgen
pp 4238 - 4245; DOI:
10.1021/ic00022a027
PDF
Tetracyanoquinodimethane salts of transition-metal complexes. 2. Single-crystal electron paramagnetic resonance of tris(1,10-phenanthroline)zinc(II) bis(tetracyanoquinodimethanide) and tris(1,10-phenanthroline) copper(II) bis(tetracyanoquinodimethanide)
Alessandro Bencini and Claudia Zanchini
pp 4245 - 4251; DOI:
10.1021/ic00022a028
PDF
Temperature-dependent crystallographic studies on ferric spin-crossover complexes with different spin-interconversion rates
Hiroki Oshio, Koshiro Toriumi, Yonezo Maeda, and Yoshimasa Takashima
pp 4252 - 4260; DOI:
10.1021/ic00022a029
PDF
Thermal analysis and Raman spectroscopic measurements on the scandium iodide-cesium iodide system
M. M. Metallinou, L. Nalbandian, G. N. Papatheodorou, W. Voigt, and H. H. Emons
pp 4260 - 4264; DOI:
10.1021/ic00022a030
PDF
Synthesis and identification of the monocation Tc(CPI)6+ in Tc(CNC(CH3)2COOCH3)6Cl and its hydrolysis products
James F. Kronauge, Alan Davison, Anne M. Roseberry, Catherine E. Costello, Simin Maleknia, and Alun G. Jones
pp 4265 - 4271; DOI:
10.1021/ic00022a031
PDF
Structure and metal coordination of the diphosphane 2,2'-bis((diphenylphosphino)methyl)-1,1'-biphenyl ("BISBI")
Wolfgang A. Herrmann, Christian W. Kohlpaintner, Eberhardt Herdtweck, and Paul Kiprof
pp 4271 - 4275; DOI:
10.1021/ic00022a032
PDF
Spectroscopic characterization of the octachlorodirhenate(3-) ion, [Re2Cl8]3-
Sandra K. D. Strubinger, Charles L. Hussey, and W. E. Cleland
pp 4276 - 4278; DOI:
10.1021/ic00022a033
PDF
Structural analysis of [Et3NH][Cu(1-B10H9N2)2] and [Et3NH][1-B10H9N2]
Lai Ling Ng, Bradford K. Ng, Kenneth Shelly, Carolyn B. Knobler, and M. Frederick Hawthorne
pp 4278 - 4280; DOI:
10.1021/ic00022a034
PDF
Effect of N-H.cntdot..cntdot..cntdot.S hydrogen bonding in dicyclohexylammonium hexakis(benzenethiolato)dizincate(2-): a model for metallothionein
Wesley P. Chung, John C. Dewan, and M. Anton Walters
pp 4280 - 4282; DOI:
10.1021/ic00022a035
PDF
Stereoselectivity in the oxidation of horse cytochrome c by tris(oxalato)cobaltate(3-)
Joel T. Ficke, Jack R. Pladziewicz, Eileen C. Sheu, and A. Graham Lappin
pp 4282 - 4285; DOI:
10.1021/ic00022a036
PDF
A simple synthetic route to platinum-carbonyl-phosphine cluster compounds
Klaus Hermann Dahmen, Alfred Moor, Ralph Naegeli, and Luigi M. Venanzi
pp 4285 - 4286; DOI:
10.1021/ic00022a037
PDF
Synthesis and characterization of rhenium complexes with 4-ethyl-2,6,7-trioxa-1-phosphabicyclo[2.2.2]octane (P(OCH2)3CEt)
Xiao Liang Luo, Demetrius Michos, and Robert H. Crabtree
pp 4286 - 4288; DOI:
10.1021/ic00022a038
PDF
Structural and spectroscopic properties of the bis(catecholato)dichloroferrate(2-) anion
Ding Zirong, R. Curtis Haltiwanger, Samaresh Bhattacharya, and Cortlandt G. Pierpont
pp 4288 - 4290; DOI:
10.1021/ic00022a039
PDF
Preparation and structural characterization of new derivatives of digermane bearing tris(trimethylsilyl)silyl substituents [Erratum to document cited in CA114(17):164365w]
S. P. Mallela and Russell A. Geanangel
pp 4290 - 4290; DOI:
10.1021/ic00022a040
PDF

Issue 23


Long-range magnetic interactions between manganese centers separated by 7 .ANG. in MnIIIZnIIMnIII and MnIVZnIIMnIV complexes
Phalguni Chaudhuri, Manuela Winter, Frank Birkelbach, Peter Fleischhauer, Wolfgang Haase, Ulrich Floerke, and Hans Juergen Haupt
pp 4291 - 4293; DOI:
10.1021/ic00023a001
PDF
Synthesis and characterization of (.beta.-diketonato)copper(I) alkyne complexes: structural characterization of (hexafluoroacetylacetonato)(diphenylacetylene)copper(I)
K. M. Chi, H. K. Shin, M. J. Hampden-Smith, T. T. Kodas, and E. N. Duesler
pp 4293 - 4294; DOI:
10.1021/ic00023a002
PDF
Catalytic transesterification and hydrolysis of RNA by zinc(II) complexes
Valerie M. Shelton and Janet R. Morrow
pp 4295 - 4299; DOI:
10.1021/ic00023a003
PDF
Selective hydrolysis of unactivated peptide bonds, promoted by platinum(II) complexes anchored to amino acid side chains
Ingrid E. Burgeson and Nenad M. Kostic
pp 4299 - 4305; DOI:
10.1021/ic00023a004
PDF
Reactivity of ferrate(VI) and ferrate(V) with amino acids
Virender K. Sharma and Benon H. J. Bielski
pp 4306 - 4310; DOI:
10.1021/ic00023a005
PDF
Electrochemical potentials and associated pKa values for the various oxidation states of a water-soluble, non .mu.-oxo dimer forming chromium tetraphenylporphyrin in aqueous solution
Seungwon Jeon and Thomas C. Bruice
pp 4311 - 4315; DOI:
10.1021/ic00023a006
PDF
Iron(III) porphyrins substituted with highly electron-withdrawing trifluoromethyl groups: electronic absorption, MCD, and EPR spectral study
Tetsuhiko Yoshimura, Hiroo Toi, Shinji Inaba, and Hisanobu Ogoshi
pp 4315 - 4321; DOI:
10.1021/ic00023a007
PDF
Imidazole adducts of (octaethylporphinato) iron(III) methoxide: resonance Raman evidence for the formation of hydrogen bonds between sterically hindered imidazoles and methoxide
Tadayuki Uno, Keiichiro Hatano, Tatsuya Nawa, Kazuko Nakamura, Yoshifumi Nishimura, and Yoji Arata
pp 4322 - 4327; DOI:
10.1021/ic00023a008
PDF
Nuclear magnetic resonance investigation of the formation of oxalato, malonato, and 2-methylmalonato complexes of platinum(II). Crystal and molecular structures of potassium anti-bis(2-methylmalonato)platinate(II) dihydrate and potassium dichloro(oxalato)platinate(II) hydrate
S. O. Dunham, R. D. Larsen, and E. H. Abbott
pp 4328 - 4335; DOI:
10.1021/ic00023a009
PDF
Preparation of complexes containing the [Mo3S(S2)3]4+ core and structure of tris(diethyldithiocarbamato)tris(.mu.-disulfido)(.mu.3-thio)-triangulo-trimolybdenum(IV) iodide
Heinrich Zimmermann, Kaspar Hegetschweiler, Thomas Keller, Volker Gramlich, Helmut W. Schmalle, Walter Petter, and Walter Schneider
pp 4336 - 4341; DOI:
10.1021/ic00023a010
PDF
Electrochemical reduction of complexes containing the [Mo3S(S2)3]4+ core in aqueous media and the structure of bis(triethylammonium) tris(2-mercaptobenzoato)tris(.mu.-disulfido)(.mu.3-thio)-triangulo-trimolybdate(IV)
Kaspar Hegetschweiler, Thomas Keller, Martin Baeumle, Greti Rihs, and Walter Schneider
pp 4342 - 4347; DOI:
10.1021/ic00023a011
PDF
Reaction of dioxygen with poly[(3,5-dimethylpyrazolato)copper]. Crystal structure, reactivity, and catalytic properties of [Cu8(dmpz)8(OH)8]
G. Attilio Ardizzoia, M. Angela Angaroni, Girolamo La Monica, Franco Cariati, Sergio Cenini, Massimo Moret, and Norberto Masciocchi
pp 4347 - 4353; DOI:
10.1021/ic00023a012
PDF
Sulfur-ligated nickel oxidation states. Chemistry of a family of NizS2N4 (z = +2, +3, +4) complexes incorporating hexadentate thioether-imine-oxime binding
Suranjan Bhanja Choudhury, Debashis Ray, and Animesh Chakravorty
pp 4354 - 4360; DOI:
10.1021/ic00023a013
PDF
Synthesis and molecular structure of copper(I) and organozinc(II) arenethiolates with chelating amino and ether groups: x-ray structure of [CuSC6H4(CH2N(Me)CH2CH2OMe)-2]4 and [Zn(Me){SC6H4((R)-CH(Me)NMe2)-2}]2
D. Martin Knotter, Maurits D. Janssen, David M. Grove, Wilberth J. J. Smeets, Ernst Horn, Anthony L. Spek, and Gerard Van Koten
pp 4361 - 4366; DOI:
10.1021/ic00023a014
PDF
Hydrated phases in the vanadium pentoxide-potassium oxide-sulfur trioxide-water system. Preparation and structures of K[VO2(SO4)(H2O)] and K[VO2(SO4)(H2O)2].cntdot.H2O
Kurt Ludwig Richter and Rainer Mattes
pp 4367 - 4369; DOI:
10.1021/ic00023a015
PDF
Synthesis and characterization of the first multiply bonded [molybdenum-tungsten] heteronuclear edge-sharing bioctahedral complex, MoWCl4(.mu.-Cl)(.mu.-H)(.mu.-dppm)2
F. Albert Cotton, Chris A. James, and Rudy L. Luck
pp 4370 - 4373; DOI:
10.1021/ic00023a016
PDF
Electrophilic substitution reactions in heterocycles complexed to exchange-inert metal ions. (Ethylenediamine)cobalt(III) complexes of imidazole and histidine
N. Rowan-Gordon, A. A. Nguyenpho, E. Mondon-Konan, A. H. Turner, R. J. Butcher, A. S. Okonkwo, H. H. Hayden, and C. B. Storm
pp 4374 - 4380; DOI:
10.1021/ic00023a017
PDF
New ionic ozonides: syntheses, structures, and properties of N(CH3)4O3 and N(C2H5)4O3
Werner Hesse and Martin Jansen
pp 4380 - 4385; DOI:
10.1021/ic00023a018
PDF
New di- and trinuclear complexes of ruthenium with octahedra joined on faces or edges. 4. Compounds containing [(R3P)3RuCl3RuCl3Ru(PR3)3]+ ions: structures, EPR spectroscopy, and electrochemistry
F. Albert Cotton and Raymund C. Torralba
pp 4386 - 4391; DOI:
10.1021/ic00023a019
PDF
New di- and trinuclear complexes of ruthenium with octahedra joined on faces or edges. 5. Further study of edge-sharing bioctahedral complexes of the type Ru2Cl6(PR3)4 (R = Et, Bu)
F. Albert Cotton and Raymund C. Torralba
pp 4392 - 4393; DOI:
10.1021/ic00023a020
PDF
Reaction of trans,trans-dicarbonylhydridonitrosylbis(tertiary phosphine)tungsten with Lewis acidic boron compounds. X-ray structure of trans-W(.eta.2-BH4)(CO)(NO)(PMe3)2
Adolphus A. H. Van der Zeijden, Valery Shklover, and Heinz Berke
pp 4393 - 4396; DOI:
10.1021/ic00023a021
PDF
Synthesis and structural and spectroscopic studies of manganese complexes of pendant-arm macrocycles based on 1,4,7-triazacyclononane: crystal structures of the manganese(II) complex [MnLH3][MnCl4] and of the mixed-valence manganese(II)-manganese(IV) hydrogen-bridged dimer [MnLH3LMn][PF6]3 (LH3 = N,N',N''-tris[(2S)-2-hydroxypropyl]-1,4,7-triazacyclononane) and of the manganese(IV) monomer [MnL'][ClO4] (L'H3 = N,N',N''-tris(2-hydroxyethyl)-1,4,7-triazacyclononane)
Arafa A. Belal, Phalguni Chaudhuri, Ian Fallis, Louis J. Farrugia, Robert Hartung, Norman M. MacDonald, Bernhard Nuber, Robert D. Peacock, Johannes Weiss, and Karl Weighardt
pp 4397 - 4402; DOI:
10.1021/ic00023a022
PDF
Surface cristobalite formation by mild hydrothermal treatment of silica gel and its effect on the deposition of tris(allyl)rhodium and subsequent reactivity of (silica)rhodium(allyl)2
H. Eric Fischer, Steven A. King, John B. Miller, Jackie Y. Ying, Jay B. Benziger, and Jeffrey Schwartz
pp 4403 - 4408; DOI:
10.1021/ic00023a023
PDF
Reinvestigation of epoxidation using tungsten-based precursors and hydrogen peroxide in a biphase medium
Catherine Aubry, Genevieve Chottard, Nicole Platzer, Jean Marie Bregeault, Rene Thouvenot, Francoise Chauveau, Catherine Huet, and Henry Ledon
pp 4409 - 4415; DOI:
10.1021/ic00023a024
PDF
Synthesis and oxidation of cationic heterobinuclear cyanide-bridged complexes of manganese and iron
Georgina Barrado, Gabino A. Carriedo, Carlos Diaz-Valenzuela, and Victor Riera
pp 4416 - 4420; DOI:
10.1021/ic00023a025
PDF
Electrochemistry and photocurrents of the tris(bipyridine)ruthenium(II) and methyl viologen cations immobilized in carrageenan hydrogel
D. Paul Rillema, A. Kirk Edwards, Sherry C. Perine, and Alvin L. Crumbliss
pp 4421 - 4425; DOI:
10.1021/ic00023a026
PDF
Preparation of fluoro(thio)sulfonium salts CF3SSCF3(F)+MF6-, CF3SSCH3(F)+MF6-, and CH3SSCH3(F)+MF6- (M = As, Sb)
Rolf Minkwitz and Gabriele Nowicki
pp 4426 - 4428; DOI:
10.1021/ic00023a027
PDF
Tungsten-183 2D NMR assignments of all tungsten-tungsten connectivities in lacunary and in vanadium(V)-containing .alpha.2-17-tungstodiphosphates. Further insights into relation of structure to 183W chemical shifts
Mariusz Kozik, Rafael Acerete, Charles F. Hammer, and Louis C. W. Baker
pp 4429 - 4433; DOI:
10.1021/ic00023a028
PDF
Bond-stretch isomers of transition-metal complexes. Do they exist?
Jun Song and Michael B. Hall
pp 4433 - 4437; DOI:
10.1021/ic00023a029
PDF
Chemical applications of topology and group theory. 25. Electron delocalization in early-transition-metal heteropoly- and isopolyoxometalates
R. B. King
pp 4437 - 4440; DOI:
10.1021/ic00023a030
PDF
Ab initio Study of the coordination modes of tetrahydroborato ligands: the high-spin complex bis(phosphine)tris(tetrahydroborato)vanadium
Agusti Lledos, Miquel Duran, Yves Jean, and Francois Volatron
pp 4440 - 4445; DOI:
10.1021/ic00023a031
PDF
Electronic spectra and photophysics of platinum(II) complexes with .alpha.-diimine ligands solid-state effects. 2. Metal-metal interaction in double salts and linear chains
Vincent M. Miskowski and Virginia H. Houlding
pp 4446 - 4452; DOI:
10.1021/ic00023a032
PDF
Surface electrochemistry of chloro(phthalocyaninato)rhodium(III) species and oxygen reduction electrocatalysis. Formation of a dimeric species
Yu Hong Tse, Penny Seymour, Nagao Kobayashi, Herman Lam, Clifford C. Leznoff, and A. B. P. Lever
pp 4453 - 4459; DOI:
10.1021/ic00023a033
PDF
Solution spectroscopic studies of electrolytically generated iron(III) and iron(IV) tetrakis(2,6-difluorophenyl)porphyrin .pi. cation radicals
Alaganandan Nanthakumar and Harold M. Goff
pp 4460 - 4464; DOI:
10.1021/ic00023a034
PDF
Mononuclear tungsten(VI) calix[4]arene complexes
Fabio Corazza, Carlo Floriani, Angiola Chiesi-Villa, and Corrado Rizzoli
pp 4465 - 4468; DOI:
10.1021/ic00023a035
PDF
Oxidative homolysis reactions between organochromium macrocycles and dihalide radical anions
Shu Shi, James H. Espenson, Dan Meyerstein, and Dan Meisel
pp 4468 - 4470; DOI:
10.1021/ic00023a036
PDF
Kinetic and thermodynamic acidity of hydrido transition-metal complexes. 9. A sterically hindered cationic hydride, [H4Re(PMe2Ph)4]+
S. Soley Kristjansdottir, Amy J. Loendorf, and Jack R. Norton
pp 4470 - 4471; DOI:
10.1021/ic00023a037
PDF
Octahedral metal carbonyls. 78. Mechanism of alkane displacement by 1-hexene from (alkane)pentacarbonyltungsten complexes (alkane = cyclohexane, n-heptane). Estimates of the alkane-tungsten bond strengths in condensed media
Gerard R. Dobson, Charles D. Cate, Colin W. Cate, and Khalil J. Asali
pp 4471 - 4474; DOI:
10.1021/ic00023a038
PDF
Structural and redox properties of the Tempo adducts of copper(II) halides
Jean Laugier, Jean Marc Latour, Andrea Caneschi, and Paul Rey
pp 4474 - 4477; DOI:
10.1021/ic00023a039
PDF
ESR spectra of hexaaquamolybdenum(III) ions in cesium indium alum
Claus J. H. Jacobsen and Erik Pedersen
pp 4477 - 4478; DOI:
10.1021/ic00023a040
PDF

Issue 24


Synthesis and x-ray diffraction crystal structure of bis[bis(2,2,6,6-tetramethylheptane-3,5-dionato)diamminebarium]. A novel low-molecularity barium compound
William S. Rees, Michael W. Carris, and Werner Hesse
pp 4479 - 4481; DOI:
10.1021/ic00024a001
PDF
An interesting low barrier to metal-ligand contrarotational fluxionality in closed 11-vertex [1,1-(PMe2Ph)2-1,2,3-PtC2B8H9X] compounds that is characterized by arachno .dblharw. nido geometric changes within the 10-vertex .eta.6-{C2B8H9X} ligand
John D. Kennedy, Mark Thornton-Pett, Bohumil Stibr, and Tomas Jelinek
pp 4481 - 4484; DOI:
10.1021/ic00024a002
PDF
Thermodynamic nucleic base specificity in nucleotide-metallointercalator association. Structure-stability relationship showing significant contribution of the amino group to aromatic ring stacking
Akira Odani, Hideki Masuda, Osamu Yamauchi, and Shinichi Ishiguro
pp 4484 - 4486; DOI:
10.1021/ic00024a003
PDF
Luminescent nitridorhenium(V) complexes
Gregory A. Neyhart, Kevin J. Seward, James Boaz, and B. Patrick Sullivan
pp 4486 - 4488; DOI:
10.1021/ic00024a004
PDF
Reactions at metal-bound nitrogen atoms. Synthesis and structure of vanadium complex V(NPMePh2)Cl4(NCMe).MeCN
Beth M. Schomber, Joseph W. Ziller, and Nancy M. Doherty
pp 4488 - 4490; DOI:
10.1021/ic00024a005
PDF
Ni2Cl2[C(SiMe3)(PMe3)]2, containing a very short nickel-nickel distance with little metal-metal bonding character: possible synergy of electronic and steric factors
Georges Trinquier, Michele Dartiguenave, Yves Dartiguenave, and Marc Benard
pp 4490 - 4497; DOI:
10.1021/ic00024a006
PDF
Electrochemical and spectroelectrochemical studies of tin(II) porphyrins
K. M. Kadish, D. Dubois, J. M. Barbe, and R. Guilard
pp 4498 - 4501; DOI:
10.1021/ic00024a007
PDF
Electrochemistry of five- and six-coordinate .sigma.-bonded cobalt porphyrins. Reactions of (TPP)Co(C2H5)(py) and (TPP)Co(R) where TPP is the dianion of tetraphenylporphyrin and R = CH3, C2H5, or CH2Cl
K. M. Kadish, B. C. Han, and A. Endo
pp 4502 - 4506; DOI:
10.1021/ic00024a008
PDF
Oxidation of alkanes by cobalt(II) salts of weakly coordinating anions
Alan S. Goldstein and Russell S. Drago
pp 4506 - 4510; DOI:
10.1021/ic00024a009
PDF
Comparative proton NMR study of ferric low-spin cytochrome c peroxidase and horseradish peroxidase
Lucia Banci, Ivano Bertini, Paola Turano, Juan C. Ferrer, and A. Grant Mauk
pp 4510 - 4516; DOI:
10.1021/ic00024a010
PDF
Proton NMR spectra of oxidized high-potential iron-sulfur protein (HiPIP) from Rhodocyclus gelatinosus. A model for oxidized HiPIPs
Lucia Banci, Ivano Bertini, Fabrizio Briganti, Claudio Luchinat, Andrea Scozzafava, and Margarita Vicens Oliver
pp 4517 - 4524; DOI:
10.1021/ic00024a011
PDF
Synthesis, properties, and complexation of a new imidazole-pendant macrocyclic 12-membered triamine ligand
Eiichi Kimura, Yasuhisa Kurogi, Mitsuhiko Shionoya, and Motoo Shiro
pp 4524 - 4530; DOI:
10.1021/ic00024a012
PDF
Characterization and properties of monoammine nitroimidazole complexes of platinum [PtCl2(NH3)(NO2Im)]. Crystal and molecular structure of cis-amminedichloro(1-{(((2-hydroxyethyl)amino)carbonyl)methyl}-2-nitroimidazole)platinum(II)
Fernande D. Rochon, Pi Chang Kong, Robert Melanson, Kirsten A. Skov, and Nicholas Farrell
pp 4531 - 4535; DOI:
10.1021/ic00024a013
PDF
Syntheses and characterization of complexes derived from .alpha.-aminomalonate and trans-[CoCl2(2,3,2-tet)]+ (2,3,2-tet = 1,9-diamino-3,7-diazanonane)
T. Kojima, T. Usui, A. Shimada, M. Yashiro, T. Tanase, R. Yoshioka, R. Kuroda, S. Yano, M. Hidai, and et al.
pp 4535 - 4541; DOI:
10.1021/ic00024a014
PDF
X-ray structural and NMR characterization of the copper(I) dimer [Cu(dmpe)2]2(BF4)2, where dmpe is 1,2-bis(dimethylphosphino)ethane
Bernhard Mohr, Elwood E. Brooks, Nigam Rath, and Edward Deutsch
pp 4541 - 4545; DOI:
10.1021/ic00024a015
PDF
Electron-transfer reactions of technetium and rhenium complexes. 3. Pulse radiolysis studies on trans-[MIIIX2(DMPE)2]+ and [MI(DMPE)3]+ complexes in aqueous and aqueous surfactant media, where M = Tc or Re, X = Cl or Br, and DMPE = 1,2-bis(dimethylphosphino)ethane
Andreas Roodt, James C. Sullivan, Dan Meisel, and Edward Deutsch
pp 4545 - 4549; DOI:
10.1021/ic00024a016
PDF
Proton NMR investigation of the tetrahydrofuran replacement by phosphine ligands on trichlorotris (tetrahydrofuran)molybdenum. A trans effect
Rinaldo Poli and John C. Gordon
pp 4550 - 4554; DOI:
10.1021/ic00024a017
PDF
Is the oxidation of L-ascorbic acid by aquated iron(III) ions in acidic aqueous solution substitution- or electron-transfer-controlled? A combined chloride, pH, temperature, and pressure dependence study
B. Baensch, P. Martinez, D. Uribe, J. Zuluaga, and R. Van Eldik
pp 4555 - 4559; DOI:
10.1021/ic00024a018
PDF
Effect of pressure on the complex formation and aquation kinetics of iron(III) with hydroxamic acids
Mladen Birus and Rudi Van Eldik
pp 4559 - 4563; DOI:
10.1021/ic00024a019
PDF
Interaction of metal cations with heteropolytungstate ions SiW12O404- and P2W18O626-
Akira Saito and Gregory R. Choppin
pp 4563 - 4566; DOI:
10.1021/ic00024a020
PDF
Low-spin monoiron(III) and oxo-bridged diiron(III) complexes of bis(difluoro(dimethylglyoximato)borate)
Dennis V. Stynes, Horst Noglik, and David W. Thompson
pp 4567 - 4571; DOI:
10.1021/ic00024a021
PDF
Kinetics of the reduction of oxo-bridged diiron complexes of bis(difluoro(dimethylglyoximato)borate) with hydroxy aromatics, amines, and phosphines
Horst Noglik, David W. Thompson, and Dennis V. Stynes
pp 4571 - 4575; DOI:
10.1021/ic00024a022
PDF
Ligand field photochemistry of pentacyanoferrate(II) complexes with diamine ligands: influence of the chelating ligands and the role of neighboring group effects on the photoinduced ring closure process
Neyde Yukie Murakami Iha and Jailson Farias de Lima
pp 4576 - 4579; DOI:
10.1021/ic00024a023
PDF
Synthesis and spectroscopic properties of zeolite-entrapped bis-heteroleptic ruthenium(II) polypyridine complexes
Krzysztof Maruszewski, Dennis P. Strommen, Kristy Handrich, and James R. Kincaid
pp 4579 - 4582; DOI:
10.1021/ic00024a024
PDF
Structure of the dimethyl ether-sulfur dioxide complex
Jung Jin Oh, Kurt W. Hillig, and Robert L. Kuczkowski
pp 4583 - 4588; DOI:
10.1021/ic00024a025
PDF
Structural dependence of the luminescence from bis(substituted benzenethiolato)(2,9-dimethyl-1,10-phenanthroline)zinc(II) complexes
K. J. Jordan, W. F. Wacholtz, and G. A. Crosby
pp 4588 - 4593; DOI:
10.1021/ic00024a026
PDF
Nonradiative decay in rhenium(I) monometallic complexes of 2,3-di-2-pyridylpyrazine
John A. Baiano and W. Rorer Murphy
pp 4594 - 4598; DOI:
10.1021/ic00024a027
PDF
Synthesis and reduction of osmium(VI) nitrido complexes and x-ray crystal structure of tetra-n-butylammonium octachlorodinitrido(.mu.-pyrazine)diosmate(VI)
David C. Ware and Henry Taube
pp 4598 - 4605; DOI:
10.1021/ic00024a028
PDF
Substitution-induced nitrogen-nitrogen coupling for nitride coordinated to osmium(VI)
David C. Ware and Henry Taube
pp 4605 - 4610; DOI:
10.1021/ic00024a029
PDF
Extensive substitution, protonation, and methoxidation reactions of triruthenium carbonyl clusters containing 2-amino-6-methylpyridinato (.mu.3-ampy) as a face-bridging ligand. X-ray structures of [Ru3(.mu.-H)(.mu.3-ampy)(CO)7(PPh3)2] and [Ru3(.mu.-H)2(.mu.3-ampy)(CO2Me)(CO)6(PPh3)2].cntdot.MeOH
Pedro L. Andreu, Javier A. Cabeza, Maria A. Pellinghelli, Victor Riera, and Antonio Tiripicchio
pp 4611 - 4616; DOI:
10.1021/ic00024a030
PDF
Hydrido thiolato and thiolato complexes of ruthenium(II) carbonyl phosphines
Philip G. Jessop, Steven J. Rettig, Chung Li Lee, and Brian R. James
pp 4617 - 4627; DOI:
10.1021/ic00024a031
PDF
Monomeric and dimeric titanatranes
W. M. P. B. Menge and J. G. Verkade
pp 4628 - 4631; DOI:
10.1021/ic00024a032
PDF
Preparation of unsymmetrically B-substituted borazines and characterization of tris(4,6-diethylborazin-2-yl)amine
J. Bai, K. Niedenzu, J. Serwatowska, and J. Serwatowski
pp 4631 - 4635; DOI:
10.1021/ic00024a033
PDF
Perfluorocarbon phosphonic and sulfonic acids containing discretely varying terminal functional groups
Bobbie L. Rice, Cai Yun Guo, and Robert L. Kirchmeier
pp 4635 - 4638; DOI:
10.1021/ic00024a034
PDF
Synthesis and structural characterization of trimethylphosphine complexes of technetium(III)
Patricia L. Watson, Joseph A. Albanese, Joseph C. Calabrese, Derick W. Ovenall, and Richard G. Smith
pp 4638 - 4643; DOI:
10.1021/ic00024a035
PDF
Dependence of complex structure on ligand conformation in palladium(II) complexes of the crown thioether ligands 2,5,8-trithia[9]-o-benzenophane (TT[9]OB) and 2,5,8-trithia[9]-m-benzenophane (TT[9]MB). Structures of PdCl2(TT[9]OB).cntdot.DMSO and PdCl2(TT[9]MB)
Broer De Groot, Garry S. Hanan, and Stephen J. Loeb
pp 4644 - 4647; DOI:
10.1021/ic00024a036
PDF
Vibrational and electronic spectra of tetrasulfatodiplatinate(2-) complexes
Robert A. Newman, Don S. Martin, Richard F. Dallinger, William H. Woodruff, Albert E. Stiegman, Chi Ming Che, William P. Schaefer, Vincent M. Miskowski, and Harry B. Gray
pp 4647 - 4654; DOI:
10.1021/ic00024a037
PDF
Spectroscopic and electrochemical characterization of nickel .beta.-oxoporphyrins: identification of nickel(III) oxidation products
Patricia A. Connick and Kathleen A. Macor
pp 4654 - 4663; DOI:
10.1021/ic00024a038
PDF
Is there a hole in the t2g subshell in the chromium(III) doublets?
Patrick E. Hoggard
pp 4664 - 4666; DOI:
10.1021/ic00024a039
PDF
A unidentate thiometalate complex: (MeCp)(dppe)Ru-S-ReS3 [bis(diphenylphosphinoethane][methyl cyclopentadienyl-.mu.-sulfidotrisulfidorheniumruthenium]
Mark A. Massa, Thomas B. Rauchfuss, and Scott R. Wilson
pp 4667 - 4669; DOI:
10.1021/ic00024a040
PDF
Disproportionation of the bis(benzene)chromium cation induced by pyridine. Crystal and molecular structure of two tetrapyridine complexes containing chromium(II) and chromium(III)
Giovanni Fochi, Joachim Straehle, and Franz Gingl
pp 4669 - 4671; DOI:
10.1021/ic00024a041
PDF
Rational design of linear trinuclear metal complexes
L. Keith Woo and Mannar R. Maurya
pp 4671 - 4673; DOI:
10.1021/ic00024a042
PDF
Nuclearity and formulation of SALPN2- complexes formed from M(O2CCH3)2: resolution of longstanding problems by x-ray crystallography
Alessandra Gerli, Karl S. Hagen, and Luigi G. Marzilli
pp 4673 - 4676; DOI:
10.1021/ic00024a043
PDF
A zinc complex of the carbonic anhydrase inhibitor acetazolamide (aaaH): crystal structure of (aaa)2Zn(NH3)2
Uwe Hartmann and Heinrich Vahrenkamp
pp 4676 - 4677; DOI:
10.1021/ic00024a044
PDF
Synthesis and structural characterization of a bis(cyclopentadienyl)methane-cobaltacarborane complex: CH2[closo-1-(.eta.-C5H4)Co(2,3-Et2C2B4H4)]2
Carole A. Plumb, Patrick J. Carroll, and Larry G. Sneddon
pp 4678 - 4680; DOI:
10.1021/ic00024a045
PDF
X-ray crystal structure of bismuth dimethylamide
William Clegg, Neville A. Compton, R. John Errington, George A. Fisher, Marjorie E. Green, David C. R. Hockless, and Nicholas C. Norman
pp 4680 - 4682; DOI:
10.1021/ic00024a046
PDF
Reactions of bis(nitro) (.alpha.,.alpha.,.alpha.,.alpha.-tetrakis(o-pivalamidophenyl)porphinato)ferrate(III) with pyridine and imidazole. EPR and Moessbauer spectra and molecular structures of the mixed-ligand species [Erratum to document cited in CA114:177156]
Habib Nasri, Yaning Wang, Huynh Boi Hanh, F. Ann Walker, and W. Robert Scheidt
pp 4682 - 4682; DOI:
10.1021/ic00024a047
PDF

Issue 25


Influence of phosphine conformation on the structure and stereodynamics of tetracarbonyl(tri-o-tolylphosphine)iron and pentacarbonyl(tri-o-tolylphosphine)chromium
James A. S. Howell, Michael G. Palin, Patrick McArdle, Desmond Cunningham, Zeev Goldschmidt, Hugo E. Gottlieb, and Dafna Hezroni-Langerman
pp 4683 - 4685; DOI:
10.1021/ic00025a001
PDF
Crown ether encapsulation effects upon optical electron-transfer energetics in a symmetrical mixed-valence system
Matthew D. Todd, Yuhua Dong, and Joseph T. Hupp
pp 4685 - 4687; DOI:
10.1021/ic00025a002
PDF
Tetrabutylammonium tetrakis[3,5-bis(trifluoromethyl)phenyl]borate as a noncoordinating electrolyte: reversible 1e- oxidations of ruthenocene, osmocene, and Rh2(TM4)42+ (TM4=2,5-diisocyano-2,5-dimethylhexane)
Michael G. Hill, William M. Lamanna, and Kent R. Mann
pp 4687 - 4690; DOI:
10.1021/ic00025a003
PDF
Palladium-hydrogen-phosphorus bridging in a palladium(I) dimer
A. Albinati, F. Lianza, M. Pasquali, M. Sommovigo, P. Leoni, P. S. Pregosin, and H. Ruegger
pp 4690 - 4692; DOI:
10.1021/ic00025a004
PDF
Synthesis and reactivity of platinum and palladium complexes with a phosphorus analog of 2,2'-bipyridine, NIPHOS. X-ray crystal structure of [PtCl(NIPHOSH.cntdot.OMe)(PMe3)][SbF6]
Bruno Schmid, Luigi M. Venanzi, Alberto Albinati, and Francois Mathey
pp 4693 - 4699; DOI:
10.1021/ic00025a005
PDF
Nucleophilic attacks of 1,2-diaminoethane on MeCN ligands: synthesis, x-ray structure, and spectral and electrochemical properties of [Ru(.mu.-O)(.mu.-O2CAr)2[NH2CH2CH2NHC(Me)NH]2(PPh3)2](ClO4)2(Ar = C6H4-p-X; X = H, Me, OMe, Cl)
Ariyanchira Syamala and Akhil R. Chakravarty
pp 4699 - 4704; DOI:
10.1021/ic00025a006
PDF
Synthesis and characterization of copper- and silver-containing platinum-gold cluster compounds. X-ray crystal structure of [Pt(CuCl)(AuPPh3)8](NO3)2.cntdot.CH3OH
M. F. J. Schoondergang, J. J. Bour, P. P. J. Schlebos, A. W. P. Vermeer, W. P. Bosman, J. M. M. Smits, P. T. Beurskens, and J. J. Steggerda
pp 4704 - 4709; DOI:
10.1021/ic00025a007
PDF
Reactions of a cobalt-molybdenum and related cobalt-tungsten tetrahedral clusters with phenylacetylene: formation of tetrametallic alkyne clusters or cluster fragmentation?
Michael J. Chetcuti, Phillip E. Fanwick, and John C. Gordon
pp 4710 - 4717; DOI:
10.1021/ic00025a008
PDF
Cluster synthesis. 36. New platinum-ruthenium and platinum-osmium carbonyl cluster complexes from the reactions of the complexes Pt2M4(CO)18 (M = ruthenium, osmium) with cycloocta-1,5-diene in the presence of UV irradiation
Richard D. Adams, Michael S. Alexander, Isam Arafa, and Wengan Wu
pp 4717 - 4723; DOI:
10.1021/ic00025a009
PDF
Bimetallic hydrazido(3- and 4-) and nitrido complexes of tungsten containing the W(.eta.5-C5Me5)Me3 core
Timothy E. Glassman, Andrew H. Liu, and Richard R. Schrock
pp 4723 - 4732; DOI:
10.1021/ic00025a010
PDF
Characterization of silica-supported osmium carbonyl clusters by magic-angle-spinning carbon-13 NMR spectroscopy
Thomas H. Walter, Greg R. Frauenhoff, John R. Shapley, and Eric Oldfield
pp 4732 - 4739; DOI:
10.1021/ic00025a011
PDF
Separating the rhenium-hydride and proton-proton dipole-dipole contributions to the 1H NMR spin-lattice relaxation rate of the hydride ligand in mer,trans-ReH(CO)3(PPh3)2 by deuteration
Xiao Liang Luo, Hong Liu, and Robert H. Crabtree
pp 4740 - 4742; DOI:
10.1021/ic00025a012
PDF
Phosphole complexes of copper(I) halides. Investigations of structure and bonding by x-ray crystallography, infrared spectroscopy, and CP/MAS phosphorus-31 NMR spectroscopy
Saeed Attar, Graham A. Bowmaker, Nathaniel W. Alcock, James S. Frye, William H. Bearden, and John H. Nelson
pp 4743 - 4753; DOI:
10.1021/ic00025a013
PDF
Structural, spectral, and charge-transfer properties of ClRe(CO)3(2-PP) [2-PP = N-(2-pyridinylmethylene)phenylamine] and ClRe(CO)3(2-PC) [2-PC = N-(2-pyridinylmethylene)cyclohexylamine]
Raymond N. Dominey, Brian Hauser, John Hubbard, and Jennifer Dunham
pp 4754 - 4758; DOI:
10.1021/ic00025a014
PDF
Gas-phase electron-diffraction studies of the molecular structures of tetrabromo(sulfido)tungsten(VI), WSBr4, and tetrabromo(seleno)tungsten(VI), WSeBr4
Elizabeth M. Page, David A. Rice, Kolbjorn Hagen, Lise Hedberg, and Kenneth Hedberg
pp 4758 - 4761; DOI:
10.1021/ic00025a015
PDF
Molecular structure of chromyl nitrate (CrO2(NO3)2) in the gas phase: a novel form of coordination for chromium?
Colin J. Marsden, Kenneth Hedberg, M. M. Ludwig, and Gary L. Gard
pp 4761 - 4766; DOI:
10.1021/ic00025a016
PDF
Synthesis and characterization of dihalogenoruthenium(IV) and diphenylruthenium(IV), and phenylruthenium(III) tetraphenylporphyrin complexes, including the crystal structure of Ru(TPP)Br2
Mingzhe Ke, Chand Sishta, Brian R. James, David Dolphin, John W. Sparapany, and James A. Ibers
pp 4766 - 4771; DOI:
10.1021/ic00025a017
PDF
Synthesis of complexes of rhodium(I) and iridium(I) with 3,5-pyrazoledicarboxylic acid and their mixed-valence oxidation products
J. C. Bayon, G. Net, P. Esteban, P. G. Rasmussen, and D. F. Bergstrom
pp 4771 - 4777; DOI:
10.1021/ic00025a018
PDF
Synthesis, electrochemistry, magnetic and spectroscopic properties of an exchange-coupled iron(III)-nickel(II)-iron(III) complex. Crystal structure of [L2Fe2(dmg)3Ni](PF6)2.0.5CH3OH (L = 1,4,7-trimethyl-1,4,7-triazacyclononane; dmg = dimethylglyoximate(2-))
Phalguni Chaudhuri, Manuela Winter, Beatriz P. C. Della Vedova, Peter Fleischhauer, Wolfgang Haase, Ulrich Floerke, and Hans Juergen Haupt
pp 4777 - 4783; DOI:
10.1021/ic00025a019
PDF
Complexes of group 15 metals with sterically hindered thiolate ligands. Crystal and molecular structures of [Sb(2-SC5H4N)3], [Sb(2-SC5H3N-3-SiMe3)3], and [Bi(2-SC5H3N-3-SiMe3)3]
Eric Block, Gabriel Ofori-Okai, Hyunkyu Kang, Jin Wu, and Jon Zubieta
pp 4784 - 4788; DOI:
10.1021/ic00025a020
PDF
Syntheses and structures of lanthanum germanide, LaGe2-x, and lanthanum aluminum germanide, LaAlGe: interrelationships among the .alpha.-ThSi2, .alpha.-GdSi2, and LaPtSi structure types
Arnold M. Guloy and John D. Corbett
pp 4789 - 4794; DOI:
10.1021/ic00025a021
PDF
Two novel titanium halide phases: KTi4Cl11 and CsTi4.3I11
Jie Zhang, Ru Yi Qi, and John D. Corbett
pp 4794 - 4798; DOI:
10.1021/ic00025a022
PDF
Reactions of alkali-metal poly(1-pyrazolyl)borates with Main Group element halides
C. H. Dungan, W. Maringgele, A. Meller, K. Niedenzu, H. Noeth, J. Serwatowska, and J. Serwatowski
pp 4799 - 4806; DOI:
10.1021/ic00025a023
PDF
Synthesis and reactivity of the pentaamminecobalt(III) linkage isomers of succinimide
Patricia M. Angus and W. Gregory Jackson
pp 4806 - 4813; DOI:
10.1021/ic00025a024
PDF
Kinetics and stereochemistry of base hydrolysis of (+)-[Co(dienim)(en)Cl]2+ and the racemization of (+)-[Co(dienim)(en)OH]2+
W. Gregory Jackson and Rachelle J. Walsh
pp 4813 - 4820; DOI:
10.1021/ic00025a025
PDF
Two fluorinated, fluorosulfonyl-containing hypochlorites and their alkali-metal precursors
Werner Storzer and Darryl D. DesMarteau
pp 4821 - 4826; DOI:
10.1021/ic00025a026
PDF
Alkyl radical colligation and release by a chromium macrocycle
Patrick Huston, James H. Espenson, and Andreja Bakac
pp 4826 - 4830; DOI:
10.1021/ic00025a027
PDF
Kinetics and mechanism of the oxidation of hexaaquavanadium(II) ions by alkyl radicals
James H. Espenson, Andreja Bakac, and Jeong Hyun Kim
pp 4830 - 4833; DOI:
10.1021/ic00025a028
PDF
Reductive defluorination of (trifluoromethyl)cobamides
Kenneth L. Brown, Xiang Zou, Michael Richardson, and William P. Henry
pp 4834 - 4838; DOI:
10.1021/ic00025a029
PDF
Non-metal redox kinetics: iodine monobromide reaction with iodide ion and the hydrolysis of IBr
Robert C. Troy, Mark D. Kelley, Julius C. Nagy, and Dale W. Margerum
pp 4838 - 4845; DOI:
10.1021/ic00025a030
PDF
Non-metal redox kinetics: a reexamination of the mechanism of the reaction between hypochlorite and nitrite ions
Debra W. Johnson and Dale W. Margerum
pp 4845 - 4851; DOI:
10.1021/ic00025a031
PDF
Kinetic and equilibrium studies of the complexation of aqueous iron(III) by daunomycin, quinizarin, and quinizarin-2-sulfonate
S. S. Massoud and R. B. Jordan
pp 4851 - 4856; DOI:
10.1021/ic00025a032
PDF
Kinetic and thermodynamic synergism of chloride and carbon monoxide binding to bis(acetonitrile)bis((dimethylglyoximato)difluoroborato)iron(II)
D. G. A. H. De Silva, David W. Thompson, and Dennis V. Stynes
pp 4856 - 4858; DOI:
10.1021/ic00025a033
PDF
Synthesis, crystal and molecular structure, and magnetic properties of bis[(.mu.-3,5-diamino-1,2,4-triazole-N1,N2-bis(.mu.-3,5-diamino-1,2,4-triazolato-N1,N2)triaquacobalt(II))]cobalt(III) trichloride nonahydrate
L. Antolini, A. C. Fabretti, D. Gatteschi, A. Giusti, and R. Sessoli
pp 4858 - 4860; DOI:
10.1021/ic00025a034
PDF
Reactions of aryl(B-carboranyl)iodonium cations with the fluoride anion. Synthesis of icosahedral o-carboran-9-yl, m-carboran-9-yl, and p-carboran-2-yl fluorides
V. V. Grushin, I. I. Demkina, and T. P. Tolstaya
pp 4860 - 4863; DOI:
10.1021/ic00025a035
PDF
Carbon-carbon double-bond formation in the intermolecular acetonitrile reductive coupling promoted by a mononuclear titanium(II) compound. Preparation and characterization of two titanium(IV) imido derivatives
Robbert Duchateau, Antony J. Williams, Sandro Gambarotta, and Michael Y. Chiang
pp 4863 - 4866; DOI:
10.1021/ic00025a036
PDF
Simple syntheses and alkylation reactions of 3-iodo-o-carborane and 9,12-diiodo-o-carborane
Ji Li, Cameron F. Logan, and Maitland Jones
pp 4866 - 4868; DOI:
10.1021/ic00025a037
PDF
Oligomeric gallium amide/hydride complexes, [H2Ga2{(NPriCH2)2}2] and [H5Ga3{(NMeCH2)2}2], via hydrometalation and metalation
Jerry L. Atwood, Simon G. Bott, Cameron Jones, and Colin L. Raston
pp 4868 - 4870; DOI:
10.1021/ic00025a038
PDF

Issue 26


The luminescent fac-tricarbonylchloro(4,7-diphenyl-1,10-phenanthroline)rhenium complex as a spectroscopic probe in monitoring photochemical polymerization of epoxy resins
Thomas G. Kotch, Alistair J. Lees, Stephen J. Fuerniss, Kostas I. Papathomas, and Randy Synder
pp 4871 - 4873; DOI:
10.1021/ic00026a001
PDF
Is chromium hexafluoride octahedral? Experiment still suggests "yes!"
Eric G. Hope, William Levason, and J. Steven Ogden
pp 4873 - 4874; DOI:
10.1021/ic00026a002
PDF
A new class of tetrapodal ligands
Teddy G. Traylor, Patricia S. Traylor, and Ben Yao Liu
pp 4874 - 4875; DOI:
10.1021/ic00026a003
PDF
A remarkable hypoelectronic indium cluster in K8In11
Slavi C. Sevov and John D. Corbett
pp 4875 - 4877; DOI:
10.1021/ic00026a004
PDF
A model for the substrate adduct of copper nitrite reductase and its conversion to a novel tetrahedral copper(II) triflate complex
William B. Tolman
pp 4877 - 4880; DOI:
10.1021/ic00026a005
PDF
A 3-coordinate 4-electron phosphorus donor
Anthony J. Arduengo, H. V. Rasika Dias, and Joseph C. Calabrese
pp 4880 - 4882; DOI:
10.1021/ic00026a006
PDF
Siderophore chemistry of vanadium. Kinetics and equilibrium of interaction between vanadium(IV) and desferrioxamine B in aqueous acidic solutions
Ines Batinic-Haberle, Mladen Birus, and Marijan Pribanic
pp 4882 - 4887; DOI:
10.1021/ic00026a007
PDF
Influence of the distal para substituent through NH---S hydrogen bonds on the positive shift of the reduction potentials of [Fe4S4(Z-cys-Gly-NHC6H4-p-X)4]2- (X = H, OMe, F, Cl, CN) complexes
Ryotaro Ohno, Norikazu Ueyama, and Akira Nakamura
pp 4887 - 4891; DOI:
10.1021/ic00026a008
PDF
Spectroscopic studies of ferric porphyrins with quantum mechanically admixed intermediate-spin states: models for cytochrome c'
Elisabeth T. Kintner and John H. Dawson
pp 4892 - 4897; DOI:
10.1021/ic00026a009
PDF
2,2':4,4'':4',4'''-Quaterpyridyl: a building block for the preparation of novel redox reagents. 2. Bis(2,2'-bipyridine)ruthenium(II) complexes
Karen Bierig, Robert J. Morgan, Steven Tysoe, Harry D. Gafney, Thomas C. Strekas, and A. David Baker
pp 4898 - 4903; DOI:
10.1021/ic00026a010
PDF
Preparation, structure, and properties of the bis(.mu.-acetato)(.mu.-oxo)ruthenium(III) dimers [Ru2(.mu.-CH3COO)2(.mu.-O)(py)6]2+ and [Ru2(.mu.-CH3COO)2(.mu.-O)(bpy)2(py)2]2+
Yoichi Sasaki, Masakazu Suzuki, Akira Nagasawa, Ayako Tokiwa, Masahiro Ebihara, Tadashi Yamaguchi, Chizuko Kabuto, Takashi Ochi, and Tasuku Ito
pp 4903 - 4908; DOI:
10.1021/ic00026a011
PDF
Syntheses and characterization of binuclear manganese(III,IV) and -(IV,IV) complexes with ligands related to N,N'-bis(2-pyridylmethyl)-1,2-ethanediamine
Patricia A. Goodson, Joergen Glerup, Derek J. Hodgson, Kirsten Michelsen, and Hoegni Weihe
pp 4909 - 4914; DOI:
10.1021/ic00026a012
PDF
Synthesis and characterization of a pentadentate Schiff base N3O2 ligand and its neutral technetium(V) complex. X-ray structure of {N,N'-3-azapentane-1,5-diylbis(3-(1-iminoethyl)-6-methyl-2H-pyran-2,4(3H)-dionato)(3-)-O,O',N,N',N''}oxotechnetium(V)
Shuang Liu, Steven J. Rettig, and Chris Orvig
pp 4915 - 4919; DOI:
10.1021/ic00026a013
PDF
Synthesis and characterization of the (thiolato)rhenium(III) complexes trans-[Re(SR)2(R'2PCH2CH2PR'2)2]+, where R is an alkyl, benzyl, or phenyl group and R' is an ethyl or phenyl group. Single-crystal structural analyses of trans-[Re(SC6H5)2(Et2PCH2CH2PEt2)2]PF6, trans-[Re(SC6H4-p-CH3)2(Et2PCH2CH2PEt2)2]PF6, and trans-[Re(SC6H5)2(Ph2PCH2CH2PPh2)2]CF3SO3.cntdot.1/2NCCH3
Lihsueh Chang, Senichi Aizawa, Mary Jane Heeg, and Edward Deutsch
pp 4920 - 4927; DOI:
10.1021/ic00026a014
PDF
Crystal structure, electrical and magnetic properties of tris(N,N,N',N'-tetramethyl-p-phenylenediamine) bis(4,5-dimercapto-1,3-dithiole-2-thionato)nickelate
Derk Reefman, Joost P. Cornelissen, Rudolf A. G. De Graaff, Jaap G. Haasnoot, and Jan Reedijk
pp 4928 - 4931; DOI:
10.1021/ic00026a015
PDF
Comparative study of NS2 ligands, S-alkyl vs S-aryl. Molecular structure of [2,6-bis(((2-(methoxycarbonyl)phenyl)thio)methyl)pyridine]dichlorocopper(II)
Francesc Teixidor, Gloria Sanchez-Castello, Nativitat Lucena, Lluis Escriche, Raikko Kivekas, Markku Sundberg, and Jaume Casabo
pp 4931 - 4935; DOI:
10.1021/ic00026a016
PDF
Hydrogen potassium vanadoarsenate ([H3KV12As3O39(AsO4)]6-) and related topological and/or structural aspects of polyoxometalate chemistry
A. Mueller, M. Penk, and J. Doering
pp 4935 - 4939; DOI:
10.1021/ic00026a017
PDF
Initial stages in the molecule-based growth of the solid-state compound cobalt telluride (CoTe)
M. L. Steigerwald, T. Siegrist, and S. M. Stuczynski
pp 4940 - 4945; DOI:
10.1021/ic00026a018
PDF
Direct comparison of the preparation and structural features of crown ether and polyethylene glycol complexes of neodymium trichloride hexahydrate
Robin D. Rogers, Andrew N. Rollins, Rodger F. Henry, James S. Murdoch, Russell D. Etzenhouser, Stephen E. Huggins, and Luis Nunez
pp 4946 - 4954; DOI:
10.1021/ic00026a019
PDF
Chiral discriminations and crystal packing. Two diastereomeric compounds involving complex ions of D3 symmetry, [tris(ethylenediamine)cobalt(III)] and [tris(oxalato)rhodate(III)]
Reiko Kuroda
pp 4954 - 4959; DOI:
10.1021/ic00026a020
PDF
Condensed metal cluster iodides centered by noble metals. Six examples of cubic R3I3Z phases (R = La, Pr; Z = Os, Ir, Pt)
Peter K. Dorhout, Martin W. Payne, and John D. Corbett
pp 4960 - 4962; DOI:
10.1021/ic00026a021
PDF
A comparative synthetic and structural study of triphenylmethoxide and triphenylsiloxide complexes of the early lanthanides, including x-ray crystal structures of La2(OCPh3)6 and Ce2(OSiPh3)6
William J. Evans, Robert E. Golden, and Joseph W. Ziller
pp 4963 - 4968; DOI:
10.1021/ic00026a022
PDF
Chemistry of (octaethylporphyrinato)lutetium and -yttrium complexes: synthesis and reactivity of (OEP)MX derivatives and the selective activation of O2 by (OEP)Y(.mu.-Me)2AlMe2
Colin J. Schaverien and A. Guy Orpen
pp 4968 - 4978; DOI:
10.1021/ic00026a023
PDF
Reactivity of triphenylphosphine toward RuIIRuIIICl(O2CAr)4: syntheses, molecular structures, and spectroscopic and electrochemical properties of RuIIRuIII(OH2)Cl(MeCN)(O2CAr)4(PPh3)2 and RuII2(OH2)(MeCN)2(O2CAr)4(PPh3)2
Birinchi K. Das and Akhil R. Chakravarty
pp 4978 - 4986; DOI:
10.1021/ic00026a024
PDF
Reactions of the polyhydride complex ReH7(PPh3)2 with hydroxypyridine and mercaptopyridine ligands. Formation of hydrido complexes of rhenium(III), rhenium(IV), and rhenium(V) and the characterization of eight-coordinate isomers in the solid state and in solution
Malee Leeaphon, Phillip E. Fanwick, and Richard A. Walton
pp 4986 - 4995; DOI:
10.1021/ic00026a025
PDF
Synthesis, structure, and reactivity of chiral rhenium amine complexes of the formula [(.eta.5-C5H5)Re(NO)(PPh3)(NRR'R'')]+ TfO-
Michael A. Dewey, D. Andrew Knight, Darryl P. Klein, Atta M. Arif, and J. A. Gladysz
pp 4995 - 5002; DOI:
10.1021/ic00026a026
PDF
Catalytic asymmetric hydrogenation of imines. Use of rhodium(I)/phosphine complexes and characterization of rhodium(I)/imine complexes
Adam G. Becalski, William R. Cullen, Michael D. Fryzuk, Brian R. James, Guo J. Kang, and Steven J. Rettig
pp 5002 - 5008; DOI:
10.1021/ic00026a027
PDF
Titanatranes and azatitanatranes: nucleophilic substitution reactions on the axial position
A. A. Naiini, W. M. P. B. Menge, and J. G. Verkade
pp 5009 - 5012; DOI:
10.1021/ic00026a028
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Synthesis and characterization of the isoelectronic d10 species bis[bis(methyldiphenylsilyl)amido]cuprate(1-) and -zinc
Philip P. Power, Karin Ruhlandt-Senge, and Steven C. Shoner
pp 5013 - 5015; DOI:
10.1021/ic00026a029
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Synthesis and complexation properties of a new macrocyclic polyaza polyphosphinate ligand, DOTEP (1,4,7,10-tetraazacyclododecane-1,4,7,10-tetrakis(methyleneethylphosphinate))
Istvan Lazar, A. Dean Sherry, Ravichandran Ramasamy, Erno Brucher, and Robert Kiraly
pp 5016 - 5019; DOI:
10.1021/ic00026a030
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A triangular heterometallic siloxide containing barium
Paul S. Coan, William E. Streib, and Kenneth G. Caulton
pp 5019 - 5023; DOI:
10.1021/ic00026a031
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Oxidation of dihydroxy aromatic substrates by hexachloroiridate(IV). Mechanistic information from volumes of activation
Colin D. Hubbard, A. Gerhard, and R. Van Eldik
pp 5023 - 5027; DOI:
10.1021/ic00026a032
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Kinetic study on bis(N-alkylsalicylaldiminato)nickel(II) complexes: chiral discrimination in associatively controlled ligand substitution
Ruth Warmuth and Horst Elias
pp 5027 - 5032; DOI:
10.1021/ic00026a033
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Proton NMR kinetic study of ligand exchange on bis(1,4-dithiane)platinum(II), bis(1,4-dithiane)palladium(II), and tetrakis(dimethyl sulfide)platinum(II)
Urban Frey, Sofi Elmroth, Bertrand Moullet, Lars I. Elding, and Andre E. Merbach
pp 5033 - 5037; DOI:
10.1021/ic00026a034
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Direct determination of the self-exchange electron-transfer rate constant for a copper(II/I) macrocyclic pentathiaether complex
Ana M. Q. Vande Linde, Kerri L. Juntunen, Ole Mols, Mohamad Bachar Ksebati, L. A. Ochrymowycz, and D. B. Rorabacher
pp 5037 - 5042; DOI:
10.1021/ic00026a035
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Kinetic studies on the thiocyanate substitution of water on two incomplete cuboidal tritungsten(IV) oxo sulfido aqua complexes: [W3O2S2(H2O)9]4+ and [W3OS3(H2O)9]4+
Yue Jin Li, Carol A. Routledge, and A. Geoffrey Sykes
pp 5043 - 5046; DOI:
10.1021/ic00026a036
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.eta.1(S)- and .eta.6-coordination of dibenzothiophene (DBT) in Cp*MCl2[.eta.1(S)-DBT] and Cp*M(.eta.6-DBT)2+ (M = iridium, rhodium; Cp* = pentamethylcyclopentadienyl)
K. Mohan Rao, Catherine L. Day, Robert A. Jacobson, and Robert J. Angelici
pp 5046 - 5049; DOI:
10.1021/ic00026a037
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A superior method for the metalation of hydroporphyrins
Goutam Kumar Lahiri, Jack S. Summers, and Alan M. Stolzenberg
pp 5049 - 5052; DOI:
10.1021/ic00026a038
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Synthesis and structure of the norbornene adduct of 1,3,5,2,4,6-trithiatriazinium tetrachloroaluminate [C7H10.cntdot.S3N3][AlCl4] [Erratum to document cited in CA114(25):247242e]
Allen Apblett, Tristram Chivers, A. Wallace Cordes, and Rainer Vollmerhaus
pp 5052 - 5052; DOI:
10.1021/ic00026a039
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Preparation and structure of a mixed niobium(I) isocyanide carbonyl complex with a bent C-N-C linkage [Erratum to document cited in CA115(6):63353f]
Ghazar Aharonian, Liliane G. Hubert-Pfalzgraf, Abdenasser Zaki, and Guy Le Borgne
pp 5052 - 5052; DOI:
10.1021/ic00026a040
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Intermediates in the 1,2-diaminobenzene/tris(diethylamino)phosphine transamination reaction [Erratum to document cited in CA113(23):212146d]
Elizabeth G. Bent, R. Curtis Haltiwanger, and Arlan D. Norman
pp 5053 - 5053; DOI:
10.1021/ic00026a041
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